Abstract
The crystal structure of the nacrite mineral of the kaolin group (space group Cc; R = 2.76%; 634 unique reflections) is refined from the digital oblique-texture electron diffraction patterns obtained with the use of imaging plates. The maxima characterizing the locations and potentials of the hydrogen atoms of the hydroxyl groups are revealed from the difference Fourier-potential syntheses. The O-H interatomic distances and the angles of inclination of the O-H bond with respect to the ab plane are equal to 0.97 Å and −18.3° for the inner hydroxyl group and 0.92, 0.85, 0.93 Å and 60.8°, 67.8°, 58.4° for the outer hydroxyl groups, respectively. The Odonor-Oacceptor interatomic distances are 2.940, 2.949, and 3.121 Å. It is established that the electrostatic potential distributions of the hydrogen atoms of the inner hydroxyl group and one of the outer hydroxyl groups located in the vicinity of the symmetry pseudoplane m of the layer are characterized by anisotropy, which can indicate a statistical distribution of these hydrogen atoms.
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References
R. E. Newnhem, Mineral. Mag. J. Mineral. Soc. 32(252), 683 (1961).
B. B. Zvyagin, Kristallografiya 7(1), 51 (1962) [Sov. Phys. Crystallogr. 7 (1), 38 (1962)].
B. B. Zvyagin, Z. V. Vrublevskaya, A. P. Zhukhlistov, et al., High-Voltage Electron Diffraction in the Investigation of Layered Minerals (Nauka, Moscow, 1979) [in Russian].
B. B. Zvyagin and V. A. Drits, Clays Clay Miner. 44(3), 297 (1996).
B. B. Zvyagin, S. V. Soboleva, and A. F. Fedotov, Kristallografiya 17(3), 514 (1972) [Sov. Phys. Crystallogr. 17 (3), 448 (1972)].
A. M. Blount, I. M. Threadgold, and S. W. Bailey, Clays Clay Miner. 17(3), 185 (1969).
H. Zheng and S. W. Bailey, Clays Clay Miner. 42(1), 46 (1994).
S. I. Tsipurskiĭ and V. A. Drits, Izv. Akad. Nauk SSSR, Ser. Fiz. 41(11), 2263 (1977).
V. A. Drits, S. I. Tsipurskiĭ, and A. M. Plançon, Izv. Akad. Nauk SSSR, Ser. Fiz. 48(9), 1708 (1984).
A. Plançon, S. I. Tsipurski, and V. A. Drits, J. Appl. Crystallogr. 18, 191 (1985).
A. P. Zhukhlistov, A. S. Avilov, D. Ferraris, et al., Kristallografiya 42(5), 841 (1997) [Crystallogr. Rep. 42 (5), 774 (1997)].
A. P. Zhukhlistov, Kristallografiya 46(5), 805 (2001) [Crystallogr. Rep. 46 (5), 730 (2001)].
A. P. Zhukhlistov and B. B. Zvyagin, Kristallografiya 43(6), 1009 (1998) [Crystallogr. Rep. 43 (6), 950 (1998)].
A. P. Zhukhlistov, M. S. Nikolsky, B. B. Zvyagin, et al., Z. Kristallogr. 219, 224 (2004).
A. P. Zhukhlistov, Kristallografiya 50(6), 976 (2005) [Crystallogr. Rep. 50 (6), 902 (2005)].
B. B. Zvyagin and A. D. Shcheglov, Dokl. Akad. Nauk SSSR 142(1), 185 (1962).
B. B. Vainshtein, Structural Analysis by Electron Diffraction (SSSR Academy of Sciences, Moscow, 1956; Pergamon, Oxford, 1964).
V. I. Andrianov, Kristallografiya 32(1), 228 (1987) [Sov. Phys. Crystallogr. 32 (1), 130 (1987)].
V. Petricek and M. Dusek, The Crystallographic Computing System (Institute of Physics, Czech Republic, Prague, 2000).
B. K. Vainshtein, B. B. Zvyagin, and A. S. Avilov, Electron Diffraction Techniques (Oxford University Press, Oxford, 1992), Vol. 1, p. 216.
R. F. Giese, Rev. Mineral. 19, 29 (1988).
D. L. Bish and C. T. Johnston, Clays Clay Miner. 41(3), 297 (1993).
R. B. Neder, M. Burghammer, T. H. Grasl, et al., Clays Clay Miner. 47(4), 487 (1999).
D. L. Bish, Clays Clay Miner. 41(6), 738 (1993).
H. Sato, K. Ono, C. T. Johnston, et al., Am. Mineral. 89, 1581 (2004).
A. S. Bookin, V. A. Drits, A. Plançon, et al., Clays Clay Miner. 37(4), 297 (1989).
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Original Russian Text © A.P. Zhukhlistov, 2008, published in Kristallografiya, 2008, Vol. 53, No. 1, pp. 76–82.
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Zhukhlistov, A.P. Crystal structure of nacrite from the electron diffraction data. Crystallogr. Rep. 53, 76–82 (2008). https://doi.org/10.1134/S1063774508010094
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DOI: https://doi.org/10.1134/S1063774508010094