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Crystal and molecular structures of trifluoromethyl derivatives of fullerenes C76 and C82

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Abstract

Trifluoromethyl derivatives of C76 and C82 were synthesized by the reaction of a mixture of higher fullerenes with trifluoroiodomethane followed by the separation by high-performance liquid chromatography. The crystal and molecular structures of C76(CF3)16 (two isomers) and crystal solvates of C76(CF3)18, C82(CF3)16, and C82(CF3)18 were determined by single-crystal X-ray diffraction using synchrotron radiation. The addition patterns of CF3 groups in the C76(CF3)14–18 and C82(CF3)16–18 molecules are discussed.

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    M. A. Lanskikh, Yu. M. Belova, N. B. Tamm & S. I. Troyanov

  2. Institute of Chemistry, Humboldt University of Berlin, Brook-Taylor Strasse 2, Berlin, 12489, Germany

    K. Chang & E. Kemnitz

Authors
  1. M. A. Lanskikh
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  2. Yu. M. Belova
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  3. N. B. Tamm
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  4. K. Chang
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  5. E. Kemnitz
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  6. S. I. Troyanov
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Corresponding author

Correspondence to S. I. Troyanov.

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Dedicated to the memory of N.V. Belov

Original Russian Text © M.A. Lanskikh, Yu.M. Belova, N.B. Tamm, K. Chang, E. Kemnitz, S.I. Troyanov, 2011, published in Kristallografiya, 2011, Vol. 56, No. 6, pp. 1116–1122.

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Lanskikh, M.A., Belova, Y.M., Tamm, N.B. et al. Crystal and molecular structures of trifluoromethyl derivatives of fullerenes C76 and C82 . Crystallogr. Rep. 56, 1047–1053 (2011). https://doi.org/10.1134/S1063774511050178

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  • DOI: https://doi.org/10.1134/S1063774511050178

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