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Utilizing a Nanocomposite Based on Ion-Imprinted Polydopamine-Coated Magnetic Graphene Oxide for Extraction of Cd(II) and Ni(II) from Water Samples

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Abstract

In this study, a new magnetic ion-imprinted polymer was prepared as a nanosorbent for selective extraction and pre-concentration of low levels of Cd(II) and Ni(II) prior to determination by flame atomic absorption spectrometry. The sorbent material consists of graphene oxide as a carrier, Fe3O4 nanoparticles as magnetic components immobilized on the surface of the carrier and polydopamine as a metal ion-imprinted polymer which is uniformly coated on the surface of the magnetic graphene oxide sheet layer. Several factors affecting the extraction of the analytes were studied and optimized. In the optimum conditions, the calibration graphs were linear in the ranges of 0.1–18 and 0.1–20 ng/mL for Cd(II) and Ni(II), respectively. The limits of detection (3sb/m) for Cd(II) and Ni(II) were 25 and 60 pg/mL, respectively. The accuracy of the method was confirmed by successful analyzing the certified reference material NIST SRM 1643e. The method can be used for the pre-concentration and determination of Ni(II) and Cd(II) in water samples.

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Funding

This work was supported by the research council of Azarbaijan Shahid Madani University (Grant no. ASMU/96372-17).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, Azarbaijan Shahid Madani University, P.O. Box 53714-161, Tabriz, Iran

    Hossein Abdolmohammad-Zadeh & Yavar Pasandideh

  2. Pharmaceutical Analysis Research Center and Faculty of Pharmacy, University of Tabriz, Tabriz, Iran

    Elaheh Rahimpour

Authors
  1. Hossein Abdolmohammad-Zadeh
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  2. Elaheh Rahimpour
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  3. Yavar Pasandideh
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Correspondence to Hossein Abdolmohammad-Zadeh.

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Hossein Abdolmohammad-Zadeh, Rahimpour, E. & Pasandideh, Y. Utilizing a Nanocomposite Based on Ion-Imprinted Polydopamine-Coated Magnetic Graphene Oxide for Extraction of Cd(II) and Ni(II) from Water Samples. J Anal Chem 75, 967–974 (2020). https://doi.org/10.1134/S106193482008002X

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  • DOI: https://doi.org/10.1134/S106193482008002X

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