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Determination of Adsorbates on the Surface of Polymer with Low Absorption Capacity by Thermal Lens Spectrometry

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Abstract

Thermal lens spectrometry in a coaxial configuration is used for the direct determination of adsorbates on a planar surface of polyethylene terephthalate (PET). A possibility of the direct measurement of the rate of adsorption from solutions and the determination of the parameters of the adsorbed layer is demonstrated by the example of an investigation of the adsorption of iron(II) tris(1,10-phenantrolinate) on a PET surface. The adsorption isotherm of iron(II) tris(1,10-phenantrolinate) on the PET surface is described by the Langmuir equation and is linear in the concentration range in solution from 0.02 to 0.7 mM. The method for calculating the thermal perturbation in surface-absorbing solids was used to interpret the results of the adsorption study, and a possibility of determining iron(II) tris(1,10-phenantrolinate) on the surface at a level smaller than a monolayer was shown. Thermal lens spectrometry enables the determination of the absorption of the surface layer at a level up to 5 × 10–5 absorbance units, which corresponds to the surface concentration of iron(II) tris(1,10-phenanthrolinate) 2 × 10–13 mol/cm2. Using the example of the adsorption of 4-(2-pyridylazo) resorcinol on the PET surface, it is demonstrated that, in the case of strong absorption of the surface layer, the thermal destruction of substance and the deformation of the substrate may occur. A local increase in temperature in the layer is also confirmed by theoretical calculations.

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References

  1. Liu, M. and Franko, M., Crit. Rev. Anal. Chem., 2014, vol. 44, no. 4, p.328.

    Article  CAS  PubMed  Google Scholar 

  2. Bialkowski, S.E., Photothermal Spectroscopy Methods for Chemical Analysis, New York: Wiley, 1996.

    Google Scholar 

  3. Nedosekin, D.A., Saranchina, N.V., Sukhanov, A.V., Gavrilenko, N.A., Mikheev, I.V., and Proskurnin, M.A., Appl. Spectrosc., 2013, vol. 67, no. 7, p.709.

    Article  CAS  PubMed  Google Scholar 

  4. Korte, D. and Franko, M., Int. J. Thermophys., 2014, vol. 35, no. 12, p. 2352.

    Article  CAS  Google Scholar 

  5. Malacarne, L.C., Astrath, N.G.C., Lukasievicz, G.V.B., Lenzi, E.K., Baesso, M.L., and Bialkowski, S.E., Appl. Spectrosc., 2011, vol. 65, no. 1, p.99.

    Article  CAS  PubMed  Google Scholar 

  6. Kononets, M.Yu, Cand. Sci. (Chem.) Dissertation, Moscow: Moscow State Univ., 2005.

    Google Scholar 

  7. Najmoddin, N. and Khosroshahi, M.E., Nucl. Instrum. Methods Phys. Res., Sect. A, 2015, vol. 774, p.1.

    Article  CAS  Google Scholar 

  8. Capeloto, O.A., Lukasievicz, G.V.B., Zanuto, V.S., Herculano, L.S., Souza Filho, N.E., Novatski, A., Malacarne, L.C., Bialkowski, S.E., Baesso, M.L., and Astrath, N.G.C., Appl. Opt., 2014, vol. 53, no. 33, p. 7985.

    Article  CAS  PubMed  Google Scholar 

  9. Saranchina, N.V., Sukhanov, A.V., Nedosekin, D.A., Gavrilenko, N.A., and Proskurnin, M.A., J. Anal. Chem., 2011, vol. 66, no. 6, p.623.

    Article  CAS  Google Scholar 

  10. Proskurnin, M.A. and Kononets, M.Yu., Russ. Chem. Rev., 2004, vol. 73, no. 12, p. 1143.

    Article  CAS  Google Scholar 

  11. Wang, Z.-G., Wan, L.-S., and Xu, Z.-K., J. Membr. Sci., 2007, vol. 304, nos. 1–2, p.8.

    Article  CAS  Google Scholar 

  12. Gavrilenko, N.A. and Saranchina, N.V., J. Anal. Chem., 2010, vol. 65, no. 2, p.148.

    Article  CAS  Google Scholar 

  13. Gavrilenko, N.A. and Saranchina, N.V., J. Anal. Chem., 2009, vol. 64, no. 3, p.226.

    Article  CAS  Google Scholar 

  14. Nedosekin, D.A., Proskurnin, M.A., and Kononets, M.Y., Appl. Opt., 2005, vol. 44, no. 29, p. 6296.

    Article  CAS  PubMed  Google Scholar 

  15. Schweitzer, M.A. and Power, J.F., Appl. Spectrosc., 1994, vol. 48, p. 1054.

    Article  CAS  Google Scholar 

  16. Shen, J. and Snook, R.D., J. Appl. Phys., 1993, vol. 73, no. 10, p. 5286.

    Article  CAS  Google Scholar 

  17. Proskurnin, M.A., Volkov, D.S., Gor’kova, T.A., Bendrysheva, S.N., Smirnova, A.P., and Nedosekin, D.A., J. Anal. Chem., 2015, vol. 70, no. 3, p.249.

    Article  CAS  Google Scholar 

  18. Proskurnin, M.A., Photothermal spectroscopy, in Laser Spectroscopy for Sensing, Baudelet, M., Ed., Cambridge: Woodhead, 2014, p.313.

    Chapter  Google Scholar 

  19. Proskurnin, M.A., Nedosekin, D.A., Volkov, D.S., Mikheev, I.V., and Filichkina, V.A., RF Patent 2615912, Byull. Izobret., 2017, no.11.

  20. Kononets, M.Y., Proskurnin, M.A., Bendrysheva, S.N., and Chernysh, V.V., Talanta, 2001, vol. 53, no. 6, p. 1221.

    Article  CAS  PubMed  Google Scholar 

  21. Gladyshev, V.P., Levitskaya, S.A., and Fillipova, L.M., Analiticheskaya khimiya rtuti (Analytical Chemistry of Mercury), Moscow: Nauka, 1974.

    Google Scholar 

  22. Pons, M., Nonell, S., García-Moreno, I., Costela, Á., and Sastre, R., Appl. Phys. B: Lasers Opt., 2002, vol. 75, nos. 6–7, p.687.

    Article  CAS  Google Scholar 

  23. Elperin, T. and Rudin, G., Heat Mass Transfer, 2010, vol. 46, no. 7, p. 717.

    Article  Google Scholar 

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Authors and Affiliations

  1. Arkansas Nanomedicine Center, University of Arkansas for Medical Sciences, Little Rock, AR, 72205, United States

    D. A. Nedosekin

  2. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    I. V. Mikheev, D. S. Volkov & M. A. Proskurnin

Authors
  1. D. A. Nedosekin
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  2. I. V. Mikheev
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  3. D. S. Volkov
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  4. M. A. Proskurnin
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Corresponding author

Correspondence to M. A. Proskurnin.

Additional information

Original Russian Text © D.A. Nedosekin, I.V. Mikheev, D.S. Volkov, M.A. Proskurnin, 2018, published in Zhurnal Analiticheskoi Khimii, 2018, Vol. 73, No. 7, pp. 498–507.

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Nedosekin, D.A., Mikheev, I.V., Volkov, D.S. et al. Determination of Adsorbates on the Surface of Polymer with Low Absorption Capacity by Thermal Lens Spectrometry. J Anal Chem 73, 641–649 (2018). https://doi.org/10.1134/S1061934818070146

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  • DOI: https://doi.org/10.1134/S1061934818070146

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