Skip to main content
Log in

X-ray diffraction study of an as-grown crystal of a two-phase sample of Lu0.65Ca0.35F2.65

  • Structure of Inorganic Compounds
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

The X-ray diffraction study of an “as-grown” crystal of Lu0.65Ca0.35F2.65 revealed for the first time two phases with a regular mutual orientation. The c axis of the hexagonal phase (a = 3.88 Å, c = 6.89 Å) is oriented along the body diagonal to the cubic phase (a = 5.50 Å). The hexagonal phase has a tysonite-type structure with a “small” unit cell (P63/mmc, Z = 2). The cubic phase has a fluorite structure (\(Fm\bar 3m\), Z = 4).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. B. P. Sobolev, The Rare Earth Trifluorides, Part 1: The High Temperature Chemistry of the Rare Earth Trifluorides (Institute of Crystallography, Moscow, and Institut d’Estudis Catalans, Barcelona, 2000); www.books.google.ru/books/rare earth trifluorides.

    Google Scholar 

  2. B. P. Sobolev, The Rare Earth Trifluorides, Part 2: Introduction to Materials Science of Multicomponent Metal Fluoride Crystals (Institute of Crystallography, Moscow, and Institut d’Estudis Catalans, Barcelona, 2001); www.books.google.ru/books/rare earth trifluorides.

    Google Scholar 

  3. B. P. Sobolev, Crystallogr. Rep. 57(3), 434 (2012).

    Article  ADS  Google Scholar 

  4. N. I. Sorokin and B. P. Sobolev, Crystallogr. Rep. 52(5), 842 (2007).

    Article  ADS  Google Scholar 

  5. L. P. Otroshchenko, B. P. Aleksandrov, B. A. Maksimov, et al., Kristallografiya 30(4), 658 (1985).

    Google Scholar 

  6. S. F. Radaev, E. A. Krivandina, L. A. Muradyan, et al., Kristallografiya 36(2), 369 (1991).

    Google Scholar 

  7. A. P. Dudka, A. A. Loshmanov, and B. P. Sobolev, Kristallografiya 43(4), 605 (1998).

    ADS  Google Scholar 

  8. N. B. Bolotina, A. I. Kalyukanov, T. S. Chernaya, et al., Crystallogr. Rep. 58(4), 575 (2013).

    Article  ADS  Google Scholar 

  9. CrysAlisPro. Version 171.37.31 (Agilent Technologies).

  10. V. Petricek, M. Dusek, and L. Palatinus, JANA2006. Structure Determination Software Programs (Institute of Physics, Prague, 2006).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to T. S. Chernaya.

Additional information

Dedicated to the International Year of Crystallography

Original Russian Text © T.S. Chernaya, N.B. Bolotina, I.A. Verin, B.P. Sobolev, 2014, published in Kristallografiya, 2014, Vol. 59, No. 6, pp. 962–965.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chernaya, T.S., Bolotina, N.B., Verin, I.A. et al. X-ray diffraction study of an as-grown crystal of a two-phase sample of Lu0.65Ca0.35F2.65 . Crystallogr. Rep. 59, 874–877 (2014). https://doi.org/10.1134/S1063774514060066

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063774514060066

Keywords

Navigation