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Analyzing the Symmetry of the Raman Spectra of Crystals According to Angular Dependences

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Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

The authors propose a way of reconstructing the Raman tensor by studying the angular dependences of the intensities of the Raman lines of unoriented microcrystals. The technique is verified using familiar calomel Hg2Cl2 crystals. It is shown that the lines on DUT-8 (Ni) crystals indicating phases with open and closed pores have different types of symmetries. The technique can be used to reconstruct the Raman tensor for any unoriented crystalline sample.

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REFERENCES

  1. Zhou, H.C., Long, J.R., and Yaghi, O.M., Chem. Rev., 2012, vol. 112, p. 673.

    Article  Google Scholar 

  2. Mingabudinova, L.R., Vinogradov, V.V., Milichko, V.A., et al., Chem. Soc. Rev., 2016, vol. 45, p. 5408.

    Article  Google Scholar 

  3. Zhestkij, N.A., Efimova, A.S., Kenzhebayeva, Y., et al., Adv. Opt. Mater., 2023, vol. 11, no. 22, p. 2300881.

    Article  Google Scholar 

  4. Kulachenkov, N.K., Orlioglo, B., Vasilyev, E.S., et al., Chem. Commun., 2023, vol. 59, p. 9964.

    Article  Google Scholar 

  5. Milichko, V.A., Makarov, S.V., Yulin, A.V., et al., Adv. Mater., 2017, vol. 29, no. 12, p. 1606034.

    Article  Google Scholar 

  6. Kulachenkov, N., Barsukova, M., Alekseevskiy, P., et al., Nano Lett., 2022, vol. 22, no. 17, p. 6972.

    Article  ADS  Google Scholar 

  7. Horike, S., Shimomura, S., and Kitagawa, S., Nat. Chem., 2009, vol. 1, no. 9, p. 695.

    Article  Google Scholar 

  8. Oreshonkov, A.S., Gerasimova, J.V., Ershov, A.A., et al., J. Raman Spectrosc., 2016, vol. 47, no. 5, p. 531.

    Article  ADS  Google Scholar 

  9. Pezzotti, G., J. Appl. Phys., 2011, vol. 110, no. 1, p. 013527.

    Article  ADS  Google Scholar 

  10. Munisso, M., Phys. Status Solidi B, 2009, vol. 246, no. 8, p. 1893.

    Article  ADS  Google Scholar 

  11. Fujii, Y., Ferroelectrics, 2014, vol. 462, p. 8.

    Article  ADS  Google Scholar 

  12. Krylov, A., Krylova, S., Gudim, I., et al., Magnetochemistry, 2022, vol. 8, p. 59.

    Article  Google Scholar 

  13. Chang, Y., Xiao, A., Li, R., et al., Crystals, 2021, vol. 11, p. 62.

    Article  Google Scholar 

  14. Sushchinskii, M.M., Kombinatsionnoe rasseyanie sveta i stroenie veshchestva (Combinational Scattering of Light and Material Structure), Moscow: Nauka, 1981.

  15. Poulet, H. and Mathieu, J.-P., Spectres de vibration et symetrie des cristaux, Paris: Gordon and Breach, 1970.

    Google Scholar 

  16. Munisso, M.C., Zhu, W., and Pezzoti, G., Phys. Status Solidi, 2009, vol. 246, no. 8, p. 1893.

    Article  Google Scholar 

  17. Born, M. and Wolf, E., Principles of Optics, Oxford: Pergamon, 1964.

    Google Scholar 

  18. Roginskii, E. M., Markov, Yu. F., and Lebedev, A.I., J. Exp. Theor. Phys., 2019, vol. 128, no. 5, p. 727.

    Article  Google Scholar 

  19. Loudon, R., Adv. Phys., 1964, vol. 13, p. 423.

    Article  ADS  Google Scholar 

  20. Markov, Yu.F., Roginskii, E.M., and Yurkov, A.S., Phys. Solid State, 2012, vol. 54, no. 6, p. 1212.

    Article  ADS  Google Scholar 

  21. Kaplyanskii, A.A., Theory of Light Scattering in Condensed Matter: Proc. First Joint USA–USSR Symp., 1976, ch. 4, p. 31.

  22. Damen, T.C., Porto, S.P.S., and Tell, B., Phys. Rev., 1966, vol. 142, p. 570.

    Article  ADS  Google Scholar 

  23. Markov, Yu.F. and Roginskii, E.M., Phys. Solid State, 2009, vol. 51, no. 2, p. 298.

    Article  ADS  Google Scholar 

  24. Barta, Ch., Kaplyanskii, A.A., and Markov, Yu.F., Phys. Solid State, 1973, vol. 15, no. 9, p. 2835.

    Google Scholar 

  25. Barta, Ch., Kaplyanskii, A.A., Kulakov, V.V., and Markov, Yu.F., Opt. Spektrosk., 1974, no. 37, p. 95.

  26. Klein, N., Herzog, C., Sabo, M., et al., Phys. Chem. Chem. Phys., 2010, vol. 12, p. 11778.

    Article  Google Scholar 

  27. Petkov, P., Bon, V., Hobday, C.L., et al., Phys. Chem. Chem. Phys., 2019, vol. 21, p. 674.

    Article  Google Scholar 

  28. Krylov, A., Vtyurin, A., Petkov, P., et al., Phys. Chem. Chem. Phys., 2017, vol. 19, p. 32099.

    Article  Google Scholar 

  29. Krylov, A., Yushina, I., Slyusareva, E., et al., Phys. Chem. Chem. Phys., 2022, vol. 24, p. 3788.

    Article  Google Scholar 

  30. Ehrling, S., Senkovska, I., Bon, V., et al., J. Mater. Chem. A, 2019, vol. 7, p. 21459.

    Article  Google Scholar 

  31. Krylov, A., Senkovska, I., Ehrling, S., et al., Chem. Commun., 2020, vol. 56, p. 8269.

    Article  Google Scholar 

  32. Gribanov, D.A., Rudakova, E.V., and Zavialova, E.G., Bull. Russ. Acad. Sci. Ser.: Phys., 2023, vol. 87, no. 2, p. 165.

    Article  Google Scholar 

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ACKNOWLEDGMENTS

The authors are grateful to Dr. Irena Senkovska for providing our DUT-8(Ni) samples. The experiments were performed at the shared resource center of the Russian Academy of Sciences’ Krasnoyarsk Scientific Center.

Funding

This work was supported by the Russian Foundation for Basic Research, project no. 21-52-12018.

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Authors and Affiliations

  1. Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia

    E. V. Golovkina, S. N. Krylova, A. N. Vtyurin & A. S. Krylov

  2. Siberian Federal University, 660041, Krasnoyarsk, Russia

    A. N. Vtyurin

Authors
  1. E. V. Golovkina
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  2. S. N. Krylova
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  3. A. N. Vtyurin
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  4. A. S. Krylov
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Corresponding author

Correspondence to A. S. Krylov.

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The authors of this work declare that they have no conflicts of interest.

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Translated by E. Bondareva

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Golovkina, E.V., Krylova, S.N., Vtyurin, A.N. et al. Analyzing the Symmetry of the Raman Spectra of Crystals According to Angular Dependences. Bull. Russ. Acad. Sci. Phys. 88, 773–778 (2024). https://doi.org/10.1134/S1062873824706573

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  • DOI: https://doi.org/10.1134/S1062873824706573

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