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Synthesis and crystal structure of Li3.17(P0.69Ge0.24Mo0.07)O4

  • Structure of Inorganic Compounds
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Abstract

The crystal structure of Li3.17(P0.69Ge0.24Mo0.07)O4, which was synthesized by the flux method under the action of an electric field with a potential difference of 0.8 V, was studied by X-ray diffraction on a Nonius Kappa CCD diffractometer (MoK α radiation, λ = 0.71073 Å, R = 0.0137). The crystal structure is based on a tetrahedral framework typical of γ-Li3PO4. The framework of the new compound is formed by (P,Ge,Mo)O4 and LiO4 tetrahedra. The positions of additional Li atoms in the structure of Li3.17(P0.69Ge0.24Mo0.07)O4 are found to be different from those in the structure of Li3.31(P0.69Ge0.31)O4, which is synthesized in the absence of an electric field and also belongs to the γ-Li3PO4 structure type.

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Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskiĭ pr. 59, Moscow, 119333, Russia

    D. A. Ksenofontov, L. N. Dem’yanets & A. K. Ivanov-Shits

  2. Faculty of Geology, Moscow State University, Vorob’evy gory, Moscow, 119992, Russia

    N. V. Zubkova & D. Yu. Pushcharovsky

  3. Institute of Mineralogy and Crystallography, Geocenter, University of Vienna, Althanstrasse 14, A-1090, Vienna, Austria

    U. Kolitsch & E. Tillmanns

Authors
  1. D. A. Ksenofontov
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  2. N. V. Zubkova
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  3. D. Yu. Pushcharovsky
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  4. L. N. Dem’yanets
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  5. U. Kolitsch
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  6. E. Tillmanns
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  7. A. K. Ivanov-Shits
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Original Russian Text © D.A. Ksenofontov, N.V. Zubkova, D.Yu. Pushcharovsky, L.N. Dem’yanets, U. Kolitsch, E. Tillmanns, A.K. Ivanov-Shits, 2006, published in Kristallografiya, 2006, Vol. 51, No. 3, pp. 425–428.

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Ksenofontov, D.A., Zubkova, N.V., Pushcharovsky, D.Y. et al. Synthesis and crystal structure of Li3.17(P0.69Ge0.24Mo0.07)O4 . Crystallogr. Rep. 51, 391–394 (2006). https://doi.org/10.1134/S1063774506030059

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  • DOI: https://doi.org/10.1134/S1063774506030059

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