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Structure and magnetic properties of heterometallic coordination carboxylate polymers with cobalt and lithium atoms

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Abstract

Reactions between lithium pivalate and cobalt coordination polymers [Co5(OH2)(OH)(Piv)9)L 1)4] n (I) and [Co2(OH2)(Piv)4(L 2)2] n (II), where Piv—is the pivalate anion, L 1 is pyrazine, and L 2 is pyrimidine, result in new heterometallic polymers {[Li2Co2(Piv)6(L 1)2]2 MeCN} n (III), {[Li2Co2(Piv)6(L 2)]0.5 MeCN} n (IV), and [Li2Co2(Piv)6(L 2)2] n (V). The resulting compounds contain tetra-nuclear {Li2Co2(Piv)6} fragments connected by neutral bridging ligands (pyrazine or pyrimidine) into layer structures. Crystal structures III–V are determined, and the magnetic properties of III and IV are studied.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    I. E. Evstifeev, M. A. Kiskin, A. A. Sidorov, V. M. Novotortsev & I. L. Eremenko

  2. International Tomography Center, Siberian Branch, Russian Academy of Sciences, ul. Institutskaya 3a, Novosibirsk, 630090, Russia

    A. S. Bogomyakov

Authors
  1. I. E. Evstifeev
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  2. M. A. Kiskin
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  3. A. S. Bogomyakov
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  4. A. A. Sidorov
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  5. V. M. Novotortsev
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  6. I. L. Eremenko
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Corresponding author

Correspondence to M. A. Kiskin.

Additional information

Original Russian Text © I.E. Evstifeev, M.A. Kiskin, A.S. Bogomyakov, A.A. Sidorov, V.M. Novotortsev, I.L. Eremenko, 2011, published in Kristallografiya, 2011, Vol. 56, No. 5, pp. 900–905.

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Evstifeev, I.E., Kiskin, M.A., Bogomyakov, A.S. et al. Structure and magnetic properties of heterometallic coordination carboxylate polymers with cobalt and lithium atoms. Crystallogr. Rep. 56, 842–847 (2011). https://doi.org/10.1134/S1063774511050087

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  • DOI: https://doi.org/10.1134/S1063774511050087

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