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Selective Solid Phase Extraction of Copper from Different Samples using Copper Ion-Imprinted Polymer

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Abstract

Ion imprinted polymer (IIP) for copper was synthesized for selective extraction of copper from different samples for analysis using flame atomic absorption spectrophotometry. In the synthesis of ion-imprinted polymer Cu(II) ion (template), 2,2'-bibyridine (ligand) and 4-vinylpyridine (functional monomer) which formed a complex through coordination with Cu(II) ion, ethylene glycol dimethacrylate (cross-linker) and 2,2'-azobisisobutyronitrile (initiator) were used. The ion-imprinted polymer and non-imprinted polymer (NIP) were synthesized via precipitation polymerization process. The synthesized polymers were characterized using Fourier transform infrared spectroscopy and scanning electron microscopy. Variables affecting the solid phase extraction of Cu(II) such as pH, initial Cu(II) concentration and time were studied in batch experiments. Quantitative retention of Cu(II) on IIP was achieved at pH 7. The IIP selectivity for copper ion extraction was higher as compared to NIP in the presence of other competing metal ions. The method was successfully applied to the determination of copper in multivitamin tablet, various natural water samples and industrial effluent.

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REFERENCES

  1. Ashkenani, H. and Taher, M.A., J. Electroanal. Chem., 2012, vol. 683, p. 80.

    Article  CAS  Google Scholar 

  2. Khajeh, M. and Sanchooli, E., Environ. Chem. Lett., 2011, vol. 9, p. 177.

    Article  CAS  Google Scholar 

  3. Lu, S. and Gibb, S.W., Bioresour. Technol., 2008, vol. 99, p. 1509.

    Article  CAS  PubMed  Google Scholar 

  4. Sörme, L. and Lagerkvist, R., Sci. Total Environ., 2002, vol. 298, p. 131.

    Article  PubMed  Google Scholar 

  5. Godlewska-Żyłkiewicz, B., Spectrochim. Acta, Part B, 2003, vol. 58, p. 1531.

    Article  CAS  Google Scholar 

  6. Cabral de Lima, G., Campos do Lago, A., Alves Chaves, A., Fadini, P.S., and Luccas, P.O., Anal. Chim. Acta, 2013, vol. 768, p. 35.

    Article  CAS  Google Scholar 

  7. Alizadeh, T., Ganjali, M.R., and Zare, M., Anal. Chim. Acta, 2011, vol. 689, p. 52.

    Article  CAS  PubMed  Google Scholar 

  8. Liu, Y., Liu, Z., Gao, J., Dai, J., Han, J., Wang, Y., Xie, J., and Yan, Y., J. Hazard. Mater., 2011, vol. 186, p. 197.

    Article  CAS  PubMed  Google Scholar 

  9. Singh, D.K. and Mishra, S., Chromatographia, 2009, vol. 70, p. 1539.

    Article  CAS  Google Scholar 

  10. Hoai, N.T. and Kim, D., AIChE J., 2009, vol. 55, p. 3248.

    Article  CAS  Google Scholar 

  11. Branger, C., Meouche, W., and Margaillan, A., React. Funct. Polym., 2013, vol. 73, p. 859.

    Article  CAS  Google Scholar 

  12. Bahrami, A., Besharati-Seidani, A., and Abbaspour, A., Electrochim. Acta, 2014, vol. 118, p. 92.

    Article  CAS  Google Scholar 

  13. Azevedo Lemos, V., Sena Gomes Teixeira, L., de Almeida Bezzera, M., Spínola Costa, A.C., Teixeira Castro, J., Martins Cardoso, L.A., et al., Appl. Spectrosc. Rev., 2008, vol. 43, p. 303.

    Article  CAS  Google Scholar 

  14. Yilmaz, V., Hazer, O., and Kartal, Ş., Talanta, 2013, vol. 116, p. 322.

    Article  CAS  PubMed  Google Scholar 

  15. Abedi, H. and Ebrahimzadeh, H., React. Funct. Polym., 2013, vol. 73, p. 634.

    Article  CAS  Google Scholar 

  16. Ebrahimzadeh, H., Behbahani, M., Yamini, Y., and Adlnasab, L., React. Funct. Polym., 2013, vol. 73, p. 23.

    Article  CAS  Google Scholar 

  17. Britton, H.T.S., Hydrogen Ions, Ser.: Monographs on Applied Chemistry, vol. 3, Tripp, E.H., Ed., New York, 1943.

    Google Scholar 

  18. Jo, S.H., Park, C., Yi, S.C., Kim, D., and Mun, S., J. Chromatogr. A, 2011, vol. 1218, p. 5664.

    Article  CAS  PubMed  Google Scholar 

  19. Luo, X., Luo, S., Zhan, Y., Shu, H., Huang, Y., and Tu, X., J. Hazard. Mater., 2011, vol. 192, p. 949.

    Article  CAS  PubMed  Google Scholar 

  20. Shah, J., Jan, M.R., Haq, A.U., and Zeeshan, M., J. Saudi Chem. Soc., 2015, vol. 19, p. 301.

    Article  Google Scholar 

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ACKNOWLEDGMENTS

The analysis in the Centralized Resource Laboratory, University of Peshawar is highly acknowledged.

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Authors and Affiliations

  1. Institute of Chemical Sciences, University of Peshawar, Khyber Pakhtunkhwa, Pakistan

    Jasmin Shah, M. Rasul Jan &  Anjum

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  1. Jasmin Shah
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  2. M. Rasul Jan
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  3. Anjum
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Correspondence to Jasmin Shah.

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Jasmin Shah, Jan, M.R. & Anjum Selective Solid Phase Extraction of Copper from Different Samples using Copper Ion-Imprinted Polymer. J Anal Chem 73, 1146–1153 (2018). https://doi.org/10.1134/S1061934818120055

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  • DOI: https://doi.org/10.1134/S1061934818120055

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