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Crystal structure of a new amine nitrate: 4-dimethylaminopyridinium nitrate (C7H11N2)NO3

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Abstract

The title compound (C7H11N2)NO3 (I) was obtained by the slow evaporation method at room temperature. Its crystal structure consists of organic cations (C7H11N2)+ and nitrate anions (NO3)– linked by two types of hydrogen bonds. Each monoprotonated nitrogen atom, called bifurcated, is engaged in two N–H···O hydrogen bonds with two symmetric oxygen atoms. In addition, the crystal structure stability is established by C–H···O hydrogen bonds that ensure the formation of infinite layers, parallel to (001) plane. These layers are related together through π···π interactions established between aromatic amines.

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Authors and Affiliations

  1. Laboratoire Physicochimie de l’Etat Solide, Département de Chimie Faculté des Sciences de Sfax, Université de Sfax, B.P: 1171, 3000, Sfax, Tunisia

    D. Benhassan, W. Rekik & H. Naïli

  2. Faculty of Chemistry, University of Wroclaw, Joliot-Curie 14, 50-383, Poland

    Katarzyna Ślepokura

Authors
  1. D. Benhassan
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  2. W. Rekik
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  3. H. Naïli
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  4. Katarzyna Ślepokura
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Correspondence to D. Benhassan.

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Benhassan, D., Rekik, W., Naïli, H. et al. Crystal structure of a new amine nitrate: 4-dimethylaminopyridinium nitrate (C7H11N2)NO3 . Crystallogr. Rep. 60, 1093–1096 (2015). https://doi.org/10.1134/S1063774515070044

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  • DOI: https://doi.org/10.1134/S1063774515070044

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