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Synthesis and crystal structure of catena-bis(nicotinamide)aqua(μ-phthalato)copper(II) hemihydrate

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Abstract

The copper(II) phthalate complex with nicotinamide [CuL 2(μ-Pht)(H2O)] · 0.5H2O(I) (where L is nicotinamide and Pht 2− is an anion of phthalic acid) is synthesized and investigated using IR spectroscopy and X-ray diffraction. The crystals of compound I are monoclinic, a = 13.368(2) Å, b = 7.891(3) Å, c = 20.480(2) Å, β = 108.69(2)°, Z = 4, and space group P21/c. The structural units of crystal I are linear chains formed by bridging phthalate anions and crystallization water molecules. The copper atom is coordinated by two pyridine nitrogen atoms of two nicotinamide ligands (Cu-N, 2.001 and 2.045 Å), two oxygen atoms of different phthalate anions (Cu-O, 1.964 and 2.235 Å), and the oxygen atom of the H2 O molecule (Cu-O, 2.014 Å). The coordination polyhedron of the copper atom is completed to an elongated (4 + 1 + 1) tetragonal bipyramid by the second (chelating) oxygen atom of the carboxyl group (Cu-O, 2.587 Å), which is one of the anions of phthalic acid. The linear polymer molecules are joined into complex macromolecular dimers with the closest internal contacts of the specific type. The macromolecular dimers are the main supramolecular ensembles of the crystal structure.

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References

  1. A. S. Antsyshkina, M. A. Poraoe-Koshits, M. Gandlovich, et al., Koord. Khim. 5(11), 1716 (1979).

    Google Scholar 

  2. A. S. Antsyshkina, G. G. Sadikov, T. V. Koksharova, et al., Zh. Neorg. Khim. 51(10), 1671 (2006) [Russ. J. Inorg. Chem. 51 (10), 1571 (2006)].

    Google Scholar 

  3. G. V. Tsintsadze, R. A. Kiguradze, A. N. Shnulin, and Kh. S. Mamedov, Zh. Strukt. Khim. 25(6), 82 (1984).

    Google Scholar 

  4. A. S. Antsyshkina, T. V. Koksharova, G. G. Sadikov, et al., Zh. Neorg. Khim. 51(6), 972 (2006) [Russ. J. Inorg. Chem. 51 (6), 901 (2006)].

    Google Scholar 

  5. M. I. Matsaberidze, A. S. Batsanov, R. G. Gerr, et al., Koord. Khim. 11(3), 411 (1985).

    Google Scholar 

  6. T. A. Azizov, Kh. T. Sharipov, N. A. Parpiev, et al., Zh. Neorg. Khim. 36(7), 1722 (1991).

    Google Scholar 

  7. S. G. Baca, I. G. Filippova, O. A. Cherco, et al., Inorg. Chim. Acta 357, 3419 (2004).

    Article  Google Scholar 

  8. T. Cojocari, Ch. Ambrus, H. Adams, et al., in Abstracts of Papers of the XV International Conference “Physical Methods in Coordination and Supramolecular Chemistry,” Chĭsinäu, Moldova, 2006 (Chĭsinäu, Moldova, 2006), p. 115.

    Google Scholar 

  9. S. G. Baca, I. G. Filippova, O. A. Gherco, et al., Inorg. Chim. Acta 357(12), 3419 (2004).

    Article  Google Scholar 

  10. S. G. Baca, S. T. Malinovskii, P. Franz, et al., J. Solid State Chem. 177(8) (2004).

  11. G. M. Sheldrick, SHELX97: Program for the Solution and Refinement of the Crystal Structures (University of Göttingen, Göttingen, Germany, 1997).

    Google Scholar 

  12. T. V. Koksharova, G. G. Sadikov, A. S. Antsyshkina, et al., Zh. Neorg. Khim. 51(6), 966 (2006) [Russ. J. Inorg. Chem. 51 (6), 895 (2006)].

    Google Scholar 

  13. A. S. Antsyshkina, T. V. Koksharova, G. G. Sadikov, et al., in Abstracts of Papers of the XV International Conference “Physical Methods in Coordination and Supramolecular Chemistry,” Chĭsinäu, Moldova, 2006 (Chĭsinäu, Moldova, 2006), p. 91.

    Google Scholar 

  14. A. I. Kitaigorodskii, Mixed Crystals (Nauka, Moscow, 1983; Springer, Berlin, 1984).

    Google Scholar 

  15. G. G. Sadikov, A. S. Antsyshkina, V. S. Sergienko, and A. D. Garnovskiĭ, Kristallografiya 51(6), 1132 (2006) [Crystallogr. Rep. 52 (1), 94 (2007)].

    Google Scholar 

  16. H. Xu, R. Sun, Y.-Z. Li, and J.-F. Bai, Acta Crystallogr., Sect. E: Struct. Rep. Online 62, 1156 (2006).

    Article  Google Scholar 

  17. L. Tian, L. Chen, and L.-H. Yi, Xiangtan Daxue Ziran Kexue Xuebao (Nat. Sci. J. Xiangtan Univ.) 25, 113 (2003).

    Google Scholar 

  18. C.-H. Ye, H.-L. Sun, X.-Y. Wang, et al., J. Chem. Crystallogr. 35, 381 (2005).

    Article  Google Scholar 

  19. I. Krstanovic, L. Karanovic, and D. Stojakovic, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 41, 43 (1985).

    Article  Google Scholar 

  20. X.-C. Fu, X.-Y. Wang, M.-T. Li, et al., Acta Crystallogr., Sect. E: Struct. Rep. Online 62, 43 (2006).

    Google Scholar 

  21. N. V. Gerbeleu, Yu. A. Simonov, G. A. Timko, et al., Zh. Neorg. Khim. 44(8), 1264 (1999) [Russ. J. Inorg. Chem. 44 (8), 1191 (1999)].

    Google Scholar 

  22. D. Poleti, L. Karanovic, and B. V. Prelesnik, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 49, 1249 (1993).

    Article  Google Scholar 

  23. Y. Zhang, J. LI, Q. Su, et al., J. Mol. Struct. 516, 231 (2000).

    Article  ADS  Google Scholar 

  24. S. G. Baca, M. T. Reetz, R. Goddard, et al., Polyhedron 25, 1215 (2006).

    Article  Google Scholar 

  25. S. L. Ma and L. Z. Zhang, Pol. J. Chem. 76(11), 1537 (2002).

    Google Scholar 

  26. A. Yu. Tsivadze, G. V. Tsintsadze, Yu. Ya. Kharitonov, and L. V. Gverdtsiteli, Zh. Neorg. Khim. 23(2), 447 (1978).

    Google Scholar 

  27. A. A. Shabilalov, N. N. Borisova, and M. A. Azizov, Koord. Khim. 13(9), 1227 (1987).

    Google Scholar 

  28. G. V. Tsintsadze, M. V. Shavtvaladze, and A. Yu. Tsivadze, Koord. Khim. 16(12), 1666 (1990).

    Google Scholar 

  29. C. K. Prout, J. R. Carruthers, and F. J. C. Rossotti, J. Chem. Soc. A, p. 3350 (1971).

  30. Yu. N. Kukushkin, Chemistry of Coordination Compounds (Vysshaya Shkola, Moscow, 1985) [in Russian].

    Google Scholar 

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiĭ pr. 31, Moscow, 119991, Russia

    G. G. Sadikov, A. S. Antsyshkina & V. S. Sergienko

  2. Odessa National University, Dvoryanskaya ul. 2, Odessa, 65026, Ukraine

    T. V. Koksharova & I. S. Gritsenko

Authors
  1. G. G. Sadikov
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  2. T. V. Koksharova
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  3. A. S. Antsyshkina
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  4. I. S. Gritsenko
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  5. V. S. Sergienko
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Correspondence to G. G. Sadikov.

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Original Russian Text © G.G. Sadikov, T.V. Koksharova, A.S. Antsyshkina, I.S. Gritsenko, V.S. Sergienko, 2008, published in Kristallografiya, 2008, Vol. 53, No. 4, pp. 668–675.

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Sadikov, G.G., Koksharova, T.V., Antsyshkina, A.S. et al. Synthesis and crystal structure of catena-bis(nicotinamide)aqua(μ-phthalato)copper(II) hemihydrate. Crystallogr. Rep. 53, 631–638 (2008). https://doi.org/10.1134/S1063774508040135

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