Abstract
We recorded and interpreted DART mass spectra of Hoveyda–Grubbs catalysts with N→Ru and S→Ru coordination bonds. The set of ions formed under DART ionization conditions is similar to those obtained using matrix-assisted laser desorption/ionization mass spectrometry. The optimal conditions (ionization gas, gas flow temperature) for recording DART mass spectra of the studied compounds were determined.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Ogba, O.M., Warner, N.C., O’Leary, D.J., et al., Chem. Soc. Rev., 2018, vol. 47, no. 12, p. 4510.
Chen, Y., Abdellatif, M.M., and Nomura, K., Tetrahedron, 2018, vol. 74, no. 6, p. 619.
Sabino, A.A., Machado, A.H.L., Correia, C.R.D., et al., Angew. Chem., Int. Ed. Engl., 2004, vol. 43, no. 19, p. 2514.
Chrader, W.S., Handayani, P., Zhou, J., et al., Angew. Chem., Int. Ed. Engl., 2009, vol. 48, no. 8, p. 1463.
Wang, H.-Y., Yim, W.-L., Guo, Y.-L., et al., Organometallics, 2012, vol. 31, no. 5, p. 1627.
Oberacher, H., Pitterl, F., Erb, R., and Plattner, S., Mass Spectrom. Rev., 2015, vol. 34, no. 1, p. 64.
Iacobucci, C., Reale, S., and De Angelis, F., Angew. Chem., Int. Ed. Engl., 2016, vol. 55, no. 9, p. 2980.
Ma, X., Zhang, S., and Zhang, X., TrAC, Trends Anal. Chem., 2012, vol. 35, p. 50.
Espy, R.D., Wleklinski, M.X., Yan, R.G., et al., TrAC, Trends Anal. Chem., 2012, vol. 57, p. 135.
Jiang, J., Zhao, D., Zhang, H., et al., Anal. Methods, 2017, vol. 9, no. 28, p. 4201.
Sparrapan, R., Eberlin, L.S., Haddad, R., et al., J. Mass Spectrom., 2006, vol. 41, no. 9, p. 1242.
O’Leary, A.E., Hall, S.E., Vircks, K.E., et al., Anal. Methods, 2015, vol. 7, p. 7156.
Marquez, C.A., Wang, H.Y., Fabbretti, F., et al., J. Am. Chem. Soc., 2008, vol. 130, no. 51, p. 17208.
Liu, W., Wang, N., Lin, X., et al., Anal. Chem., 2014, vol. 86, no. 14, p. 7128.
Zhang, J.T., Wang, H.Y., Zhu, W., et al., Anal. Chem., 2014, vol. 86, no. 18, p. 8937.
Mazzotta, M.G., Young, J.O.E., Evans, J.W., et al., Anal. Chem., 2015, vol. 7, no. 9, p. 4003.
Polyanskii, K.B., Alekseeva, K.A., Raspertov, P.V., et al., Beilstein J. Org. Chem., 2019, vol. 15, p. 769.
Polyanskii, K.B., Alekseeva, K.A., Kumandin, P.A., et al., Acta Crystallogr., Sect. E: Crystallogr. Commun., 2019, vol. 75, no. 3, p. 342.
ACKNOWLEDGMENTS
The work was carried out using the equipment of the Center for Collective Use of the RUDN University and the Center for Collective Use “Analytical Center for the Problems of Deep Refining of Oil and Petrochemistry” of the Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences.
Funding
This work was supported by the Russian Science Foundation, project no. 18-13-00456.
Author information
Authors and Affiliations
Contributions
All authors contributed to the work equally.
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Additional information
Translated by O. Zhukova
ADDITIONAL INFORMATION
Sergey Vladimirovich Goryainov, ORCID 0000-0002-7625-9110.
Cesar Esparza, ORCID 0000-0002-8200-6208.
Larisa Nikolaevna Kulikova, ORCID 0000-0001-5111-8111.
Alexandra Romanovna Borisova, ORCID 0000-0001-9599-2230.
Yekaterina Olegovna Rystsova, ORCID 0000-0002-0516-6056.
Rights and permissions
About this article
Cite this article
Goryainov, S.V., Esparza, C., Kulikova, L.N. et al. DART Mass Spectrometry in the Analysis of Organometallic Complexes. J Anal Chem 76, 1520–1524 (2021). https://doi.org/10.1134/S1061934821130049
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061934821130049