Abstract
The X-ray diffraction study of an “as-grown” crystal of Lu0.65Ca0.35F2.65 revealed for the first time two phases with a regular mutual orientation. The c axis of the hexagonal phase (a = 3.88 Å, c = 6.89 Å) is oriented along the body diagonal to the cubic phase (a = 5.50 Å). The hexagonal phase has a tysonite-type structure with a “small” unit cell (P63/mmc, Z = 2). The cubic phase has a fluorite structure (\(Fm\bar 3m\), Z = 4).
Similar content being viewed by others
References
B. P. Sobolev, The Rare Earth Trifluorides, Part 1: The High Temperature Chemistry of the Rare Earth Trifluorides (Institute of Crystallography, Moscow, and Institut d’Estudis Catalans, Barcelona, 2000); www.books.google.ru/books/rare earth trifluorides.
B. P. Sobolev, The Rare Earth Trifluorides, Part 2: Introduction to Materials Science of Multicomponent Metal Fluoride Crystals (Institute of Crystallography, Moscow, and Institut d’Estudis Catalans, Barcelona, 2001); www.books.google.ru/books/rare earth trifluorides.
B. P. Sobolev, Crystallogr. Rep. 57(3), 434 (2012).
N. I. Sorokin and B. P. Sobolev, Crystallogr. Rep. 52(5), 842 (2007).
L. P. Otroshchenko, B. P. Aleksandrov, B. A. Maksimov, et al., Kristallografiya 30(4), 658 (1985).
S. F. Radaev, E. A. Krivandina, L. A. Muradyan, et al., Kristallografiya 36(2), 369 (1991).
A. P. Dudka, A. A. Loshmanov, and B. P. Sobolev, Kristallografiya 43(4), 605 (1998).
N. B. Bolotina, A. I. Kalyukanov, T. S. Chernaya, et al., Crystallogr. Rep. 58(4), 575 (2013).
CrysAlisPro. Version 171.37.31 (Agilent Technologies).
V. Petricek, M. Dusek, and L. Palatinus, JANA2006. Structure Determination Software Programs (Institute of Physics, Prague, 2006).
Author information
Authors and Affiliations
Corresponding author
Additional information
Dedicated to the International Year of Crystallography
Original Russian Text © T.S. Chernaya, N.B. Bolotina, I.A. Verin, B.P. Sobolev, 2014, published in Kristallografiya, 2014, Vol. 59, No. 6, pp. 962–965.
Rights and permissions
About this article
Cite this article
Chernaya, T.S., Bolotina, N.B., Verin, I.A. et al. X-ray diffraction study of an as-grown crystal of a two-phase sample of Lu0.65Ca0.35F2.65 . Crystallogr. Rep. 59, 874–877 (2014). https://doi.org/10.1134/S1063774514060066
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063774514060066