Skip to main content
SpringerLink
Log in

Detection of Monosodium Glutamate by Lanthanide-oxybis(benzoate) Coordination Polymers

  • ARTICLES
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

A series of lanthanide coordination polymers, i.e., [LnIII4(oba)6(H2O)9]·3H2O, where LnIII corresponded to EuIII (I), GdIII (II), TbIII (III), H2oba—4,4'-oxybis(benzoic acid), were synthesized using the rapid and facile microwave technique. They were structurally characterized and evaluated for use as photoluminescent probes in monosodium glutamate (MSG) detection. Possible interferences of amino acids were examined. Based on the devised ratiometric parameters, I showed viable responses to MSG. Linear calibration plot could be constructed over 10–100 mM with sensitivity, limits of detection and quantification of 33.2% mM, 1.3, and 4 mM, respectively. The constructed calibration plot could be used to determine concentrations of standard MSG solutions providing the percentage recoveries of 94–103%. The use of I for real soup samples was also attempted through the standard spiking approach.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.

Similar content being viewed by others

REFERENCES

  1. Wang, W., Zhou, X., and Liu, Y., TrAC, Trends Anal. Chem., 2020, vol. 127, p. 115876.

    Article  CAS  Google Scholar 

  2. Wahlstedt, A., Bradley, E., Castillo, J., and Burt, K.G., J. Acad. Nutr. Diet., 2022, vol. 122, no. 1, p. 25.

    Article  PubMed  Google Scholar 

  3. Walker, R. and Lupien, J.R., J. Nutr., 2000, vol. 130, no. 4, p. 1049S.

    Article  CAS  PubMed  Google Scholar 

  4. EFSA Panel on Food additives and Nutrient Sources added to Food (ANS), EFSA J., 2015, vol. 13, no. 1, p. 3981.

  5. EFSA Panel on Food additives and Nutrient Sources added to Food (ANS), Mortensen, A., Aguilar, F., Crebelli, R., Di Domenico, A., Dusemund, B., Frutos, M.J., Galtier, P., Gott, D., Gundert-Remy, U., Leblanc, J.-C., Lindtner, O., Moldeus, P., Mosesso, P., Parent-Massin, D., Oskarsson, A., Stankovic, I., Waalkens-Berendsen, I., Woutersen, R.A., Wright, M., Younes, M., Boon, P., Chrysafidis, D., Gürtler, R., Tobback, P., Altieri, A., Rincon, A.M., and Lambré, C., EFSA J., 2017, vol. 15, no. 7, p. e04910.

  6. Lewis, R.J., SAX’s Dangerous Properties of Industrial Materials, Hoboken, NJ: Wiley, 2004, 11th ed.

    Book  Google Scholar 

  7. Henry-Unaeze, H.N., Pathophysiology, 2017, vol. 24, no. 4, p. 243.

    Article  CAS  PubMed  Google Scholar 

  8. Insawang, T., Selmi, C., Cha’on, U., Pethlert, S., Yongvanit, P., Areejitranusorn, P., Boonsiri, P., Khampitak, T., Tangrassameeprasert, R., Pinitsoontorn, C., Prasongwattana, V., Gershwin, M.E., and Hammock, B.D., Nutr. Metab., 2012, vol. 9, no. 1, p. 50.

    Article  CAS  Google Scholar 

  9. Bölükbaş, F. and Öznurlu, Y., Environ. Sci. Pollut. Res., 2022, vol. 29, no. 30, p. 45338.

    Article  Google Scholar 

  10. Bawaskar, H.S., Bawaskar, P.H., and Bawaskar, P.H., Indian J. Crit. Care Med., 2017, vol. 21, no. 1, p. 49.

    Article  PubMed  PubMed Central  Google Scholar 

  11. Hernández Bautista, R.J., Mahmoud, A.M., Königsberg, M., and López Díaz Guerrero, N.E., Biomed. Pharmacother., 2019, vol. 111, p. 503.

    Article  PubMed  Google Scholar 

  12. El Tabbal, J., Regul. Toxicol. Pharm., 2022, vol. 133, p. 105223.

    Article  CAS  Google Scholar 

  13. Banerjee, A., Mukherjee, S., and Maji, B.K., Toxicol. Rep., 2021, vol. 8, p. 938.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  14. Ali, H.M., Hammad, S.F., and El-Malla, S.F., Microchem. J., 2021, vol. 169, p. 106622.

    Article  CAS  Google Scholar 

  15. Acebal, C.C., Lista, A.G., and Fernández Band, B.S., Food Chem., 2008, vol. 106, no. 2, p. 811.

    Article  CAS  Google Scholar 

  16. Croitoru, M., Fülöp, I., Ajtay, M., Dudutz, G., Crăciun, O., and Dogaru, M., Acta Aliment., 2010, vol. 39, no. 2, p. 239.

    Article  CAS  Google Scholar 

  17. Jiao, Z.-H., Jiang, X.-L., Hou, S.-L., Tang, M.-H., and Zhao, B., Inorg. Chem., 2020, vol. 59, no. 4, p. 2171.

    Article  CAS  PubMed  Google Scholar 

  18. Ma, S., Gao, L., Zhang, Y., Zhang, J., and Hu, T., J. Solid State Chem., 2022, vol. 306, p. 122718.

    Article  CAS  Google Scholar 

  19. Zhang, Y., Li, Y., and Zhang, L., Spectrochim. Acta, Part A, 2021, vol. 259, p. 119892.

    Article  CAS  Google Scholar 

  20. Latva, M., Takalo, H., Mukkala, V.-M., Matachescu, C., Rodríguez-Ubis, J.C., and Kankare, J., J. Lumin., 1997, vol. 75, no. 2, p. 149.

    Article  CAS  Google Scholar 

  21. Einkauf, J.D., Clark, J.M., Paulive, A., Tanner, G.P., and de Lill, D.T., Inorg. Chem., 2017, vol. 56, no. 10, p. 5544.

    Article  CAS  PubMed  Google Scholar 

  22. Moore, E.G., Samuel, A.P.S., and Raymond, K.N., Acc. Chem. Res., 2009, vol. 42, no. 4, p. 542.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  23. Meshkova, S.B., Kuz’min, V.E., Shapiro, Y.E., Topilova, Z.M., Yudanova, I.V., Bol’shoi, D.V., and Antonovich, V.P., J. Anal. Chem., 2000, vol. 55, no. 2, p. 102.

    Article  CAS  Google Scholar 

  24. Hasegawa, Y. and Kitagawa, Y., J. Photochem. Photobiol., C, 2022, vol. 51, p. 100485.

    Article  CAS  Google Scholar 

  25. Skripinets, Y.V., Egorova, A.V., Ukrainets, I.V., and Antonovich, V.P., J. Anal. Chem., 2006, vol. 61, no. 1, p. 44.

    Article  CAS  Google Scholar 

  26. Egorova, A.V., Anelchyk, A.V., Leonenko, I.I., Skripinets, Y.V., and Antonovich, V.P., J. Anal. Chem., 2015, vol. 70, no. 4, p. 440.

    Article  CAS  Google Scholar 

  27. Yang, D., Tian, Y., Xu, W., Cao, X., Zheng, S., Ju, Q., Huang, W., and Fang, Z., Inorg. Chem., 2017, vol. 56, no. 4, p. 2345.

    Article  CAS  PubMed  Google Scholar 

  28. Mahmood, T., Saddique, M.T., Naeem, A., Westerhoff, P., Mustafa, S., and Alum, A., Ind. Eng. Chem. Res., 2011, vol. 50, no. 14, p. 10017.

    Article  CAS  Google Scholar 

  29. Strasser, A. and Vogler, A., Inorg. Chim. Acta, 2004, vol. 357, no. 8, p. 2345.

    Article  CAS  Google Scholar 

  30. Wei, Z., Gu, Z.-Y., Arvapally, R.K., Chen, Y.-P., McDougald, R.N., Ivy, J.F., Jr., Yakovenko, A.A., Feng, D., Omary, M.A., and Zhou, H.-C., J. Am. Chem. Soc., 2014, vol. 136, no. 23, p. 8269.

    Article  CAS  PubMed  Google Scholar 

  31. Wu, A., Gao, Y., and Zheng, L., Green Chem., 2019, vol. 21, no. 16, p. 4290.

    Article  CAS  Google Scholar 

  32. Phan, P.T., Hong, J., Tran, N., and Le, T.H., Nanomaterials, 2023, vol. 13, no. 2, p. 352.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  33. Massart, D.L., Dijkstra, A., and Kaufman, L., in Techniques and Instrumentation in Analytical Chemistry, Massart, D.L., Dijkstra, A., and Kaufman, L., Eds., Amsterdam: Elsevier, 1978, vol. 1, ch. 6, p. 143.

    Google Scholar 

  34. Armbruster, D.A. and Pry, T., Clin. Biochem. Rev., 2008, vol. 29, no. 1, p. S49.

    PubMed  PubMed Central  Google Scholar 

  35. Shrivastava, A. and Gupta, V., Chron. Young Sci., 2011, vol. 2, no. 1, p. 21.

    Article  Google Scholar 

  36. Jinap, S., Hajeb, P., Karim, R., Norliana, S., Yibadatihan, S., and Abdul-Kadir, R., Food Nutr. Res., 2016, vol. 60, p. 30463.

    Article  PubMed  Google Scholar 

  37. Maluly, H.D.B., Arisseto-Bragotto, A.P., and Reyes, F.G.R., Food Sci. Nutr., 2017, vol. 5, no. 6, p. 1039.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  38. Miyaki, T., Retiveau-Krogmann, A., Byrnes, E., and Takehana, S., J. Food Sci., 2016, vol. 81, no. 2, p. S483.

    Article  CAS  PubMed  Google Scholar 

  39. Bodman, S.E. and Butler, S.J., Chem. Sci., 2021, vol. 12, no. 8, p. 2716.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  40. Weitz, E.A., Chang, J.Y., Rosenfield, A.H., and Pierre, V.C., J. Am. Chem. Soc., 2012, vol. 134, no. 39, p. 16099.

    Article  CAS  PubMed  Google Scholar 

  41. Rossini, E.L., Milani, M.I., and Pezza, H.R., Talanta, 2019, vol. 201, p. 503.

    Article  CAS  PubMed  Google Scholar 

  42. Official Journal of the European Communities, L 257, September 16 1983, 1983, p. 1.

Download references

Funding

Chiang Mai University is acknowledged for the research funding and the Presidential Scholarship to T. Chuasaard (Postdoctoral Fellowship). P. Tapangpan thanks to the Science Achievement Scholarship of Thailand (SAST) for graduate scholarship.

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Chiang Mai University, 50200, Chiang Mai, Thailand

    Thammanoon Chuasaard, Pimchanok Tapangpan, Kate Grudpan & Apinpus Rujiwatra

  2. Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, 50200, Chiang Mai, Thailand

    Athipong Ngamjarurojana

  3. Materials Science Research Center, Faculty of Science, Chiang Mai University, 50200, Chiang Mai, Thailand

    Apinpus Rujiwatra

Authors
  1. Thammanoon Chuasaard
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Pimchanok Tapangpan
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Athipong Ngamjarurojana
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Kate Grudpan
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Apinpus Rujiwatra
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Apinpus Rujiwatra.

Ethics declarations

The authors declare that they have no conflicts of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chuasaard, T., Tapangpan, P., Ngamjarurojana, A. et al. Detection of Monosodium Glutamate by Lanthanide-oxybis(benzoate) Coordination Polymers. J Anal Chem 78, 1389–1397 (2023). https://doi.org/10.1134/S1061934823100064

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934823100064

Keywords:

Search

Navigation