Skip to main content
SpringerLink
Log in

UV Spectroscopic Determination of Aloin in Aloe vera (A. vera) Samples Based on Chemometric Data Processing

  • ARTICLES
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

A simple method was developed for determining aloin in A. vera samples by UV–visible spectroscopy with the study of the results of measurements by principal component analysis (PCA), which showed the separation of samples in the PC space depending on their manufacturer. The spectra of model binary (aloin–malic acid) and ternary (aloin–malic acid–citric acid) systems and the spectra of A. vera samples were decomposed using the mutual information least dependent component analysis (MILCA) algorithm based on the minimization of numerical values of mutual information. A good correlation is observed for model mixtures between the predicted and actual concentrations of aloin in the samples under study (n = 3, r = 0.986). The spectra of the model systems, that is, A. vera samples with a known concentration of aloin, and the spectra of A. vera samples artificially contaminated relative to the initial samples were used as calibration systems for the decomposition of the spectra of A. vera samples by independent component analysis. It was demonstrated that UV spectroscopy in combination with corresponding chemometric data processing enables the quantitative determination of aloin in plant samples of A. vera.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. Baruah, A., Bordoloi, M., and Deka Baruah, H.P., Ind. Crops Prod., 2016, vol. 94, p. 951. https://doi.org/10.1016/J.INDCROP.2016.08.034

    Article  CAS  Google Scholar 

  2. Gao, Y., Kuok, K.I., Jin, Y., and Wang, R., Crit. Rev. Food. Sci. Nutr., 2019, vol. 59, no. 1, p. 244. https://doi.org/10.1080/10408398.2018.1496320

    Article  CAS  Google Scholar 

  3. Guo, X. and Mei, N., J. Environ. Sci. Health, Part C: Environ. Carcinog. Ecotoxicol. Rev., 2016, vol. 34, p. 77. https://doi.org/10.1080/10590501.2016.1166826

    Article  CAS  Google Scholar 

  4. Pandey, A. and Singh, S., Int. J. Pharm. Res. Allied Sci., 2016, vol. 5, no. 1, p. 21.

    CAS  Google Scholar 

  5. Rodríguez, E.R., Martín, J.D., and Romero, C.D., Crit. Rev. Food. Sci. Nutr., 2010, vol. 50, p. 305. https://doi.org/10.1080/10408390802544454

    Article  CAS  Google Scholar 

  6. Sahu, P.K., Giri, D., Singh, R., Pandey, P., Gupta, S., Shrivastava, A., Kumar, A., and Pandey, K., Pharmacol. Pharm., 2013, vol. 4, p. 599. https://doi.org/10.4236/pp.2013.48086

    Article  CAS  Google Scholar 

  7. Aloes: The Genus Aloe, Reynolds, T., Ed., Boca Raton, FL: CRC, 2004.

    Google Scholar 

  8. Ray, A., Gupta, S.D., and Ghosh, S., Ind. Crops Prod., 2013, vol. 49, p. 712. https://doi.org/10.1016/J.INDCROP.2013.06.008

    Article  CAS  Google Scholar 

  9. Harlev, E., Nevo, E., Lansky, E., Ofir, R., and Bishayee, A., Planta Med., 2012, vol. 78, p. 843. https://doi.org/10.1055/s-0031-1298453

    Article  CAS  PubMed  Google Scholar 

  10. International Aloe Science Council. www.iasc.org. Accessed January 29, 2020.

  11. Ramírez-Durón, R., Ceniceros-Almaguer, L., Cavazos-Rocha, N.C., Silva-Flores, P.G., and de Torres, N.W., J. AOAC Int., 2008, vol. 91, no. 6, p. 1265.

    Article  Google Scholar 

  12. Brown, P.N., Yu, R., Kuan, C.H., Kuan, C.H., Finley, J., Mudge, E.M., and Dentali, S., J. AOAC Int., 2014, vol. 97, p. 1323. https://doi.org/10.5740/jaoacint.13-028

    Article  CAS  PubMed  Google Scholar 

  13. Mandrioli, R., Mercolini, L., Ferranti, A., Fanali, S., and Raggi, M.A., Food. Chem., 2011, vol. 126, p. 387. https://doi.org/10.1016/J.FOODCHEM.2010.10.112

    Article  CAS  Google Scholar 

  14. Zhou, Y., Chiu, C.-W., and Liang, H., Sensors, 2012, vol. 12, p. 15 036. https://doi.org/10.3390/s121115036

    Article  CAS  Google Scholar 

  15. Elsohly, M.A., Gul, W., Avula, B., and Khan, I.A., J. AOAC Int., 2007, vol. 90, no. 1, p. 28.

    Article  CAS  Google Scholar 

  16. Fanali, S., Aturki, Z., D’Orazio, G., Rocco, A., Ferranti, A., Mercolini, L., and Raggi, M.A., J. Sep. Sci., 2010, vol. 33, p. 2663. https://doi.org/10.1002/jssc.201000408

    Article  CAS  PubMed  Google Scholar 

  17. Zhao, Y., Sun, Y.N., Lee, M.J., Kim, Y.H., Lee, W., Kim, K.H., and Kang, J.S., J. Chromatogr. B: Anal. Technol. Biomed. Life Sci., 2016, vol. 1031, p. 163. https://doi.org/10.1016/J.JCHROMB.2016.07.036

    Article  CAS  Google Scholar 

  18. Jiao, P., Jia, Q., Randel, G., Diehl, B., Weaver, S., and Milligan, G.J., J. AOAC Int., 2010, vol. 93, no. 3, p. 842.

    CAS  PubMed  Google Scholar 

  19. Monakhova, Y.B., Randel, G., and Diehl, B.W.K., J. AOAC Int., 2016, vol. 99, p. 1213. https://doi.org/10.5740/jaoacint.16-0020

    Article  CAS  PubMed  Google Scholar 

  20. Logaranjan, K., Devasena, T., and Pandian, K., Am. J. Anal. Chem., 2013, vol. 4, p. 600. https://doi.org/10.4236/ajac.2013.410071

    Article  CAS  Google Scholar 

  21. Sánchez-Machado, D.I., López-Cervantes, J., Sendón, R., and Sanches-Silva, A., Trends Food Sci. Technol., 2017, vol. 61, p. 94. https://doi.org/10.1016/J.TIFS.2016.12.005

    Article  Google Scholar 

  22. Sánchez-Machado, D.I., López-Cervantes, J., Mariscal-Domínguez, M.F., Cruz-Flores, P., Campas-Baypoli, O.N., Cantú-Soto, E.U., and Sanches-Silva, A., J. Chromatogr. Sci., 2017, vol. 55, p. 251. https://doi.org/10.1093/chromsci/bmw179

    Article  CAS  PubMed  Google Scholar 

  23. Wang, P.G., Zhou, W., Wamer, W.G., Krynitsky, A.J., and Rader, J.I., Anal. Methods, 2012, vol. 4, no. 11, p. 3612. https://doi.org/10.1039/c2ay25599e

    Article  CAS  Google Scholar 

  24. Pomerantsev, A.L., Chemometrics in Excel, New York: Wiley, 2014.

    Book  Google Scholar 

  25. MILCA. www.ucl.ac.uk/ion/milca-0. Accessed January 29, 2020.

  26. Ravi, S., Kabilar, P., Velmurugan, S., Kumar, R.A., and Gayathiri, M., J. Exp. Sci., 2011, vol. 2, no. 8, p. 10.

    CAS  Google Scholar 

  27. Ray, A., Gupta, S.D., and Ghosh, S., Ind. Crops Prod., 2013, vol. 49, p. 712.

    Article  CAS  Google Scholar 

  28. Monakhova, Y.B. and Mushtakova, S.P., Anal. Bioanal. Chem., 2017, vol. 409, p. 3319. https://doi.org/10.1007/s00216-017-0275-0

    Article  CAS  PubMed  Google Scholar 

  29. Monakhova, Y.B. and Mushtakova, S.P., J. Anal. Chem., 2016, vol. 71, no. 8, p. 759. https://doi.org/10.1134/S1061934816060125

    Article  CAS  Google Scholar 

  30. Monakhova, Yu.B. and Mushtakova, S.P., J. Anal. Chem., 2017, vol. 72, no. 2, p. 147. https://doi.org/10.1134/S1061934816120066

    Article  CAS  Google Scholar 

  31. Stögbauer, H., Kraskov, A., Astakhov, S.A., and Grassberger, P., Phys. Rev. E: Stat., Nonlinear, Soft Matter Phys., 2004, vol. 70, 066 123. https://doi.org/10.1103/PhysRevE.70.066123

    Article  CAS  Google Scholar 

  32. Monakhova, Y.B., Astakhov, S.A., Kraskov, A., and Mushtakova, S.P., Chemom. Intell. Lab. Syst., 2010, vol. 103, p. 108. https://doi.org/10.1016/J.CHEMOLAB.2010.05.023

    Article  CAS  Google Scholar 

  33. Kraskov, A., Stögbauer, H., and Grassberger, P., Phys. Rev. E: Stat., Nonlinear, Soft Matter Phys., 2004, vol. 69, 066 138. https://doi.org/10.1103/PhysRevE.69.066138

    Article  CAS  Google Scholar 

  34. Malinowski, E.R., Anal. Chim. Acta, 1982, vol. 134, p. 129. https://doi.org/10.1016/S0003-2670(01)84184-2

    Article  CAS  Google Scholar 

Download references

Funding

This work was supported by the Russian Science Foundation, project no. 18-73-10009.

Author information

Authors and Affiliations

  1. Institute of Chemistry, Saratov State University, 410012, Saratov, Russia

    N. A. Burmistrova, O. O. Krivets & Yu. B. Monakhova

  2. Spectral Service AG, 50996, Cologne, Germany

    Yu. B. Monakhova

Authors
  1. N. A. Burmistrova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. O. Krivets
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. B. Monakhova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. A. Burmistrova.

Additional information

Translated by O. Zhukova

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Burmistrova, N.A., Krivets, O.O. & Monakhova, Y.B. UV Spectroscopic Determination of Aloin in Aloe vera (A. vera) Samples Based on Chemometric Data Processing. J Anal Chem 75, 1137–1142 (2020). https://doi.org/10.1134/S1061934820070047

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934820070047

Keywords:

Search

Navigation