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Structural chemistry of peroxo compounds of group VI transition metals: II. Peroxo complexes of molybdenum and tungsten: A review

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Abstract

The specific features revealed in the structure of the molybdenum and tungsten peroxo complexes with the ratios M: O2 = 1: 1, 1: 2, and 1: 4 are considered. It is demonstrated that the geometry of the coordination polyhedron of the metal atom is primarily determined by the “metal: peroxo ligand” ratio. Formally, the pentagonal bipyramidal coordination polyhedra of the Mo(VI) and W(VI) oxo monoperoxo and oxo diperoxo complexes (the coordination numbers of the metal atoms are equal to seven) have different geometries, namely, the MO(O2)A 4 pseudooctahedral and MO(O2)2 A 2 pseudotrigonal bipyramidal configurations.

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References

  1. I. I. Vol’nov, Chromium, Molybdenum, and Tungsten Peroxo Complexes (Nauka, Moscow, 1989) [in Russian].

    Google Scholar 

  2. M. H. Dickman and M. T. Pope, Chem. Rev. 94(3), 569 (1994).

    Article  Google Scholar 

  3. V. S. Sergienko, Russ. J. Inorg. Chem. 48(Suppl. 1), 55 (2003).

    MathSciNet  Google Scholar 

  4. V. S. Sergienko, Kristallografiya 49(3), 467 (2004) [Crystallogr. Rep. 49 (3), 401 (2004)].

    Google Scholar 

  5. V. S. Sergienko, Kristallografiya 49(6), 1003 (2004) [Crystallogr. Rep. 49 (6), 907 (2004)].

    Google Scholar 

  6. V. S. Sergienko, Russ. J. Inorg. Chem. 49(Suppl. 1), 22 (2004).

    Google Scholar 

  7. V. S. Sergienko, Kristallografiya 51(4), 636 (2007) [Crystallogr. Rep. 51 (4), 639 (2007)].

    Google Scholar 

  8. F. H. Allen, Acta Crystallogr., Sect B: Struct. Sci. 58(2), 380 (2002).

    Article  Google Scholar 

  9. Inorganic Crystal Structure Database: Release 2003/2 (FIZ, Karlsruhe, Germany; NIST, Gaithersburg, Germany, 2003).

  10. D.-Y. Zhou, L.-B. Zhang, M. Minato, et al., Chem. Lett., No. 2, 187 (1998).

  11. R. K. Murmann and C. L. Barnes, Inorg. Chem. 40(25), 6514 (2001).

    Article  Google Scholar 

  12. R. Stomberg, J. Crystallogr. Spectrosc. Res. 18(6), 659 (1988).

    Article  Google Scholar 

  13. R. Stomberg, J. Alloys Compd. 186(2), 271 (1992).

    Article  Google Scholar 

  14. C. B. Shoemaker, D. R. Shoemaker, L. V. McAfee, and C. W. de Kock, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 41, 347 (1985).

    Article  Google Scholar 

  15. W. P. Griffith, A. M. Z. Slawin, K. M. Thompson, and D. J. Williams, J. Chem. Soc., Chem. Commun., No. 5, 569 (1994).

  16. F. P. Sensato, Q. B. Cass, E. Longo, et al., Inorg. Chem. 40(23), 6022 (2001).

    Article  Google Scholar 

  17. N. M. Gresley, W. P. Griffith, B. C. Parkin, et al., J. Chem. Soc., Dalton Trans., No. 10, 2039 (1996).

  18. J.-M. Le Carpentier, R. Schlupp, and R. Weiss, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 28(4), 1278 (1972).

    Article  Google Scholar 

  19. G. Amato, A. Arcoria, P. Ballistreri, and G. A. Tomaselli, J. Mol. Catal. 37(2–3), 165 (1986).

    Google Scholar 

  20. R. J. Cross, L. J. Farrugia, R. D. Newman, et al., J. Chem. Soc., Dalton Trans., No. 22, 4149 (1996).

  21. C. Djordjevic, N. Vuletic, B. A. Jacobs, et al., Inorg. Chem. 36(9), 1798 (1997).

    Article  Google Scholar 

  22. C. Djordjevic and N. Valetic, Inorg. Chim. Acta 104(1), L7 (1985).

    Article  Google Scholar 

  23. P. Martĭn-Zarza, P. Gili, F. V. Rodrguez-Romero, et al., Inorg. Chim. Acta 223(1–2), 173 (1994).

    Article  Google Scholar 

  24. G. Wahl, D. Kleinhenz, A. Schorm, et al., Chem.-Eur. J. 5, 3237 (1999).

    Article  Google Scholar 

  25. C. Anderson and S. C. Smith, Synlett, No. 2, 107 (1990).

  26. N. Burford, B. W. Royan, R. E. V. H. Spence, et al., J. Chem. Soc., Dalton Trans., No. 5, 1521 (1990).

  27. G.-B. Deacon and R. J. Phillips, Coord. Chem. Rev. 33, 227 (1980).

    Article  Google Scholar 

  28. P. Martín-Zarza, J. M. Arrieta, M. C. Muñoz-Roca, and P. Gili, J. Chem. Soc., Dalton Trans., No. 10, 1551 (1993).

  29. W. P. Griffith, B. C. Parkin, A. J. P. White, and D. J. Williams, J. Chem. Soc., Dalton Trans., No. 19, 3131 (1995).

  30. M. A. Pora-Koshits and L. O. Atovmyan, Koord. Khim. 1(9), 1271 (1975).

    Google Scholar 

  31. R. Stomberg, Acta Chem. Scand. 24(6), 2024 (1970).

    Article  Google Scholar 

  32. C. Djordjevic, K. J. Covert, and E. Sinn, Inorg. Chim. Acta, No. 1, L37 (1985).

  33. R. Stomberg and S. Olson, Acta Chem. Scand., Ser. A 39(2), 79 (1985).

    Article  Google Scholar 

  34. D. Begin, F. W. B. Einstein, and J. Field, Inorg. Chem. 14(8), 1785 (1975).

    Article  Google Scholar 

  35. A. C. Dengel, W. P. Griffith, R. D. Powell, and A. C. Skapski, J. Chem. Soc., Dalton Trans., No. 5, 991 (1987).

  36. O. Bortolini, S. Campestrini, F. Di Furia, et al., J. Org. Chem. 52(24), 5467 (1987).

    Article  Google Scholar 

  37. J. Flanagan, W. P. Griffith, A. C. Skapski, and R. W. Wigging, Inorg. Chim. Acta 96(1), L23 (1985).

    Article  Google Scholar 

  38. Yu. V. Kokunov, V. A. Bochkareva, and Yu. A. Buslaev, Koord. Khim. 7, 135 (1981).

    Google Scholar 

  39. W. Winter, C. Mark, and V. Schurig, Inorg. Chem. 19(7), 2045 (1980).

    Article  Google Scholar 

  40. J. Jacobus, Z. Majerski, K. Mislow, and P. Schleyer, J. Am. Chem. Soc. 91, 1998 (1969).

    Article  Google Scholar 

  41. W. R. Krigbaum, R.-J. Roe, and J. D. Woods, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 24, 1304 (1968).

    Article  Google Scholar 

  42. G. Adiwidjaja and J. Voss, Chem. Ber. 110, 1159 (1977).

    Article  Google Scholar 

  43. W. R. Thiel, T. Priermeier, and T. Bog, J. Chem. Soc., Chem. Commun., No. 18, 1871 (1995).

  44. R. Bandyopadhyay, S. Biswas, S. Guha, et al., Chem. Commun. (Cambridge, UK), No. 22, 1627 (1999).

    Google Scholar 

  45. E. O. Schlemper, G. N. Schrauzer, and L. A. Hughes, Polyhedron 3(3), 377 (1984).

    Article  Google Scholar 

  46. G. N. Schrauzer, L. A. Hughes, N. Strampach, et al., Organometallics 1(1), 44 (1982).

    Article  Google Scholar 

  47. R. Stomberg and I.-B. Ainalem, Acta Chem. Scand. 22(5), 1439 (1968).

    Article  Google Scholar 

  48. W. A. Herrmann, W. R. Thiel, J. G. Kuchler, et al., Chem. Ber. 123(10), 1963 (1990).

    Article  Google Scholar 

  49. W. R. Thiel and T. Priermeier, Angew. Chem., Int. Ed. Engl. 34, 1737 (1995).

    Article  Google Scholar 

  50. W. R. Thiel, M. Angstl, and T. Priermeier, Chem. Ber. 127(12), 2373 (1994).

    Article  Google Scholar 

  51. H. Glas, M. Spiegler, and R. Thiel, Eur. J. Inorg. Chem., No. 2, 275 (1998).

  52. P. Schreiber, K. Weighardt, B. Nuber, and J. Weiss, Polyhedron 8(13/14), 1675 (1989).

    Article  Google Scholar 

  53. P. Schreiber, K. Weighardt, B. Nuber, and J. Weiss, Z. Anorg. Allg. Chem. 587, 174 (1990).

    Article  Google Scholar 

  54. R. Stomberg, Acta Chem. Scand. 22(4), 1076 (1968).

    Article  Google Scholar 

  55. F. W. B. Einstein and B. R. Penfold, Acta Crystallogr. 17(9), 1127 (1964).

    Article  Google Scholar 

  56. C. Djordjevic, J. L. Gundersen, B. A. Jacobs, and E. Sinn, Polyhedron 8(4), 541 (1989).

    Article  Google Scholar 

  57. J.-M. Le Carpentier and A. Mitschler, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 28, 1288 (1972).

    Article  Google Scholar 

  58. R. Stomberg, J. Less-Common Met. 144, 109 (1988).

    Article  Google Scholar 

  59. R. Stomberg, J. Alloys Compd. 229, 227 (1995).

    Article  Google Scholar 

  60. S.-Y. Hou, Z.-H. Zhou, H.-L. Wan, and S.-W. Ng, Inorg. Chem. Commun. 6, 1246 (2003).

    Article  Google Scholar 

  61. M. Hasimoto, T. Ozeki, H. Ichida, et al., Chem. Lett., No. 9, 1873 (1987).

  62. A. C. Dengel, W. P. Griffith, R. D. Powell, and C. Skapski, J. Chem. Soc., Chem. Commun., No. 7, 555 (1986).

  63. L. Salles, C. Aubry, R. Thouvenot, et al., Inorg. Chem. 33(5), 871 (1994).

    Article  Google Scholar 

  64. J.-Y. Piquemal, C. Bois, and J.-M. Brégeault, Chem. Commun. (Cambridge, UK), No. 5, 473 (1997).

  65. N. M. Gresley, W. P. Griffith, A. J. P. White, and D. J. Williams, J. Chem. Soc., Dalton Trans., No. 1, 89 (1997).

  66. R. Stomberg and S. Olson, J. Alloys Compd. 237(1), 39 (1996).

    Article  Google Scholar 

  67. L. Trysberg and R. Stomberg, Acta Chem. Scand., Ser. A A35(10), 823 (1981).

    Article  Google Scholar 

  68. I. Persdotter, L. Trysberg, and R. Stomberg, Acta Chem. Scand., Ser. A 40(1), 83 (1986).

    Article  Google Scholar 

  69. A. C. Dengel, W. P. Griffith, and B. C. Parkin, J. Chem. Soc., Dalton Trans., p. 2683 (1993).

  70. C. Venturello, R. D’ Aloisio, J. C. J. Bart, and M. Ricci, J. Mol. Catal. 32, 107 (1985).

    Article  Google Scholar 

  71. L. Salles, C. Aubry, F. Robert, et al., New J. Chem. 17(5), 367 (1993).

    Google Scholar 

  72. R. Stomberg, Acta Chem. Scand., Ser. A 39(7), 507 (1985).

    Article  Google Scholar 

  73. I. Persdotter, L. Trysberg, and R. Stomberg, Acta Chem. Scand., Ser. A 40(1), 1 (1986).

    Article  Google Scholar 

  74. I. Persdotter, L. Trysberg, and R. Stomberg, Acta Chem. Scand., Ser. A 40(1), 83 (1986).

    Article  Google Scholar 

  75. J.-J. Piquemal, S. Halut, and J.-M. Bregeault, Angew. Chem., Int. Ed. Engl. 37, 1146 (1998).

    Article  Google Scholar 

  76. R. Stomberg, Acta Chem. Scand. 23(8), 2755 (1969).

    Article  Google Scholar 

  77. R. Stomberg, J. Less-Common Met. 143, 363 (1988).

    Article  Google Scholar 

  78. G. Mathern and R. Weiss, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 27(8), 1598 (1971).

    Article  Google Scholar 

  79. T.-J. Won, L. Barnes, O. Shlemper, and R. S. Thompson, Inorg. Chem. 34(17), 4499 (1995).

    Article  Google Scholar 

  80. R. Stomberg, Acta Chem. Scand. 17, 1563 (1963).

    Article  Google Scholar 

  81. J. Fisher, A. Veillard, and R. Weiss, Theor. Chim. Acta 24(4), 317 (1972).

    Article  Google Scholar 

  82. R. M. Wood, K. A. Abbond, R. C. Palenik, and G. J. Palenik, Inorg. Chem. 39(10), 2065 (2000).

    Article  Google Scholar 

  83. J. D. Swalen and J. A. Ibers, J. Chem. Phys. 37(1), 17 (1962).

    Article  ADS  Google Scholar 

  84. J. L. Hoard and J. V. Silverton, Inorg. Chem. 2(2), 235 (1963).

    Article  Google Scholar 

  85. M. V. Galakhov, P. Gomez-Sal, and T. Pedraz, J. Organomet. Chem. 579(1–2), 190 (1999).

    Article  Google Scholar 

  86. D. Chakraborty, M. Bhattacharjee, R. Kratzner, et al., Organometallics 18(1), 106 (1999).

    Article  Google Scholar 

  87. R. Legzdins, E. C. Phillips, J. Trotter, and V. C. Yee, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 51(12), 2498 (1995).

    Article  Google Scholar 

  88. R. Legzdins, E. C. Phillips, S. J. Rettig, et al., Organometallics 7, 1877 (1988).

    Article  Google Scholar 

  89. J. W. Faller and Y. Ma, Organometallics 7, 559 (1988).

    Article  Google Scholar 

  90. R. L. Roberts, H. Puschmann, J. A. K. Howard, et al., J. Chem. Soc., Dalton Trans., No. 6, 1099 (2003).

  91. C.-W. Shiu, C.-J. Su, C.-W. Pin, et al., J. Organomet. Chem. 545–546, 151 (1997).

    Article  Google Scholar 

  92. V. S. Sergienko, Zh. Neorg. Khim. 46(2), 244 (2001) [Russ. J. Inorg. Chem. 46 (2), 196 (2001)].

    Google Scholar 

  93. R. Stomberg, Acta Chem. Scand. 24(6), 2024 (1970).

    Article  Google Scholar 

  94. P. Schwendt, K. Volka, and M. Suchanek, Spectrochim. Acta, Part A 44(5), 839 (1998).

    Google Scholar 

  95. R. Stomberg and H. Szentivanyi, Acta Chem. Scand., Ser. A A28(2), 121 (1984).

    Article  Google Scholar 

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  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiĭ pr. 31, Moscow, 119991, Russia

    V. S. Sergienko

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Original Russian Text © V.S. Sergienko, 2008, published in Kristallografiya, 2008, Vol. 53, No. 1, pp. 22–49.

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Sergienko, V.S. Structural chemistry of peroxo compounds of group VI transition metals: II. Peroxo complexes of molybdenum and tungsten: A review. Crystallogr. Rep. 53, 18–46 (2008). https://doi.org/10.1134/S1063774508010045

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