Abstract
X-ray single crystal diffraction study of the new molecular conductor (TSeF)7[FeNO(CN)5]2 has been carried out at room temperature and 130 K. The crystal structure is composed by layers of π-electron donors TSeF, separated by anion layers along the a-direction. The conducting organic layer has unusual for molecular conductors arrangement of neutral monomeric and charged hexameric TSeF units orthogonally packed with respect to each other. Another specific feature of the structure is fully ordered state of the nitroprusside anion and deep penetrating of its functional NO-group into the adjacent organic layer.
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Dedicated to the memory of N.V. Belov
Original Russian Text © L.V. Zorina, S.V. Simonov, S.S. Khasanov, R.P. Shibaeva, I.Yu. Suslikova, L.A. Kushch, E.B. Yagubskii, 2011, published in Kristallografiya, 2011, Vol. 56, No. 6, pp. 1111–1115.
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Zorina, L.V., Simonov, S.V., Khasanov, S.S. et al. Crystal structure of the new organic conductor (TSeF)7[FeNO(CN)5]2 with unusual molecular packing of conducting layer. Crystallogr. Rep. 56, 1042–1046 (2011). https://doi.org/10.1134/S1063774511060307
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DOI: https://doi.org/10.1134/S1063774511060307