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Crystallography Reports

, Volume 60, Issue 1, pp 37–45 | Cite as

Synthetic shibkovite K(K1.67H2O0.33)(Ca1.3Na0.7)[Zn3Si12O30]: the crystal structure and comparative crystal chemistry

  • G. V. Kiriukhina
  • O. V. Yakubovich
  • O. V. Dimitrova
Structure of Inorganic Compounds

Abstract

The structure of a single crystal of a synthetic analog of mineral shibkovite K(K1.67H2O0.33)(Ca1.3Na0.7)[Zn3Si12O30] (milarite structure type) obtained by hydrothermal synthesis in the AlPO4-K3PO4-CaCO3-Na2CO3-ZnCO3-SiO2-H2O system has been solved (R = 0.0406) by X-ray diffraction analysis: a = 10.5327(2) Å, c = 14.2019(3) Å, sp. gr. P6/mcc, Z = 2, and ρcalcd = 2.90 g/cm3. The crystal-chemical features of the new phase are studied in comparison with the other terms of the milarite group. It is shown that the crystallization conditions for minerals and synthetic analogs of this group determine the presence or absence of crystallization water in the structures of compounds.

Keywords

Crystallography Report Zinc Silicate Vertex Polyhedron Tetrahedral Framework Crystal Chemical Feature 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Inc. 2015

Authors and Affiliations

  • G. V. Kiriukhina
    • 1
  • O. V. Yakubovich
    • 1
    • 2
  • O. V. Dimitrova
    • 1
  1. 1.Faculty of GeologyMoscow State UniversityMoscowRussia
  2. 2.Institute of Geology of Ore Deposits, Petrography, Mineralogy, and GeochemistryRussian Academy of SciencesMoscowRussia

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