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Compositions of supersaturated solutions for enhanced growth of α-NiSO4 · 6H2O, Me 2Ni(SO4)2 · 6H2O, MeH2PO4 [Me = Li, Na, K, Rb, Cs, NH4], and K(H x D1−x )2PO4 single crystals

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Abstract

The possibility of determining the optimal compositions and temperatures of supersaturated solutions for enhanced growth of single crystals of congruently and incongruently dissolving solid phases from the solubility diagrams of ternary systems is shown, and this approach is justified. The NiSO4-H2SO4-H2O, Me 2SO4-NiSO4-H2O, and Me 2O-P2O5-H2O(D2O) systems have been used to determine the optimal compositions and temperatures of supersaturated solutions for growth of α-NiSO4 · 6H2O, Me 2Ni(SO4)2 · 6H2O, MeH2PO4 [Me = Li, Na, K, Rb, Cs, NH4], and K (H x D1−x )2PO4 (D is deuterium) single crystals.

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References

  1. V. A. Anosov and S. A. Pogodin, Fundamentals of Physico-Chemical Analysis (Izd-vo Akad. Nauk SSSR, Moscow, 1947) [in Russian].

    Google Scholar 

  2. L. V. Soboleva, Neorg. Mater. 31(5), 614 (1995).

    MathSciNet  Google Scholar 

  3. L. V. Soboleva, Neorg. Mater. 32(28), 1007 (1996).

    Google Scholar 

  4. L. V. Soboleva and I. L. Smol’skiĭ, Kristallografiya 42(4), 762 (1997) [Crystallogr. Rep. 42, 700 (1997)].

    Google Scholar 

  5. L. V. Soboleva, E. B. Rudneva, and I. L. Smol’skiĭ, Kristallografiya 43(4), 756 (1998) [Crystallogr. Rep. 43, 706 (1998)].

    Google Scholar 

  6. L. V. Soboleva and L. F. Kirpichnikova, Kristallografiya 46(2), 350 (2001) [Crystallogr. Rep. 46, 306 (2001)].

    Google Scholar 

  7. L. V. Soboleva and A. É. Voloshin, Kristallografiya 47(5), 937 (2002) [Crystallogr. Rep. 47, 871 (2002)].

    Google Scholar 

  8. L. V. Soboleva, A. É. Voloshin, V. A. Kirikov, and M. V. Biglova, Kristallografiya 47(1), 140 (2002) [Crystallogr. Rep. 47, 130 (2002)].

    ADS  Google Scholar 

  9. L. V. Soboleva and A. É. Voloshin, Kristallografiya 49(4), 773 (2004) [Crystallogr. Rep. 49, 693 (2004)].

    Google Scholar 

  10. L. V. Soboleva, Kristallografiya 50(4), 761 (2005) [Crystallogr. Rep. 50, 706 (2005)].

    Google Scholar 

  11. L. V. Soboleva, Kristallografiya 52(6), 1141 (2007) [Crystallogr. Rep. 52, 1104 (2007)].

    Google Scholar 

  12. L. M. Belyaev, M. G. Vasil’eva, and L. V. Soboleva, Kristallografiya 26(2), 373 (1981) [Sov. Phys. Crystallogr. 26, 212 (1981)].

    Google Scholar 

  13. V. A. Kuznetsov, L. V. Soboleva, V. V. Ugarov, and A. A. Chernov, Kristallografiya 31(3), 618 (1986) [Sov. Phys. Crystallogr. 31, 365 (1986)].

    Google Scholar 

  14. L. V. Soboleva, Neorg. Mater. 23(4), 642 (1990).

    Google Scholar 

  15. A. B. Vasil’ev, V. A. Kuznetsov, L. V. Soboleva, et al., Kristallografiya 33(3), 755 (1988) [Sov. Phys. Crystallogr. 33, 443 (1988)].

    Google Scholar 

  16. J. Koppel and H. Wetzel, Z. Phys. Chem. 52, 395 (1905).

    Google Scholar 

  17. V. P. Blidin and T. A. Andreeva, Zh. Neorg. Khim. 3(10), 2414 (1958).

    Google Scholar 

  18. A. Benrath, Z. Anorg. Allg. Chem. 202, 161 (1931).

    Article  Google Scholar 

  19. I. G. Druzhinin, V. G. Kuznetsov, and B. Imanakunov, Izv. Akad. Nauk Kirgiz. SSR, Ser. Estestv. Tech. Nauk 2(3), 25 (1960).

    Google Scholar 

  20. B. Benraht, Z. Anorg. Allg. Chem. 208, 169 (1932).

    Article  Google Scholar 

  21. R. Bunsen and G. Kirchgoff, Pogg. Ann 43, 187 (1861).

    Google Scholar 

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Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskiĭ pr. 59, Moscow, 119333, Russia

    L. V. Soboleva

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  1. L. V. Soboleva
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Correspondence to L. V. Soboleva.

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Original Russian Text © L.V. Soboleva, 2008, published in Kristallografiya, 2008, Vol. 53, No. 3, pp. 555–561.

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Soboleva, L.V. Compositions of supersaturated solutions for enhanced growth of α-NiSO4 · 6H2O, Me 2Ni(SO4)2 · 6H2O, MeH2PO4 [Me = Li, Na, K, Rb, Cs, NH4], and K(H x D1−x )2PO4 single crystals. Crystallogr. Rep. 53, 519–525 (2008). https://doi.org/10.1134/S1063774508030231

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  • DOI: https://doi.org/10.1134/S1063774508030231

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