Abstract
Adsorptive removal and preconcentration of Brilliant Green (BG) on Fe3O4 magnetic nanoparticles functionalized with cetyltrimethylamonium bromide (CTAB) was investigated in a batch system. The method was based on the analyte adsorption and direct determination by UV–visible spectrophotometry. Various experimental factors such as pH, adsorbent dose (m) and initial concentration (cd) were evaluated and optimized using Box-Behnken design through adsorption of BG on the modified adsorbent. The optimized conditions for maximum removal efficacy (99%) were: pH 9; amount of nanoparticles, 7.1 mg; CTAB, 5.4 mg and cd = 100 mg/L. Under optimum conditions, preconcentration of BG with enrichment factor of 35, LOD = 4 µg/L and RSD = 2.7% (n = 10) for 10 µg/L sample were achieved. The maximum monolayer adsorption of BG onto nano-Fe3O4‒CTAB through running Langmuir isotherm was obtained as 416 mg/g. The morphology and characteristics of the prepared nano-Fe3O4‒CTAB were investigated by scanning electron microscopy, X-ray diffraction, vibrating sample magnetometer, Fourier transform infrared spectroscopy and thermogravimetric analysis.
Similar content being viewed by others
REFERENCES
Forgacs, E., Cserhati, T., and Oros, G., Environ. Int., 2004, vol. 30, p. 953.
Crini, G., Bioresour. Technol., 2006, vol. 97, p. 1061.
Gupta, V.G. and Suhas, J. Environ. Manage., 2009, vol. 90, p. 2013.
Bhattacharyya, K.G. and Sarma, A., Dyes Pigm., 2003, vol. 57, p. 211.
Zolgharnein, J., Bagtash, M., and Shariatmanesh, T., Spectrochim. Acta, Part A, 2015, vol. 137, p. 1016.
Mall, I.D. and Srivastav, V.C., J. Environ. Manage., 2007, vol. 84, p. 390.
Ghaedi, M., Negintaji, G., Karimi, H., and Marahel, F., J. Ind. Eng. Chem., 2014, vol. 20, p. 1444.
Fernández, C., Larrechi, M.S., and Callao, M.P., TrAC, Trends Anal. Chem., 2010, vol. 29, p. 1202.
Zolgharnein, J., Adhami, Zh., Shahmoradi, A., and Mousavi, S.N., Anal. Sci., 2010, vol. 26, p. 111.
Zolgharnein, J., Shahmoradi, A., and Ghasemi, J., Clean: Soil, Air, Water, 2011, vol. 39, p. 105.
Mak, S. and Chen, D., Dyes Pigm., 2004, vol. 61, p. 93.
Li, J., Zhao, X., Shi, Y., Cai, Y., Mou, S., and Jiang, G., J. Chromatogr. A, 2008, vol. 1180, p. 24.
Shen, Y.F., Tang, J., Nie, Z.H., Wang, Y.D., Ren, Y., and Zuo, L., Sep. Purif. Technol., 2009, vol. 68, p. 312.
Xu, P., Zeng, G.M., Huang, D.L., Feng, C.L., Hu, S., Zhao, M.H., Lai, C., Wei, Z., Huang, C., Xie, G.X., and Liu, Z.F., Sci. Total Environ., 2012, vol. 424, p. 1.
Hua, M., Zhang, S., Pan, B., Zhang, W., Lv, L., and Zhang, Q., J. Hazard. Mater., 2012, vol. 211, p. 317.
Mahdavi, M., Ahmad, M.B., Haron, M.J., Namvar, F., Nadi, B., Ab Rahman, M.Z., and Amin, J., Molecules, 2013, vol. 18, p. 7533.
Khajeh, M., Laurent, S., and Dastafkan, K., Chem. Rev., 2013, vol. 113, p. 7728.
Zolgharnein, J., Choghaei, Z., Bagtash, M., Feshki, Sh., Rastgordani, M., and Zolgharnein, P., Desalin. Water Treat., 2016, vol. 57, p. 27672.
Zhao, X., Shi, Y., Cai, Y., and Mou, S., Environ. Sci. Technol., 2008, vol. 42, p. 1201.
Zargar, B., Parham, H., and Hatamie, A., Talanta, 2009, vol. 77, p. 1328.
Afkhami, A., Moosavi, R., and Madrakian, T., Talanta, 2010, vol. 82, p. 785.
Aguilar-Arteaga, K.M., Rodriguez, J.A., and Barrado, E., Anal. Chim. Acta, 2010, vol. 674, p. 57.
Giakisikli, G. and Anthemidis, A.N., Anal. Chim. Acta, 2013, vol. 789, p. 1.
Saitoh, T., Nakayama, Y., and Hiraide, M., J. Chromatogr. A, 2002, vol. 972, p. 205.
Peng, Z.G., Hidajat, K., and Uddin, M.S., Korean J. Chem. Eng., 2003, vol. 20, p. 896.
Zhao, X.L., Li, J.D., Shi, Y.L., Cai, Y.Q., Mou, S.F., and Jiang, G.B., J. Chromatogr. A, 2007, vol. 1154, p. 52.
Absalan, Gh., Asadi, M., Kamran, S., and Sheikhian, L., J. Hazard. Mater., 2011, vol. 192, p. 476.
Zolgharnein, J., Bagtash, M., and Asanjarani, N., J. Environ. Chem. Eng., 2014, vol. 2, p. 988.
Bagtash, M., Yamini, Y., Tahmasebi, E., Zolgharnein, J., and Dalirnasab, Z., Microchim. Acta, 2016, vol. 183, p. 449.
Li, J.D., Cai, Y.Q., Shi, Y.L., Mou, S.F., and Jiang, G.B., J. Chromatogr. A, 2007, vol. 1139, p. 178.
Ballesteros-Gómez, A. and Rubio, S., Anal. Chem., 2009, vol. 81, p. 9012.
Kim, D.K., Zhang, Y., Voit, W., Rao, K.V., and Muhammed, M., J. Magn. Magn. Mater., 2001, vol. 225, p. 30.
Ferreira, S.L.C., Bruns, R.E., Ferreira, H.S., Matos, G.D., David, J.M., and Brandão, G.C., da Silva, E.G.P., Portugal, L.A., dos Reis, P.S., Souza, A.S., and dos Santos, W.N.L., Anal. Chim. Acta, 2007, vol. 597, p. 179.
Bezerra, M., Santelli, R., Oliveira, E., Villar, L.S., and Escaleira, L.A., Talanta, 2008, vol. 76, p. 965.
Costa Ferreira, S.L., Bruns, R.E., Galvão Paranhos da Silva, E., Lopes dos Santos, W.N., Quintella, C.M., David, J.M., Bittencourt de Andrade, J., Breitkreitz, M.C., Sales Fontes Jardim, J.C., and Barros Neto, B., J. Chromatogr. A, 2007, vol. 1158, p. 2.
Zolgharnein, J., Shahmoradi, A., and Ghasemi, J.B., J. Chemom., 2013, vol. 27, p. 12.
Kazemi, S.Y., Hamidi, A.S., Zolgharnein, J., and Lakouraj, M.M., J. Anal. Chem., 2014, vol. 69, no. 7, p. 646.
Waldron, R.D., Phys. Rev., 1995, vol. 99, p. 1727.
Park, S.I., Kim, J.H., Lim, J.H., and Kim, C.O., Curr. Appl. Phys., 2008, vol. 8, p. 706.
Panneerselvam, P., Morad, N., and Tan, K.A., J. Hazard. Mater., 2011, vol. 186, p. 160.
Zolgharnein, J., Shariatmanesh, T., Asanjarani, N., and Zolanvari, A., Desalin. Water Treat., 2015, vol. 53, p. 430.
Zolgharnein, J., Shahmoradi, A., Zolgharnein, P., and Amani, S., Chem. Eng. Commun., 2016, vol. 203, p. 210.
Barbosa, A.F., Segatelli, M.G., Pereira, A.C., de Santana Santos, A., Kubota, L.T., Orival Luccas, P., and Teixeira Tarley, C.R., Talanta, 2007, vol. 71, p. 1512.
Liu, Y. and Liu, Y.J., Sep. Purif. Technol., 2008, vol. 61, p. 229.
Gimbert, F., Morin-Crini, N., Renault, F., Badot, P.-M., and Crini, G., J. Hazard. Mater., 2008, vol. 157, p. 34.
Kumar, K.V., Porkodi, K., and Rocha, F., J. Hazard. Mater., 2008, vol. 151, p. 794.
Foo, K.Y. and Hameed, B.H., Chem. Eng. J., 2010, vol. 156, p. 2.
Putra, E.K., Panonwo, R., Sunnarso, J., Indraswati, N., and Ismadji, S., Water Res., 2009, vol. 43, p. 2419.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare no conflict of interest.
Rights and permissions
About this article
Cite this article
Zolgharnein, J., Feshki, S. Multivariate Optimization for Preconcentration and Separation of Brilliant Green using Magnetite Nanoparticles Functionalized by Cetyltrimethylamonium Bromide. J Anal Chem 74, 744–755 (2019). https://doi.org/10.1134/S1061934819080094
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061934819080094