Abstract
Structure of nitronorbornene derivative C14H12N2O2 synthesized in the reaction of cyclopentadiene with E-2-phenyl-1-cyano-1-nitroethene was determined by single crystal X-ray diffraction analysis. It was found that in analyzed molecule the nitro group is in endo-position whereas phenyl group have exo-orientation.
Similar content being viewed by others
References
R. Jasiński, M. Rzyman, and A. Barański, Coll. Czech. Chem. Commun. 75, 919 (2010).
R. Huisgen, Angew. Chem. 75, 742 (1963).
F. Fringuelli and A. Taticchi, Dienes in the Diels-Alder Reaction (New York, 1990).
R. Jasiński, M. Kwiatkowska, and A. Barański, Monatsh. Chem. 143, 895 (2012).
R. Jasiński, M. Kwiatkowska, and A. Barański, J. Mol. Struct. (TheoChem) 910, 80 (2009).
R. Jasiński, M. Kwiatkowska, A. Barański, Czasopismo Tech. PK (Chemia) 41 (2006).
R. T. Arnold and G. P. Scott, Org. Synth. 4, 238 (1963).
Program CRYSALISPRO Version 1.171 (Oxford Diffraction, Abingdon, England, 2008).
G. M. Sheldrick, Acta Crystallogr. A 64, 112 (2008).
A. V. Shastin, V. G. Nenajdenko, V. M. Muzalevskiy, E. S. Balenkova, R. Frohlich, and G. Haufe, Tetrahedron 64, 9725 (2008).
J. Zukerman-Schpector, Acta Crystallogr. C 2, 980 (1999).
L. Nicolas, M. Beugelmans-Verrier, and J. Guilhem, Tetrahedron 37, 3847 (1981).
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Łapczuk-Krygier, A., Ponikiewski, Ł. & Jasiński, R. The crystal structure of (1RS,4RS,5RS,6SR)-5-cyano-5-nitro-6-phenyl-bicyclo[2.2.1]hept-2-ene. Crystallogr. Rep. 59, 961–963 (2014). https://doi.org/10.1134/S1063774514070128
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063774514070128