Skip to main content
SpringerLink
Log in

Solubility phase diagrams of Me 2SO4-NiSO4-H2O systems and the growth of Me 2Ni(SO4)2 · nH2O crystals [Me = Na, Rb, Cs; n = 4, 6]

  • Crystal Growth
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

On the basis of the physicochemical analysis of the solubility phase diagrams for the Me 2SO4-NiSO4-H2O ternary systems (Me = Na, Rb, or Cs), the optimum concentration and temperature conditions for the crystallization of the Me 2Ni(SO4)2 · nH2O solid phases were found. Techniques for growth of single crystals of these binary salts have been developed. Such techniques allow application of mother liquors containing hydrates or anhydrous sulfates of Na, Rb, Cs, and Ni as raw materials. Na2Ni(SO4)2 · 4H2O, Rb2Ni(SO4)2 · 6H2O, and Cs2Ni(SO4)2 · 6H2O single crystals (28–34) × (8–13) × (5–10) mm3 in size have been grown from aqueous solutions in the dynamic regime.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H. Euler, B. Barbier, S. Klumpp, and A. Kirfel, Z. Kristallogr. E 215, 473 (2000).

    Google Scholar 

  2. E. N. Treushnikov, V. I. Kuskov, L. V. Soboleva, and N. V. Belov, Kristallografiya 23(10), 2414 (1978).

    Google Scholar 

  3. L. V. Soboleva and L. F. Kirpichnikova, Kristallografiya 46(2), 350 (2001) [Crystallogr. Rep. 46, 306 (2001)].

    Google Scholar 

  4. V. P. Blidin and T. A. Andreeva, Zh. Neorg. Khim. 3(10), 2414 (1958).

    Google Scholar 

  5. J. Koppel and H. Wetzel, Z. Phys. Chem. 52, 395 (1905).

    Google Scholar 

  6. A. Benrath, Z. Anorg. Allg. Chem. 208, 187 (1932).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskiĭ pr. 59, Moscow, 119333, Russia

    L. V. Soboleva

Authors
  1. L. V. Soboleva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. V. Soboleva.

Additional information

Original Russian Text © L.V. Soboleva, 2007, published in Kristallografiya, 2007, Vol. 52, No. 6, pp. 1141–1144.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Soboleva, L.V. Solubility phase diagrams of Me 2SO4-NiSO4-H2O systems and the growth of Me 2Ni(SO4)2 · nH2O crystals [Me = Na, Rb, Cs; n = 4, 6]. Crystallogr. Rep. 52, 1104–1107 (2007). https://doi.org/10.1134/S1063774507060284

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063774507060284

PACS numbers

Search

Navigation