Abstract
The test of gold-bearing humic substances aimed to find forms of gold in them. The test results enable estimation of gold compound mobility during sedimentation of humic acids. Re-sedimentation of humic acids shows similar properties of gold after dissolving with and without a selective dissolver. The amino-acid analysis of humic acids before and after their interaction with ammonium hydroxide reveals the increased content of amino acids capable to dissolve gold. Stage-wise spin of gold-bearing liquid humic acids at acceleration from 4000g to 233000g and at pH of 11 nullifies gold-bearing particles in solutions and makes the latter homogenous. The authors describe the impact of destructive effects relative to organic compounds on joint sedimentation of gold and humic acids.
REFERENCES
Gordeev, D.V., Petrov, G.V., Khasanov, A.V., and Severinova, O.V., Overview of Current Technologies for Processing Rebellious Gold Ore and Concentrates Using Nitric Acid, Izv. TPU. Inzhiniring georesursov, 2022, vol. 333, no. 1, pp. 214–223.
Asamoah. R.K., Amankwah, R.K., and Addai-Mensah, J., Cyanidation of Refractory Gold Ores: A Review, Proc. of the 3rd UMaT Biennial International Mining and Mineral Conference, 2014.
Arens, V.Zh., About the Term Geotechnology, GIAB, 1998, no. 3, pp. 98–101.
Owusu, C., Mensah, S., Ackah, K., and Amankwah, R.K., Reducing Preg-Robbing in Carbonaceous Gold Ores Using Passivative or Blanking Agents, Min. Eng., 2021, no. 170, 106990, pp. 1–7.
Sitando, O., Senanayake, G., Dai, X., and Breuer, P., The Adsorption of Gold(I) on Minerals and Activated Carbon (Preg-Robbing) in Non-Ammoniacal Thiosulfate Solutions–Effect of Calcium Thiosulfate, Silver(I), Copper(I) and Polythionate Ions, Hydrometallurgy, 2019, no. 184, pp. 206–217.
Rees, K.L. and Van Deventer, J.S.J., Preg-Robbing Phenomena in the Cyanidation of Sulphide Gold Ores, Hydrometallurgy, 2000, no. 58, pp. 61–80.
Schmitz, P.A., Duyvesteyn, S., Johnson, W.P., Enloe, L., and McMullen, J., Ammoniacal Thiosulfate and Sodium Cyanide Leaching of Preg-Robbing Goldstrike Ore Carbonaceous Matter, Hydrometallurgy, 2001, no. 60, pp. 25–40.
Asamoah, R.K., Skinner, W., and Addai-Mensah, J., Alkaline Cyanide Leaching of Refractory Gold Flotation Concentrates and Bio-Oxidised Products: The Effect of Process Variables, Hydrometallurgy, 2018, no. 179, pp. 79–93.
Song, Q., Liu, M., Lu, J., Liao, Y., Chen, L., and Yang, J., Adsorption and Desorption Characteristics of Vanadium (V) on Coexisting Humic Acid and Silica, Water Air Soil Pollut., 2020, no. 460, pp. 1–10.
Khutsishvili, S.S., Tikhonov, N.I., Pavlov, D.V., Vakul’skaya, T.I., Penzik, M.V., Kozlov, A.N., Lesnichaya, M.V., Aleksandrova, G.P., and Sukhov, B.G., Gold- and Silver-Containing Bionanocomposites Based on Humic Substances Extracted from Coals, J. Thermal Analysis and Calorimetry, 2019, vol. 137, no. 4, pp. 1181–1188.
Arbuzov, S.I., Rikhvanov, L.P., Maslov, S.G., Arkhipov, V.S., and Pavlov, Z.I., Anomalous Gold Concentrations in Lignite and Peat in the Southeastern Part of the West Siberian Plate, Izv. TPU, 2004, vol. 307, no. 7, pp. 25–30.
Kuimova, N.G., Pavlova, L.M, Sorokin, A.P, Noskova, L.P., and Sergeeva, A.G., Experimental Modeling of Gold Concentration Processes in Peats, Litosfera, 2011, no. 4, pp. 131–136.
Avramenko, V.A, Bratskaya, S.Yu., Yakushevich, A.S, Voyt, A.V., Ivanov, V.V., and Ivannikov, S.I., Humic Acids of Brown Coals from the South of the Russian Far East: General Characteristics and Interaction with Precious Metals, Geokhimiya, 2012, no. 5, pp. 483–493.
Bratskaya, S.Yu., Volk, V.A., Ivanov, V.V., Ustinov, A.Yu., Barinov, N.N., and Avramenko, V.A., A New Approach to Precious Metals Recovery from Brown Coals: Correlation of Recovery Efficacy with the Mechanism of Metal-Humic Interactions, Geochim. Cosmochim. Acta, 2009, vol. 73, pp. 3301–3310.
Volk, A.S., Bratskaya, S.Yu., Ivanov, V.V., Ustinov, A.Yu., Barinov, N.N., and Avramenko, V.A., New Approaches to Recovering Gold from Alkaline Extracts of Brown Coals in the South of the Russian Far East, Mining Informational and Analytical Bulletin—GIAB, 2009, no. 4, pp. 275–284.
Kizil’shtein, L.Ya., The Role of Organic Matter in the Formation of Gold Deposits—A Case-Study of Black Shales), Priroda, 2017, no. 10, pp. 63–65.
Mustafin, S.K., Carlin-Type Gold Mineralization Potential of the SCO Countries: State of Knowledge, Forecast, Assessment and Prospects. Geodynamics and Minerageny of North and Central Asia, Proc. of the 5th All-Russian Sci. Pract. Conf. Honor the 45th Anniversary of Geological Institute of SB RAS, Ulan-Ude: BGU, 2018.
Shumilova, L.V., Influence of Dispersed Gold Forms in Mineral and Organic Substances on Ore Refractoriness, Mining Informational and Analytical Bulletin—GIAB, 2009, no. 6, pp. 184–193.
Nenakhov, V.M., Zolotareva, A.A., and Dubkov, G.S., Black Shales of the Sukhoi Log Type and Their Noble Metal Potential: Current State of Knowledge, Technological Realities and Prospects, Vestn. VGU. Geologiya, 2021, no.1, pp. 53–64.
Xu, B., Yang, Y., Li, Q., Jiang, T., Zhang, X., and Li, G., Effect of Common Associated Sulfide Minerals on Thiosulfate Leaching of Gold and the Role of Humic Acid Additive, Hydrometallurgy, 2017, vol. 171, pp. 44–52.
Semenova, S.A., Areas of Using Brown Coal Ozonizing Products, Vestn. KGTU, 2017, no. 2, pp. 144–152.
Palyanova, G.A., Gold and Silver Minerals in Sulfide Ore. Geology of Ore Deposits, Pleiades Publishing, 2020, vol. 62, no. 5, pp. 383–406.
Jampa, S.S., Kumar, A.P. Unnarkat, R.V., Pandian, S., Sinha, M.K., and Dharaskar, S., Adsorption and Recyclability Aspects of Humic Acid Using Nano-ZIF-8 Adsorbent, Environ. Technol. Innov., 2020, no. 19 (100927).
Vijesh, A.M., Arathi Krishnan, P.V., Isloor, A.M., and Shyma, P.C., Fabrication of PPSU/PANI Hollow Fiber Membranes for Humic Acid Removal, Proc. Materials Today, 2020, pp. 1–8.
Konadu, K.T., Mendoza, D.M., Huddy, R.J., Harrison, S.T.L., Kaneta, T., and Sasaki, K., Biological Pretreatment of Carbonaceous Matter in Double Refractory Gold Ores: A Review and Some Future Considerations, Hydrometallurgy, 2020, vol. 196 (105434), pp. 1–12.
Zashikhin, A.V. and Sviridova, M.L., Gold Leaching with Humic Substances, Journal of Mining Science, 2019, vol. 55, no. 4, pp. 652–657.
Avramenko, V.A., Bratskaya, S.A., Volk, A.S., Kaplun, E.V., Ivanov, V.V., and Sergienko, V.I., RF patent no. RU2380434C1, Byull. Izobret., 2010, no. 3.
Semenova, S.A., Patrakov, Yu.F., and Batina, M.V., Ozonizing Humic Acids of Brown Coal Oxidized in a Seam, Khimiya tverdogo topliva, 2008, no. 5, pp. 8–14.
Mullakaev, R.M. and Mullakaev, M.S., Ultrasound in Treatment of Oil-Polluted Effluents: A Review, Ekologiya Promyshl. Rossii, 2021, vol. 25, no.3, pp. 53–59.
Agranat, B.A., Osnovy fiziki i tekhniki ultrazvuka (Fundamentals of Physics and Technology of Ultrasound), Moscow: Vysshaya shkola, 1987.
Koshelev, A.V., Golovkov, V.F., Bogoyavlenskaya, Yu.S., Eleev, Yu.A., and Lobanov, A.V., Ultrasound Technology for Producing Humic Preparations, Khimiya Tekhnol. Organ. Vesh., 2020, no. 1, pp. 52–61.
Baklanov, A.N., Avdeenko, A.P., Evgrafova, N.I., and Chmilenko, F.A., Ultrasonic Disintegration of Metal Complexes with Organic Substances Contained in Mineralized Waters, Brines and Common Salt Solutions, Zhurn. Analit. Khimii, 2007, vol. 62, no. 6, pp. 575–582.
Makarovskaya, Yu.N., Eksperiandova, L.P., and Blank, A.B., Sampling of Natural Water Using the Ultrasonic and Ultraviolet Decomposition of Humic Substances, J. Analytical Chem., 2003, vol. 58, no. 2, pp. 110–113.
Archegova, I.B., Changes in Humus Compositions in Some Soil Samples after their Freezing, Pochvovedenie, 1984, no. 8, pp. 63–70.
Lishtvan, I.I., Brovka, G.P., Dudarchik, V.M., Kraiko, V.M., and Yanuta, Yu.G., Physicochemical and Thermophysical Foundations for the Rational Use and Deep Processing of Natural Dispersed Materials, Prirodopol’zovanie, 2020, no. 1, pp. 122–131.
Orlov, D.S., Gumusovye kisloty pochvy (Humic Acids of Soil), Moscow, 1974.
Dudkin, D.V., and Fedyaeva, I.M., Low-Waste Technology for Producing Humic Substance Solutions from Peat of Different Botanical Composition and Degree of Decomposition, Khimiya Rast. Syrya, 2018, no. 2, pp. 175–182.
Dement’eva, O.V., Rumyantseva, T.B., Rudoy, V.M., and Roldugin, V.I., Aggregative Stability of “Citrate” Gold Hydrosol: Ozone Effect, Kolloidnyi zhurnal, 2011, vol. 73, no. 5, pp. 664–671.
Mineev, G.G. and Mineeva, T.S., Biometallurgical Processes of Gold Recovery from Substandard Raw Materials, Izv. Vuzov. Prikladnaya khimiya i biotekhnologiya, 2011, no. 1, pp. 96–102.
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Translated from Fiziko-Tekhnicheskie Problemy Razrabotki Poleznykh Iskopaemykh, 2023, No. 2, pp. 144-152. https://doi.org/10.15372/FTPRPI20230214.
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Zashikhin, A.V., Suvorova, O.N. Properties of Gold-Bearing Humic Acids. J Min Sci 59, 311–319 (2023). https://doi.org/10.1134/S106273912302014X
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DOI: https://doi.org/10.1134/S106273912302014X