Abstract
The microstructure of Al-, Ge-, and Mo-doped higher manganese silicide crystals (HMS), grown by the Bridgman method have been investigated by transmission electron diffraction, electron backscatter diffraction, scanning electron microscopy, and X-ray energy-dispersive spectrometry. It is shown that the matrix crystal has the Mn4Si7 structure. The introduction of Ge and Mo impurities into an HMS crystal results in the precipitation of Si-Ge solid solution and molybdenum disilicide. The size of precipitates varies in a wide range: from several nanometers to several hundreds of micrometers. The following orientation relationships between Ge-Si precipitates and the Mn4Si7 crystal were determined: (112)\([\bar 110]\) Ge-Si ‖ (010)[100] Mn4Si7. Polycrystalline MoSi2 precipitates form a multicomponent texture along the [001] Mn4Si7 direction. Small amounts of cubic MnSi and Al-Mn-Si alloy precipitates were revealed. In addition, Al oxide was observed mainly in crystal pores. It is shown that 0.5–0.8 at % Al, 0.4–0.6 at % Mo, and 1.5–2.0 at % Ge impurities are incorporated into the Mn4Si7 lattice.
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Original Russian Text © A.S. Orekhov, E.I. Suvorova, 2014, published in Kristallografiya, 2014, Vol. 59, No. 1, pp. 83–91.
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Orekhov, A.S., Suvorova, E.I. Study of doped higher manganese silicides crystals by transmission electron diffraction and electron backscatter diffraction. Crystallogr. Rep. 59, 78–87 (2014). https://doi.org/10.1134/S106377451401009X
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DOI: https://doi.org/10.1134/S106377451401009X