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Crystallography Reports

, Volume 59, Issue 7, pp 1107–1113 | Cite as

Ceramic nanotubes for polymer composites with stable anticorrosion properties

  • R. F. Fakhrullin
  • A. Tursunbayeva
  • V. S. Portnov
  • Yu. M. L’vovEmail author
Nanomaterials and Ceramics

Abstract

The use of natural halloysite clay tubes 50 nm in diameter as nanocontainers for loading, storing, and slowly releasing organic corrosion inhibitors is described. Loaded nanotubes can be mixed well with many polymers and dyes in amounts of 5–10 wt % to form a ceramic framework (which increases the strength of halloysite composites by 30–50%), increase the adhesion of these coatings to metals, and allow for the slow release of corrosion inhibitors in defects of coatings. A significant improvement of protective anticorrosion properties of polyacryl and polyurethane coatings containing ceramic nanotubes loaded with benzotriazole and hydroxyquinoline is demonstrated.

Keywords

Polymer Composite Crystallography Report Corrosion Inhibitor Dodecylamine Anticorrosion Property 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    E. Joussein, S. Petit, J. Churchman, et al., Clay Miner. 40, 383 (2005).CrossRefGoogle Scholar
  2. 2.
    Y. Lvov, D. Shchukin, H. Möhwald, et al., ACS Nano 2, 814 (2008).CrossRefGoogle Scholar
  3. 3.
    M. Du, B. Guo, and D. Jia, Polymer Intern. 59, 574 (2010).Google Scholar
  4. 4.
    Y. Lvov and E. Abdullayev, Progress Polymer Sci. 38, 1690 (2013).CrossRefGoogle Scholar
  5. 5.
    E. Abdullayev, V. Abbasov, A. Tursunbayeva, et al., ACS Appl. Mater. Surf. 5, 4464 (2013).Google Scholar
  6. 6.
    E. Abdullayev and Y. Lvov, J. Mater. Chem. B 1, 2894 (2013).CrossRefGoogle Scholar
  7. 7.
    E. Abdullayev, A. Joshi, W. Wei, et al., ACS Nano 6, 7216 (2012).CrossRefGoogle Scholar
  8. 8.
    W-O. Yah, A. Takahara, and Y. Lvov, J. Am. Chem. Soc. 134, 1853 (2012).CrossRefGoogle Scholar
  9. 9.
    X. Lai, M. Agarwal, Y. Lvov, et al., J. Appl. Toxicity 33, 1316 (2013).Google Scholar
  10. 10.
    V. Vergaro, E. Abdullayev, R. Cingolani, et al., Biomacromol. 11, 820 (2010).CrossRefGoogle Scholar
  11. 11.
    Y. Zhang, Y. Chen, H. Zhang, et al., J. Inorg. Biochem. 118, 59 (2013).CrossRefGoogle Scholar
  12. 12.
    D. Shchukin and H. Möhwald, Small 3, 926 (2007).CrossRefGoogle Scholar
  13. 13.
    F. Presuel-Moreno, M. Jakab, N. Tailleart, et al., Mater. Today 11, 14 (2008).CrossRefGoogle Scholar
  14. 14.
    H. Kelly, P. Deasy, E. Ziaka, et al., Int. J. Pharm. 274, 167 (2004).CrossRefGoogle Scholar
  15. 15.
    Y. Lvov, A. Aerov, and R. Fakhrullin, Adv. Colloid Interface Sci. 201, 1287 (2013).Google Scholar
  16. 16.
    E. Abdullayev, K. Sakakibara, K. Okamoto, et al., ACS Appl. Mater. Interf. 3, 4040 (2011).CrossRefGoogle Scholar
  17. 17.
    K. Babic-Samardzija and N. Hackerman, J. Solid State Electrochem. 9, 483 (2005).CrossRefGoogle Scholar
  18. 18.
    B. Guo, Y. Lei, F. Chen, et al., Appl. Surf. Sci. 7, 188 (2008).Google Scholar
  19. 19.
    B. Guo, Q. Zou, Y. Lei, et al., New Chem. Mater. 36, 32 (2008).Google Scholar
  20. 20.
    M. Liu, B. Guo, M. Du, et al., Nanotechnology 18, 455703 (2007).ADSCrossRefGoogle Scholar
  21. 21.
    M. Du, B. Guo, and D. Jia, Eur. Polym. J. 42, 1362 (2006).CrossRefGoogle Scholar
  22. 22.
    G. Cavallaro, G. Lazzara, S. Milioto, et al., Langmuir 27, 1158 (2011).CrossRefGoogle Scholar
  23. 23.
    M. Liu, C. Wu, Y. Jiao, et al., J. Mater. Chem. B 1, 2078 (2013).CrossRefGoogle Scholar
  24. 24.
    Z. Huang, Z. Jia, B. Guo, et al., China Plast. Ind. 36, 29 (2008).Google Scholar
  25. 25.
    D. Fix, D. Andreeva, H. Möhwald, et al., Adv. Funct. Mater. 19, 1720 (2009).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Inc. 2014

Authors and Affiliations

  • R. F. Fakhrullin
    • 1
  • A. Tursunbayeva
    • 2
  • V. S. Portnov
    • 3
  • Yu. M. L’vov
    • 4
    Email author
  1. 1.Kazan (Volga Region) Federal UniversityKazan, TatarstanRussia
  2. 2.S. Seifullin Kazakh Agro Technical UniversityAstanaKazakhstan
  3. 3.Karaganda State Technical UniversityKaragandaKazakhstan
  4. 4.Louisiana Tech UniversityRustonUSA

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