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Crystal growth and properties of Rb2Ni(SO4)2 · 6H2O (RNSH)

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Abstract

Large single crystals of rubidium nickel hexahydrate Rb2Ni(SO4)2 · 6H2O (RNSH) of optical quality were grown for the first time. The atomic structure of RNSH crystals was refined. A comparative analysis of the crystal structures of (M 1+)2Ni(SO4)2 · 6H2O, where M 1+ is K, Rb, or Cs, was performed. The solubility curve of RNSH in water was measured. The optical and thermogravimetric properties of RNSH were investigated. The internal defect structure of RNSH crystals was studied by X-ray topography.

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Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskiĭ pr. 59, Moscow, 119333, Russia

    V. L. Manomenova, E. B. Rudneva, L. F. Malakhova, N. G. Furmanova & A. É. Voloshin

  2. Faculty of Chemistry, Moscow State University, Leninskie gory, Moscow, 119991, Russia

    T. N. Smirnova

Authors
  1. V. L. Manomenova
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  2. E. B. Rudneva
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  3. L. F. Malakhova
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  4. N. G. Furmanova
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  5. A. É. Voloshin
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  6. T. N. Smirnova
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Corresponding author

Correspondence to V. L. Manomenova.

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Original Russian Text © V.L. Manomenova, E.B. Rudneva, L.F. Malakhova, N.G. Furmanova, A.É. Voloshin, T.N. Smirnova, 2007, published in Kristallografiya, 2007, Vol. 52, No. 5, pp. 949–954.

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Manomenova, V.L., Rudneva, E.B., Malakhova, L.F. et al. Crystal growth and properties of Rb2Ni(SO4)2 · 6H2O (RNSH). Crystallogr. Rep. 52, 918–922 (2007). https://doi.org/10.1134/S1063774507050240

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  • DOI: https://doi.org/10.1134/S1063774507050240

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