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Effect of Nanosized Oxides on Structural and Dynamic Properties of Composites Based on LiClO4

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Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

Structural and dynamic properties of the composites based on lithium perchlorate LiClO4 at various temperatures, phase states, and concentrations of the inert fillers SiO2 and Al2O3 were studied by Raman scattering (RS) and differential thermal analysis (DTA). It was shown that an amorphous phase formed in the (1 – х)LiClO4 + xSiO2 and (1 – х)LiClO4 + xAl2O3 composites (for x ≥ 0.4), its thermal effect was recorded at 200°С. In the Raman spectrum of the heterogeneous system, in the frequency range corresponding to totally symmetric vibration of the perchlorate anion, an additional component with a Raman maximum at \(\nu _{1}^{{\text{c}}}\) ∼ 954 cm–1, which could be attributed to an amorphous phase, was also revealed. While the filler concentration increased, the values of enthalpies of phase transitions decreased monotonically, and at x = 0.8, both spectral and thermophysical manifestations of phase transitions completely disappeared. Doping of lithium perchlorate with silicon and aluminum oxides led to an increase in ionic conductivity. The maximum values of conductivity were observed for the 0.4LiClO4 + 0.6SiO2 and 0.5LiClO4 + 0.5Al2O3 composites.

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Funding

This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.

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Authors and Affiliations

  1. Analytical Center for Collective Use, Institute of Physics, Dagestan Federal Research Center, Russian Academy of Sciences, 367015, Makhachkala, Russia

    Z. Yu. Kubataev, M. M. Gafurov, K. Sh. Rabadanov & A. M. Amirov

Authors
  1. Z. Yu. Kubataev
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  2. M. M. Gafurov
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  3. K. Sh. Rabadanov
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  4. A. M. Amirov
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Correspondence to Z. Yu. Kubataev.

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Kubataev, Z.Y., Gafurov, M.M., Rabadanov, K.S. et al. Effect of Nanosized Oxides on Structural and Dynamic Properties of Composites Based on LiClO4. Bull. Russ. Acad. Sci. Phys. 87 (Suppl 1), S21–S28 (2023). https://doi.org/10.1134/S1062873823704361

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