Abstract
The regularities of nucleation in model solutions of oral cavity have been investigated, and the induction order and constants have been determined for two systems: saliva and dental plaque fluid (DPF). It is shown that an increase in the initial supersaturation leads to a transition from the heterogeneous nucleation of crystallites to a homogeneous one. Some additives are found to enhance nucleation: HCO −3 > C6H12O6 > F−, while others hinder this process: protein (casein) > Mg2+. It is established that crystallization in DPF occurs more rapidly and the DPF composition is favorable for the growth of small (52.6–26.1 μm) crystallites. On the contrary, the conditions implemented in the model saliva solution facilitate the formation of larger (198.4-41.8 μm) crystals.
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Original Russian Text © O.A. Golovanova, E.S. Chikanova, Yu.O. Punin, 2015, published in Kristallografiya, 2015, Vol. 60, No. 3, pp. 488–495.
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Golovanova, O.A., Chikanova, E.S. & Punin, Y.O. Main features of nucleation in model solutions of oral cavity. Crystallogr. Rep. 60, 438–445 (2015). https://doi.org/10.1134/S1063774515030074
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DOI: https://doi.org/10.1134/S1063774515030074