Abstract
Food quality and safety oversight now urgently require the identification of similar food samples. Using infant rice cereals as an example, this study collected the Raman spectra of samples from various brands and used a statistical control chart method to reveal that samples from the same brand have controllable quality fluctuations. Additionally, samples from different brands also fall within the control limit, indicating a high degree of similarity between the samples. Under conditions of raw data, the extreme learning machine algorithm and Raman spectroscopy for sample identification demonstrated a recognition rate of 77.6%, suggesting that the machine learning algorithm has some identification effect. After optimizing the conditions, it was found that the recognition accuracy was significantly improved, reaching 99.9%, based on coif3 wavelet denoising and 0~0.1 normalization processing. During the experiment, it took 100 seconds to collect the Raman spectrum signal of a single sample and running the intelligent algorithm only took less than one second to obtain the calculation results. The optimization and identification methods proposed in this work have the advantages of efficiency and accuracy, which can provide a reference for the identification of similar samples.
Similar content being viewed by others
REFERENCES
Han, Y., Liu, J., Li, J., Jiang, Z., Ma, B., Chu, C., and Geng, Z., Sci. Total Environ., 2023, vol. 877, p. 162730.
Zhou, Y., Yu, Y., Huang, Q., Zheng, H., Zhan, R., Chen, L., and Meng, X., ACS Omega, 2023, vol. 8, no. 13, p. 12404.
Jin, W., Zhang, Z., Zhao, S., Liu, J., Gao, R., and Jiang, P., Food Res. Int., 2023, vol. 169, p. 112879.
Ma, Q., Zhang, Q., Li, X., Gao, Y., Wei, C., Li, H., and Jiao, H., J. Chromatogr. A, 2022, vol. 1674, p. 463134.
Zhang, Z., Li, S., Sha, M., and Liu, J., J. Appl. Spectrosc., 2021, vol. 87, no. 6, p. 1206.
Jeong, S., Kwon, D., Lim, J., Jang, H., Kim, J., and Chung, H., Food Res. Int., 2023, vol. 174, p. 113492.
Zhang, Z., Liu, J., and Wang, H., Anal. Lett., 2015, vol. 48, no. 12, p. 1930.
An, H., Zhai, C., Zhang, F., Ma, Q., Sun, J., Tang, Y., and Wang, W., Food Chem., 2023, vol. 405, p. 134821.
Zhang, Z., Sha, M., and Wang, H., J. Raman Spectrosc., 2017, vol. 48, no. 8, p. 1111.
Vali Zade, S., Forooghi, E., Jannat, B., Hashempourbaltork, F., and Abdollahi, H., Chemom. Intell. Lab. Syst., 2023, vol. 240, p. 104903.
Wang, Z., Liu, J., Zeng, C., Bao, C., Li, Z., Zhang, D., and Zhen, F., Infrared Phys. Technol., 2023, vol. 129, p. 104563.
Zhao, Y., Yamaguchi, Y., Liu, C., Li, M., and Dou, X., Spectrochim. Acta, Part A, 2019, vol. 216, p. 202.
Kniese, J., Race, A.M., and Schmidt, H., J. Cereal Sci., 2021, vol. 101, p. 103299.
Zhu, L., Sun, J., Wu, G., Wang, Y., Zhang, H., Wang, L., Qian, H., and Qi, X., J. Cereal Sci., 2018, vol. 82, p. 175.
Song, S., Wang, Q., Zou, X., Li, Z., Ma, Z., Jiang, D., Fu, Y., and Liu, Q., Spectrochim. Acta, Part A, 2023, vol. 303, p. 123176.
Liu, W., Sun, S., Liu, Y., Deng, H., Hong, F., Liu, C., and Zheng, L., Spectrochim. Acta, Part A, 2023, vol. 299, p. 122806.
Wang, Y. and Tan, F., Vib. Spectrosc., 2021, vol. 114, p. 103249.
Tian, F., Tan, F., and Li, H., Vib. Spectrosc., 2020, vol. 107, p. 103017.
Zhang, Z., Gui, D., Sha, M., Liu, J., and Wang, H., J. Dairy Sci., 2019, vol. 102, no. 1, p. 68.
Wang, W., Shi, B., He, C., Wu, S., Zhu, L., Jiang, J., Wang, L., Lin, L., Ye, J., and Zhang, H., Spectrochim. Acta, Part A, 2023, vol. 288, p. 122163.
Munir, T., Hu, X., Kauppila, O., and Bergquist, B., Comput. Ind. Eng., 2023, vol. 175, p. 108900.
Montgomery, D.C., Introduction to Statistical Quality Control, Hoboken: Wiley, 2013.
Zhang, Z., Jiang, M., and Xiong, H., New J. Chem., 2023, vol. 47, no. 14, p. 6889.
Xia, Y., Yi, W., and Zhang, D., Eng. Appl. Artif. Intell., 2022, vol. 114, p. 105100.
Xiao, D., Li, H., and Sun, X., ACS Omega, 2020, vol. 5, no. 40, p. 25772.
Zhang, Z., Shi, X., Zhao, Y., Zhang, Y., and Wang, H., J. Anal. Chem., 2022, vol. 77, no. 10, p. 1282.
Ji, J., Huang, Y., Pi, M., Zhao, H., Peng, Z., Li, C., Wang, Q., Zhang, Y., Wang, Y., and Zheng, C., Infrared Phys. Technol., 2022, vol. 127, p. 104469.
Zhang, Z., RSC Adv., 2020, vol. 10, no. 50, p. 29682.
Lazic, V., Fantoni, R., Falzone, S., Gioia, C., and Loreti, E.M., Spectrochim. Acta, Part B, 2020, vol. 168, p. 105853.
Grelet, C., Fernández Pierna, J.A., Dardenne, P., Baeten, V., and Dehareng, F., J. Dairy Sci., 2015, vol. 98, no. 4, p. 2150.
Funding
This research was financially supported by the Excellent Young Backbone Teachers of “Blue Project” in Jiangsu Universities in 2021, the Industry University Research Collaboration Foundation of Jiangsu Province (BY2022611), Zhejiang Provincial Natural Science Foundation of China (LQ20C200004), Fundamental Research Funds for the Provincial Universities of Zhejiang from the Zhejiang Gongshang University (QRK23020), and the National Natural Science Foundation of China (61602217, 22304158, 62376249, 91746202).
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
The authors of this work declare that they have no conflicts of interest.
Additional information
Publisher’s Note.
Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Zhao, YJ., Zhang, ZY., Zhang, YS. et al. Identification of Infant Rice Cereal Based by Raman Spectroscopy Combined with an Extreme Learning Machine Algorithm. J Anal Chem 79, 447–455 (2024). https://doi.org/10.1134/S1061934824040154
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061934824040154