Abstract
Transformations of polycrystalline La0.5Sr0.5FeO3 – γ ferrites subjected to vacuum annealing in the temperature range of 400–650°C were studied by Raman spectroscopy at ambient conditions. It was shown that the homogeneity of the sample and its local ordering depended on the vacuum annealing temperature. An increase in the vacuum annealing temperature resulted in a gradual loss of oxygen and a transition of all iron ions to the oxidation state Fe3+. These ferrites demonstrated a shift of the whole Raman spectra (including two-magnon modes) to higher frequencies with increasing Sr content of 0 < x < 0.5. The possible reasons for the observed effects are discussed.
REFERENCES
Shaula, A., Pivak, Y., Waerenborgh, J., Gaczynski, P., Yaremchenko, A., and Kharton, V., Solid State Ionics, 2006, vol. 177, p. 2923.
Patrakeev, M.V., Bahteeva, J.A., Mitberg, E.B., Leonidov, I.A., Kozhevnikov, V.L., and Poeppelmeier, K.R., J. Solid State Chem., 2003, vol. 172, p. 219.
Shin, Y., Doh, K.-Y., Kim, S.H., Lee, J.H., Bae, H., Song, S.-J., and Lee, D., J. Mater. Chem. A, 2020, vol. 8, p. 4784.
Wei, Z.-X., Xu, Y.-Q., Liu, H.-Y., and Hu, C.-W., J. Hazard. Mater., 2009, vol. 165, p. 1056.
Tijare, S.N., Joshi, M.V., Padole, P.S., Mangrulkar, P.A., Rayalu, S.S., and Labhsetwar, N.K., Int. J. Hydrogen Energy, 2012, vol. 37, p. 10451.
Goodenough, J.B., Magnetism and the Chemical Bond, New York: Wiley, 1963, vol. 1.
Boekema, C., Jonker, P.C., Filoti, G., van der Woude, F., and Sawatzky, G.A., Hyperfine Interact., 1979, vol. 7, p. 45.
Schmidt, M. and Campbell, S.J., J. Solid State Chem., 2001, vol. 156, p. 292.
Sedykh, V.D., Rybchenko, O.G., Nekrasov, A.N., Koneva, I.E., and Kulakov, V.I., Phys. Solid State, 2019, vol. 61, p. 1099.
Sedykh, V., Rybchenko, O., Rusakov, V., Zaitsev, S., Barkalov, O., Postnova, E., Gubaidulina, T., Pchelina, D., and Kulakov, V., J. Phys. Chem. Solids, 2022, vol. 171, p. 111001.
Sedykh, V., Rusakov, V., Rybchenko, O., Gapochka, A., Gavrilicheva, K., Barkalov, O., Zaitsev, S., and Kulakov, V., Ceram. Int., 2023, vol. 49, p. 25640.
Barkalov, O.I., Zaitsev, S.V., and Sedykh, V.D., Solid State Commun., 2022, vol. 354, p. 114912.
Weber, M.C., Guennou, M., Zhao, H.J., Íñiguez, J., Vilarinho, R., Almeida, A., Moreira, J.A., and Kreisel, J., Phys. Rev. B, 2016, vol. 94, p. 214103.
Anokhin, A.S., Razumnaya, A.G., Torgashev, V.I., Trotsenko, V.G., Yuzyuk, Yu.I., Bush, A.A., Shkuratov, V.Ya., Gorshunov, B.P., Zhukova, E.S., Kadyrov, L.S., and Komandin, G.A., Phys. Solid State, 2013, vol. 55, p. 1417.
Andreasson, J., Holmlund, J., Knee, C.S., Käll, M., Börjesson, L., Naler, S., Bäckström, J., Rübhausen, M., Azad, A.K., and Eriksson, S.-G., Phys. Rev. B, 2007, vol. 75, p. 104302.
Manzoor, S., Husain, S., and V. Raghavendra Reddy, Appl. Phys. Lett., 2018, vol. 113, p. 072901.
Dann, S.E., Currie, D.B., Weller, M.T., Thomas, M.F., and Al-Rawwas, A.D., J. Solid State Chem., 1994, vol. 109, p. 134.
Yang, J.B., Yelon, W.B., James, W.J., Chu, Z., Kornecki, M., Xie, Y.X., Zhou, X.D., Anderson, H.U., Joshi, A.G., and Malik, S.K., Phys. Rev. B, 2002, vol. 66, p. 184415.
Selbach, S.M., Tolchard, J.R., Fossdal, A., and Grande, T., J. Solid State Chem., 2012, vol. 196, p. 249.
Sedykh, V.D., Rybchenko, O.G., Barkovsky, N.V., Ivanov, A.I., and Kulakov, V., Fiz. Tverd. Tela, 2021, vol. 63, p. 1648.
Auckett, J.E., Studer, A.J., Sharma, N., and Ling, C.D., Solid State Ionics, 2012, vol. 225, p. 432.
ACKNOWLEDGMENTS
The authors wish to acknowledge using the micro-Raman optical system of the Research Facility Center in the Osipyan Institute of Solid State Physics, Russian Academy of Sciences, for the data acquisition.
Funding
This work was carried out within the framework of the state task of the Osipyan Institute of Solid State Physics, Russian Academy of Sciences.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Additional information
Publisher’s Note.
Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
About this article
Cite this article
Gavrilicheva, K.A., Barkalov, O.I. & Sedykh, V.D. La0.5Sr0.5FeO3 – γ Ferrite Studied by Raman Spectroscopy. Bull. Russ. Acad. Sci. Phys. 87 (Suppl 1), S36–S40 (2023). https://doi.org/10.1134/S1062873823704373
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1062873823704373