Russian Microelectronics

, Volume 47, Issue 2, pp 112–117 | Cite as

Influence of Technological Modes on the Electrophysical Properties of Films of Polyacrylonitrile Doped with Metal Particles

  • T. A. Bednaya
  • S. P. Konovalenko


The electrophysical properties of the films of metal-containing polyacrylonitrile doped with Co, Cu, and Ag metals are investigated. The surface layers of the substrates are studied by the atomic force microscopy method. The thickness of the films of metal-containing polyacrylonitrile and the activation energy of the film conductivity are defined. It is revealed that the introduction of various doping elements with different concentrations makes it possible to obtain materials with different physical properties.


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  1. 1.
    Ibrahim, E.M.M., Hampel, S., Wolter, A.U.B., Kath, M., El-Gendy, A.A., Klingeler, R., Taschner, C., Khavrus, V.O., Gemming, T., Leonhardt, A., and Buchner, B., Superparamagnetic FeCo and FeNi nanocomposites dispersed in submicrometer-sized C spheres, J. Phys. Chem., 2012, vol. 116, pp. 22509–22517.Google Scholar
  2. 2.
    Turgut, Z., Scott, J.H., Huang, M.Q., Majetich, S.A., and McHenry, M.E., Magnetic properties and ordering in C-coated FexCo1–x alloy nanocrystals, J. Appl. Phys., 1998, vol. 83, no. 11, pp. 6468–6470.CrossRefGoogle Scholar
  3. 3.
    Petrov, V.V., Nikolaichuk, G.A., Yakovlev, S.V., and Lutsev, L.V., Study of radioabsorbing properties of materials based on nanostructures, Kompon. Tekhnol., 2008, no. 2, pp. 69–74.Google Scholar
  4. 4.
    McHenry, M.E. and Subramoney, S., in Fullerenes: Chemistry, Physics and Technology, New York: Wiley-Interscience, 2000, no. 6, p. 839.Google Scholar
  5. 5.
    Bednaya, T.A. and Konovalenko, S.P., Study of stability of gas sensors based cobalt polyacrylonitrile, Izv. YuFU, Tekh. Nauki, 2015, no. 8, pp. 166–174.Google Scholar
  6. 6.
    Zaporotskova, I.V., Kozhitov, L.V., Anikeev, N.A., Davletova, O.A., Muratov, D.G., Popkova, A.V., and Yakushko, E.V., Metal-carbon nanocomposites based on pyrolyzed polyacrylonitrile, Izv. Vyssh. Uchebn. Zaved., Mater. Elektron. Tekh., 2014, no. 2, pp. 34–36.Google Scholar
  7. 7.
    Muratov, D.G., Kozlov, V.V., Krapukhin, V.V., Kozhitov, L.V., Zemtsov, L.M., and Karpacheva, G.P., Studying of the electroconductivity and semiconductor properties of novel carbon material on the basis of polyacrylonitrile ((S3H3N)n) pyrolysed under action of IRradiation, Izv. Vyssh. Uchebn. Zaved., Mater. Elektron. Tekh., 2007, no. 3, p. 26.Google Scholar
  8. 8.
    Karpacheva, G.P., Bagdasarova, K.A., Bondarenko, G.N., Zemtsov, L.M., Muratov, D.G., and Perov, N.S., Cocarbon nanocomposites based on IR pyrolyzed polyacrylonitrile, Polym. Sci., 2009, vol. 51, nos. 11–12, pp. 1297–1302.Google Scholar
  9. 9.
    Kozitov, L.V., Kostikova, A.V., Kozlov, V.V., and Bulatov, M., The FeNi3/C nanocomposite formation from the composite of Fe and Ni salts and polyacrylonitrile under IR-heating, J. Nanoelectron. Optoelectron., 2012, no. 7, pp. 419–422.CrossRefGoogle Scholar
  10. 10.
    Nataraj, S.K., Yang, K.S., and Aminabhavi, T.M., Polyacrylonitrile based nanofibers, a state-of-the-art review, Prog. Polym. Sci., 2012, vol. 37, pp. 487–513.CrossRefGoogle Scholar
  11. 11.
    Al’-Khadrami, Korolev A.N., Zemtsov, L.M., Karpacheva, G.P., and Semenistaya, T.V., Study of electroconductivity of IR pyrolised copper polyacrylonitrile, Izv. Vyssh. Uchebn. Zaved., Mater. Elektron. Tekh., 2008, no. 1, pp. 16–19.Google Scholar
  12. 12.
    Muratov, D.G., Development of technology fundamentals for the production of carbon nanocrystalline material and metal-carbon nanocomposites based on polyacrylonitrile and metal salts (Cu, Fe, Co), Cand. Sci. (Tech. Sci.) Dissertation, Moscow, 2008.Google Scholar
  13. 13.
    Konovalenko, S.P. and Bednaya, T.A., Influence of the synthesis conditions on the physical properties of the cobalt-containing PAN thin films, Prikl. Fiz., 2017, no. 2, pp. 50–53.Google Scholar
  14. 14.
    Konovalenko, S.P. and Bednaya, T.A., Features selfcobalt gas-sensitive film of polyacrylonitrile, J. Nano-Electron. Phys., 2016, vol. 8, no. 4, pp. 04024-1–7.Google Scholar
  15. 15.
    Pochtennyi, A.E., Pryzhkovaya provodimost’ na postoyannom toke v sobstvennykh i primesnykh organicheskikh poluprovodnikakh (Hopping Conductivity on Direct Current in Intrinsic and Impurity Organic Semiconductors), Minsk: Belorus. Gos. Technol. Univ., 2016.Google Scholar

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© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  1. 1.Don State Technical UniversityTaganrog BranchTaganrog, Rostov-on-Don oblastRussia
  2. 2.Rostov State University of EconomicsChekhov InstituteTaganrog, Rostov-on-Don oblastRussia

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