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Alkylation of a bioinspired high spin Ni(II)N3S2 complex with bifunctional reagents

  • Structure of Organic Compounds
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Abstract

Crystal structures of two S-alkylated complexes generated from the reaction of iodoacetamide and iodoethanol with an air and moisture sensitive high spin Ni(II) pentacoordinate triaminodithiolate complex, 1 are determined by X-ray structure analysis. Crystals of complex 2, [NiC16H31N5O2S2]I2, are triclinic, sp. gr. \(P\bar 1\), Z = 2. Crystals of complex 3, [NiC16H28N3O2S2]I2, are monoclinic, sp. gr. P21/c, Z = 4. Structures of complexes 2 and 3 are very similar: one of the S-acetamide (2) or S-ethanol (3) groups coordinates to the Ni center through the oxygen atom forming N3S2O hexacoordination; the other group remains unbound to the Ni and left dangling. Crystal packing shows that complexes 2 and 3 interact with the iodide counterions, and that only complex 2 interact with neighboring molecules; some of these close intermolecular contacts include H-bonding interactions.

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  1. Department of Chemistry, The Pennsylvania State University, University Park, PA, 16802, USA

    B. S. Chohan

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  1. B. S. Chohan
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Chohan, B.S. Alkylation of a bioinspired high spin Ni(II)N3S2 complex with bifunctional reagents. Crystallogr. Rep. 58, 1067–1072 (2013). https://doi.org/10.1134/S1063774513080014

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  • DOI: https://doi.org/10.1134/S1063774513080014

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