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Journal of Analytical Chemistry

, Volume 73, Issue 4, pp 334–343 | Cite as

Possibilities of the Determination of Matrix Elements of High-Purity Glasses of As–Se and As–S Systems by Inductively Coupled Plasma Atomic Emission Spectrometry

  • I. I. EvdokimovEmail author
  • V. G. Pimenov
  • D. A. Fadeeva
Articles
  • 25 Downloads

Abstract

Possibilities of inductively coupled plasma atomic emission spectrometry (ICP AES) as an alternative to X-ray spectrochemical analysis are estimated in the determination of matrix elements of glasses of As–Se and As–S systems. Standard solutions were prepared from pure elements As, Se and S. It was shown that the matrix elements of glasses can be determined with an expanded uncertainty of 0.05–0.1 mol %. The results of determinations by ICP AES and X-ray fluorescence spectrometry were compared; and it was found that by the attained performance characteristics, the results of ICP AES are highly competitive with the data of X-ray fluorescence spectrometry, but do not require sets of adequate solid reference samples.

Keywords

inductively coupled plasma atomic emission spectrometry ICP AES chalcogenide As–Se and As–S glasses determination of matrix elements 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • I. I. Evdokimov
    • 1
    Email author
  • V. G. Pimenov
    • 1
  • D. A. Fadeeva
    • 1
  1. 1.Devyatykh Institute of Chemistry of High-Purity SubstancesRussian Academy of SciencesNizhny NovgorodRussia

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