Skip to main content
SpringerLink
Log in

Direct Determination of Lead in Sea Water by High-Resolution Atomic Absorption Spectroscopy Using a Mixed Modifier Barium Nitrate–Hydrofluoric Acid

  • ARTICLES
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

A procedure is proposed for the direct determination of lead in sea water by electrothermal atomization high-resolution atomic absorption spectrometry. The effect of background interferences due to sea water matrix is eliminated using a mixed modifier barium nitrate–hydrofluoric acid. The optimum amount of the modifier matrix is 60 µg Ba (NO3)2 + 1.52 µg HF. The conditions of analysis are as follows: pyrolysis temperature 600°C, atomization temperature 1200°C. The limit of detection for the developed procedure is 0.0003 mg/L.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.

Similar content being viewed by others

REFERENCES

  1. Juberg, D.R., Lead and Human Health: An Update, New York: Am. Council Sci. Health, 2000.

    Google Scholar 

  2. Chester, R., Marine Geochemistry, London: Unwin Hyman, 1990.

    Book  Google Scholar 

  3. Perechen’ rybokhozyaistvennykh normativov: predel’no-dopustimykh kontsentratsii i orientirovochno bezopasnykh urovnei veshchestv dlya vody, vodnykh ob”ektov, imeyushchikh rybokhozyaistvennoe znachenie (List of Fisheries Standards: Maximum Permissible Concentrations and Approximately Safe Levels of Substances for Water, Water Bodies of Fishery Importance), Moscow: Vseross. Nauchn.-Issled. Inst. Ryb. Khoz. Okeanogr., 1999.

  4. Horne, R.A., Marine Chemistry: Structure of Water and the Chemistry of the Hydrosphere, New York: Wiley, 1969.

    Google Scholar 

  5. Cabon, J.Y., Spectrochim. Acta, Part B, 2002, vol. 57, p. 513.

    Article  Google Scholar 

  6. Creed, J.T. and Martin, T.D., Determination of Trace Elements in Marine Waters by Off-Line Chelation Preconcentration with Graphite Furnace Atomic Absorption, Method 200.13, Cincinnati: United States Environmental Protection Agency, 1992.

    Google Scholar 

  7. Wells, M.L. and Bruland, K.W., Mar. Chem., 1998, vol. 63, p. 145.

    Article  CAS  Google Scholar 

  8. Kojuncu, Y., Bundalevska, J.M., Ay, U., Čundeva, K., Stafilov, T., and Akçin, G., Sep. Sci. Technol., 2004, vol. 39, p. 2751.

    Article  CAS  Google Scholar 

  9. Gladis, J.M., Biju, V.M., and Prasada Rao, T., At. Spectrosc., 2002, vol. 23, p. 143.

    CAS  Google Scholar 

  10. Shiowatana, J., Benyatianb, K., and Siripinyanond, A., At. Spectrosc., 2000, vol. 21, p. 179.

    CAS  Google Scholar 

  11. Khavezov, I. and Tsalev, D., Atomno-Absorbtsionen Analiz (Atomic-Absorption Analysis), Sofia: Nauka Izkustvo, 1980.

  12. Cabon, J.Y. and Le Bihan, A., Spectrochim. Acta, Part B, 1996, vol. 51, p. 1245.

    Article  Google Scholar 

  13. Ortner, H.M., Bulska, E., Rohr, U., Schlemmer, G., Weinbruch, S., and Welz, B., Spectrochim. Acta, Part B, 2002, vol. 57, p. 1835.

    Article  Google Scholar 

  14. Alemasova, A.S., Vysokotemperaturnye protsessy prevrashcheniya kompleksoobrazovatelei i kompleksov metallov v atomno-absorbtsionnom analize (High-Temperature Transformation Pprocesses of Complexing Agents and Metal Complexes in Atomic Absorption Analysis), Donetsk: Donetsk. Gos. Univ., 1997.

  15. Tsalev, D.L., Slaveikova, V.I., and Mandjukov, P.B., Spectrochim. Acta Rev., 1990, vol. 13, no. 3, p. 225.

    CAS  Google Scholar 

  16. Bin, H. and Zhe-Min, N., J. Anal. At. Spectrosc., 1996, vol. 11, p. 165.

    Article  CAS  Google Scholar 

  17. Volynsky, A.B., Akmana, S., Dogana, C.E., and Koklua, U., Spectrochim. Acta, Part B, 2001, vol. 56, p. 2361.

    Article  Google Scholar 

  18. Acar, O., Talanta, 2005, vol. 65, p. 672.

    Article  CAS  PubMed  Google Scholar 

  19. Pupyshev, A.A., Atomno-absorbtsionnyi spektral’nyi analiz (Atomic Absorption Spectral Analysis), Moscow: Tekhnosfera, 2009.

  20. Dean, J.A., Lange’s Handbook of Chemistry, New York: McGraw-Hill, 1999, 15th ed.

    Google Scholar 

  21. Smagunova, A.N., Metody matematicheskoi statistiki v analiticheskoi khimii (Methods of Mathematical Statistics in Analytical Chemistry), Rostov-on-Don: Feniks, 2012.

  22. Sachs, L., Statistische Auswertungsmethoden (Statistical Evaluation Methods), Berlin: Springer, 1968.

Download references

ACKNOWLEDGMENTS

This work was performed using instrumentation of the “Arktika” Core Facility Center of the Northern (Arctic) Federal University (project RFMEFI59417X0013).

Author information

Authors and Affiliations

  1. Core Facility Center “Arktika,” M.V. Lomonosov Northern (Arctic) Federal University, 163002, Arkhangelsk, Russia

    N. A. Sobolev, N. L. Ivanchenko & A. Yu. Kozhevnikov

Authors
  1. N. A. Sobolev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. L. Ivanchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. Yu. Kozhevnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. Yu. Kozhevnikov.

Additional information

Translated by E. Rykova

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sobolev, N.A., Ivanchenko, N.L. & Kozhevnikov, A.Y. Direct Determination of Lead in Sea Water by High-Resolution Atomic Absorption Spectroscopy Using a Mixed Modifier Barium Nitrate–Hydrofluoric Acid. J Anal Chem 74, 444–448 (2019). https://doi.org/10.1134/S1061934819020126

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934819020126

Keywords:

Search

Navigation