Abstract
Ecandrewsite-geikielite (Zn1/2Mg1/2TiO3), ecandrewsite-pyrophanite (Zn1/2Mn1/2TiO3), pyrophanite-geikielite (Mg1/2Mn1/2TiO3), and ecandrewsite-pyrophanite-geikielite (Zn1/3Mn1/3Mg1/3TiO3) titanates were synthesized at 900–1000°C at ambient pressure. All of the compounds adopt R— ilmenite-type structures. These structures were refined by the Rietveld method from X-ray powder diffraction data. Unit cell parameters and unit cell volumes decrease with decreasing average radii of the A 2+ cation. All structures consist of distorted AO 6 and TiO6 octahedra. In common with pyrophanite and ilmenite, the distortion of the AO 6 octahedra is less than that of the TiO6 octahedra. Data are given for the volumes and distortion indexes of all coordination polyhedra.
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Published in Russian in Kristallografiya, 2006, Vol. 51, No. 3, pp. 417–424.
The text was submitted by the authors in English.
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Liferovich, R.P., Mitchell, R.H. Mn, Mg, and Zn ilmenite group titanates: A reconnaissance rietveld study. Crystallogr. Rep. 51, 383–390 (2006). https://doi.org/10.1134/S1063774506030047
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DOI: https://doi.org/10.1134/S1063774506030047