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Facile Preparation of Magnetic Graphene Oxide and its Application in Magnetic Dispersive Solid-Phase Extraction of Insecticides from Vegetable Samples

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Abstract

In this work, magnetic graphene oxide nanoparticles were successfully synthesized by a mechanochemical approach and used as an effective sorbent in magnetic dispersive solid phase extraction of insecticides from vegetable samples followed by high-performance liquid chromatography coupled with UV-Vis detection. Imidacloprid (IMI) and chlorpyrifos (CP) were selected as model insecticides to validate the extraction performance of the obtained nanoparticles. The synthesized magnetic graphene oxide nanoparticles were characterized. Various factors which could affect the recovery were investigated and optimized. Under the optimum conditions, the calibration curves were linear in the ranges of 0.002–5 and 0.004–10 µg/mL for IMI and CP, respectively. Also, the limits of detection for IMI and CP were 1.5 and 4 μg/L, and the limits of quantitation were 5 and 11 μg/L, respectively. The linearity (R > 0.999) and precision (between 3.3 and 6.7%) were good. Notably, the developed method could be used to determine and monitor IMI and CP residues in Chinese cabbage, shiitake, and needle mushroom samples with satisfactory recoveries.

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REFERENCES

  1. Rafique, N., Tariq, S.R., and Ahmed, D., Environ. Monit. Assess., 2016, vol. 188, no. 12, p. 695.

    Article  Google Scholar 

  2. Ma., G. and Chen, L., Food Anal. Methods, 2014, vol. 7, no. 2, p. 377.

  3. Yagüe, C., Bayarri, S., Conchello, P., Lázaro, R., Pérez-Arquillué, C., Herrera, A., and Ariño, A., J. Agric. Food Chem., 2005, vol. 53, no. 13, p. 5105.

    Article  Google Scholar 

  4. Pietrzak, D., Wątor, K., Pękała, D., Wójcik, J., Chochorek, A., Kmiecik, E., and Kania, J., J. Environ. Sci. Health, Part B, 2019, vol. 57, no. 5, p. 424.

    Article  Google Scholar 

  5. Vichapong, J., Burakham, R., and Srijaranai, S., Food Anal. Methods, 2016, vol. 9, no. 2, p. 419.

    Article  Google Scholar 

  6. Hoisang, W., Nacapricha, D., Wilairat, P., and Tiyapongpattana, W., J. Sep. Sci., 2019, vol. 42, no. 11, p. 2032.

    Article  CAS  Google Scholar 

  7. Li, N., Chen, J., and Shi, Y.P., Anal. Chim. Acta, 2017, vol. 949, no. 1, p. 23.

    Article  CAS  Google Scholar 

  8. Zhang, S. and Jiang, J.Q., Biointerface Res. Appl. Chem., 2019, vol. 9, no. 5, p. 4433.

    CAS  Google Scholar 

  9. Omer, S.A. and Fakhre, N.A., J. Anal. Methods Chem., 2020, vol. 2020, no. 2, p. 1.

    Article  Google Scholar 

  10. Khalilian, F. and Rezaee, M., Food Anal. Methods, 2017, vol. 10, no. 4, p. 885.

    Article  Google Scholar 

  11. Ghiasi, A., Malekpour, A., and Mahpishanian, S., Talanta, 2020, vol. 217, no. 1, 121120.

    Article  CAS  Google Scholar 

  12. Rezk, M.R., Abd El-Aleem, A.E.A.B., Khalile, S.M., and El-Naggar, O.K., J. AOAC Int., 2017, vol. 101, no. 2, p. 587.

    Article  Google Scholar 

  13. Concha-Meyer, A., Grandon, S., Sepúlveda, G., Diaz, R., Yuri, J.A., and Torres, C., Food Chem., 2019, vol. 295, no. 15, p. 64.

    Article  CAS  Google Scholar 

  14. Gao, N., Guo, X., Zhang, K., and Hu, D., Instrum. Sci. Technol., 2014, vol. 42, no. 3, p. 267.

    Article  CAS  Google Scholar 

  15. Al-Hadithi, N., Kössler, P., and Karlovsky, P., Toxins (Basel), 2015, vol. 7, no. 8, p. 3000.

    Article  CAS  Google Scholar 

  16. Zhang, X., Zhang, J., Li, W., Yang, Y., Qin, P., Zhang, X., and Lu, M., Food Addit. Contam., Part A, 2018, vol. 35, no. 11, p. 2099.

    CAS  Google Scholar 

  17. Sha, O., Cui, B., Chen, X., Liu, H., Yao, J., and Zhu, Y., J. Anal. Methods Chem., 2020, vol. 2020. .https://doi.org/10.1155/2020/7359582

  18. Zang, X., Chang, Q., Liang, W., Wang, C., and Wang, Z., Spectrosc. Lett., 2017, vol. 50, no. 9, p. 507.

    Article  CAS  Google Scholar 

  19. Mohammadnia, M., Heydari, R., and Sohrabi, M.R., J. Environ. Sci. Health, Part B, 2020, vol. 55, no. 4, p. 293.

    Article  CAS  Google Scholar 

  20. Nazari, N., Masrournia, M., Es′haghi, Z., and Bozorgmehr, M., J. Sep. Sci., 2016, vol. 39, no. 15, p. 3046.

    Article  CAS  Google Scholar 

  21. Narayanaswamy, V., Obaidat, I.M., Kamzin, A.S., Latiyan, S., Jain, S., Kumar, H., and Issa, B., Int. J. Mol. Sci., 2019, vol. 20, no. 13, p. 3368.

    Article  CAS  Google Scholar 

  22. Tu, C., Guo, Y., Dai, Y., Wei, W., Wang, W., Wu, L., and Wang, A., J. Food Sci., 2019, vol. 84, no. 12, p. 3624.

    Article  CAS  Google Scholar 

  23. Mei, K.C., Guo, Y., Bai, J., Costa, P.M., Kafa, H., Protti, A., and Al-Jamal, K.T., ACS Appl. Mater. Interfaces, 2015, vol. 7, no. 26, p. 14176.

    Article  CAS  Google Scholar 

  24. Li, Y., Zimmerman, A.R., He, F., Chen, J., Han, L., Chen, H., and Gao, B., Sci. Total Environ., 2020, vol. 722, 137972.

    Article  CAS  Google Scholar 

  25. Rahmawati, R., Permana, M.G., Harison, B., Yuliarto, B., and Kurniadi, D., Proc. Eng., 2017, vol. 170, p. 55.

    Article  CAS  Google Scholar 

  26. Hummers Jr, W.S. and Offeman, R.E., J. Am. Chem. Soc., 1958, vol. 80, no. 6, p. 1339.

    Article  CAS  Google Scholar 

  27. Wang, Y., Wen, Y., and Ling, Y., Food Anal. Methods, 2017, vol. 10, no. 1, p. 210.

    Article  Google Scholar 

  28. Tavakoli, M., Hajimahmoodi, M., Shemirani, F., Dezfuli, A.S., and Khanavi, M., Chromatographia, 2017, vol. 80, no. 9, p. 1423.

    Article  CAS  Google Scholar 

  29. Niu, M., Li, Z., He, W., Zhou, W., Lu, R., Li, J., Gao, H., Zhang, S., and Pan, C., Food Chem., 2020, vol. 317, 126425.

    Article  CAS  Google Scholar 

  30. Shahrebabak, S.M., Saber-Tehrani, M., Faraji, M., Shabanian, M., and Aberoomand-Azar, P., Microchem. J., 2019, vol. 146, p. 630.

    Article  Google Scholar 

  31. Nodeh, H.R., Kamboh, M.A., Ibrahim, W.A.W., Jume, B.H., Sereshti, H., and Sanagi, M.M., Environ. Sci.: Processes Impacts, 2019, vol. 21, no. 4, p. 714.

    CAS  Google Scholar 

  32. Paramasivam, M., Chandrasekaran, S., Naik, R.H., Karthik, P., Thangachamy, P., and Mahalingam, C.A., J. Liq. Chromatogr. Relat. Technol., 2014, vol. 37, no. 1, p. 122.

    Article  CAS  Google Scholar 

  33. Sanagi, M.M., Salleh, S., Ibrahim, W.A.W., Naim, A.A., Hermawan, D., Miskam, M., Hussain, I., and Aboul-Enein, H.Y., J. Food Compos. Anal., 2013, vol. 32, no. 2, p. 155.

    Article  CAS  Google Scholar 

  34. Huang, X.C., Ma, J.K., Feng, R.X., and Wei, S.L., J. Sci. Food Agric., 2019, vol. 99, no. 15, p. 6998.

    Article  CAS  Google Scholar 

  35. Zhang, C., Wu, Y.J., Jin, S.F., and Yang, H., Anal. Methods, 2013, vol. 5, p. 3089.

    Article  CAS  Google Scholar 

  36. Harshit, D., Charmy, K., and Nrupesh, P., Food Chem., 2017, vol. 230, p. 448.

    Article  CAS  Google Scholar 

  37. Jovanov, P., Guzsvány, V., Lazić, S., Franko, M., Sakač, M., Šarić, L., and Kos, J., J. Food Compos. Anal., 2015, vol. 40, p. 106.

    Article  CAS  Google Scholar 

  38. Abidin, N.H.Z., Ibrahim, W.N.W., and Hanapi, N.S.M., Indones. J. Chem., 2020, vol. 20, n. 4, p. 729.

    Article  CAS  Google Scholar 

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Funding

This study was supported by the postgraduate research and practice innovation program of Jiangsu Province (SJCX20_1234; SJCX20_1224), the project of the science and technology projects of Lianyungang Hi-Tech industrial development zone (ZD201925, HZ201903), the project of the marine science and technology innovation program of Jiangsu Province (HY2018-10).

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Authors and Affiliations

  1. School of Environment and Chemical Engineering, Jiangsu Ocean University, 222005, Lianyungang, PR China

    Ou Sha & Hua Liu

  2. School of Pharmacy, Jiangsu Ocean University, 222005, Lianyungang, PR China

    Jiawei Yao, Yuqing Zhu & Quan Zhou

  3. Analysis and Test Center of Jiangsu Marine Resources Development Research Institute, 222005, Lianyungang, Jiangsu, PR China

    Li Chen

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  1. Ou Sha
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  2. Jiawei Yao
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  3. Yuqing Zhu
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  4. Hua Liu
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Correspondence to Ou Sha.

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Sha, O., Yao, J., Zhu, Y. et al. Facile Preparation of Magnetic Graphene Oxide and its Application in Magnetic Dispersive Solid-Phase Extraction of Insecticides from Vegetable Samples. J Anal Chem 77, 748–758 (2022). https://doi.org/10.1134/S1061934822060120

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  • DOI: https://doi.org/10.1134/S1061934822060120

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