Abstract
The mechanism of growth of quartz crystals from fluoride media has been investigated. It is shown by different independent methods (selective etching, X-ray diffraction analysis, optical microscopy) that the faceted forms of autonomous growth regions (trigonal pyramids formed on nonsingular crystal faces) are unstable and degenerate during growth. This degeneracy is accompanied by torsion deformation of autonomous growth regions and, as a result, formation of a series of hollow helical channels at boundaries of autonomous growth regions, whose axes make an angle of ∼16° with the OZ axis, and their projections on the XOY plane are directed along the +X axes.
Similar content being viewed by others
References
V. S. Balitskiĭ, T. M. Bublikova, and E. A. Mar’ina, Experimental and Theoretical Simulation of the Processes of Mineral Formation (Nauka, Moscow, 1998), p. 492 [in Russian].
R. M. Mazitov, A. N. Chuvyrov, and V. S. Balitskiĭ, Dokl. Akad. Nauk SSSR 247(6), 1475 (1979).
A. N. Chuvyrov, V. S. Balitskiĭ, R. M. Mazitov, et al., Dokl. Akad. Nauk SSSR 314(4), 113 (1990).
V. E. Khadzhi, L. I. Tsinober, and L. M. Shterenlikht, Synthesis of Minerals (Nedra, Moscow, 1987), Vol. 1 [in Russian].
V. S. Balitsky, L. V. Balitskaya, T. M. Bublikova, et al., J. Supercrit. Fluids, No. 13, 357 (1998).
V. Zamarovsky, Their Majesties, the Pyramids (Nauka, Moscow, 1986) [in Russian].
A. N. Bryzgalov, Doctoral Dissertation in Mathematical Physics (IFMK UNTs RAN, Ufa, 1998).
V. S. Balitskiĭ, I. V. Makhina, and L. T. Litvin, Dokl. Akad. Nauk SSSR 214(3), 654 (1974).
V. S. Balitsky, J. Cryst. Growth 41(1), 100 (1977).
E. V. Tsinzerling and Z. A. Mironova, Kristallografiya 8(1), 117 (1963) [Sov. Phys. Crystallogr. 8, 89 (1963)].
E. V. Tsinzerling and O. B. Vol’skaya, Kristallografiya 10(1), 116 (1965) [Sov. Phys. Crystallogr. 10, 93 (1965)].
F. Auqustine and D. R. Hale, J. Phys. Chem. Solids 13, 344, 1960.
O. Hanyi, J. Phys. Soc. Jpn. 19(8), 1489 (1964).
E. V. Tsinzerling, Kristallografiya 12(2), 370 (1967) [Sov. Phys. Crystallogr. 12, 319 (1967)].
M. S. Joshi and P. N. Kotru, Jpn. J. Appl. Phys. 7(7), 700 (1966).
M. S. Joshi and A. S. Vag, Kristallografiya 12(4), 656 (1967) [Sov. Phys. Crystallogr. 12, 573 (1967)].
N. A. Afanas’eva, I. E. Kamentsev, and V. A. Frank-Kamenetskiĭ, Kristallografiya 4(3), 382 (1959) [Sov. Phys. Crystallogr. 4, 354 (1959)].
I. I. Shafranovskiĭ, Zap. Vses. Mineral. O-va 73(1), 23 (1945).
F. C. Frank, Philos. Mag. 42, 1014 (1951).
A. J. Firty, Philos. Mag. 43, 72 (1952).
I. I. Shafranovskiĭ, Lectures on Crystal Morphology (Vysshaya Shkola, Moscow, 1968) [in Russian].
Yu. S. Kuz’minov, Kristallografiya 52(5), 906 (2007) [Crystallogr. Rep. 52, 906 (2007)].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.N. Chuvyrov, R.M. Mazitov, 2008, published in Kristallografiya, 2008, Vol. 53, No. 5, pp. 943–949.
Rights and permissions
About this article
Cite this article
Chuvyrov, A.N., Mazitov, R.M. Structure and properties of quartz crystals grown from fluoride solutions: I. The morphology of basal pinacoid habit. Crystallogr. Rep. 53, 894–899 (2008). https://doi.org/10.1134/S106377450805026X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S106377450805026X