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Ionic Liquid Based Ultrasound-Assisted Emulsification Microextraction for Preconcentration of Phenol Using Central Composite Design

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Abstract

In this work, phenol reacted with 4-aminoantipyrine (4-AAP) reagent in presence of potassium hexacyanoferrate(III) and then was extracted using ultrasound-assisted emulsification microextraction via 1-hexyl-3-methyl imidazolium hexafluorophosphate as an environmentally friendly solvent. Effects of the main experimental variables were investigated and optimized by central composite design. Under the optimum conditions (pH 9.5, 100 mg/L 4-AAP, 100 μL of ionic liquid as extraction solvent, 0.2 g/L K3Fe(CN)6 and 0.2 M NH4Cl) the dynamic linear range, limit of detection and relative standard deviation were obtained as 0.2‒25 μg/L, 0.07 μg/L and 2.6%, respectively. Finally, the applicability of the proposed ultrasoundassisted emulsification microextraction was examined and very good results were obtained. The results confirmed the applicability of the proposed method as a versatile, low cost and sensitive preconcentration method for determination of very low concentrations of phenol in aqueous solutions.

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References

  1. Letizia, M. and Gundi, F., Water Res., 1999, vol. 33, p. 3213.

    Article  Google Scholar 

  2. Ni, Y., Xia, Z., and Kokotc, S., J. Hazard. Mater., 2001, vol. 192, p. 722.

    Article  Google Scholar 

  3. Desiderio, C., Ossicini, L., and Fanali, S., J. Chromatogr. A, 2000, vol. 887, p. 489.

    Article  CAS  Google Scholar 

  4. Wittig, J., Wittemer, S., and Veit, M., J. Chromatogr. B: Biomed. Sci. Appl., 2001, vol. 761, p. 125.

    Article  CAS  Google Scholar 

  5. Waidyanatha, S., Rothman, N., Li, G., Smith, M.T., Yin, S., and Rappaport, S.M., Anal. Biochem., 2004, vol. 327, p. 184.

    Article  CAS  Google Scholar 

  6. Ahammad, A.J.S., Skarker, S., Rahman, M.A., and Lee, J.J., Electroanalysis, 2010, vol. 22, p. 694.

    Article  CAS  Google Scholar 

  7. Rezaee, M., Yamini, Y., Shariati, Sh., Esrafili, A., and Shamsipur, M., J. Chromatogr. A, 2009, vol. 1216, p. 1511.

    Article  CAS  Google Scholar 

  8. Shariati, Sh., Yamini, Y., and Rezaee, M., Monatsh. Chem., 2011, vol. 142, p. 555.

    Article  CAS  Google Scholar 

  9. Shariati, Sh. and Golshekan, M., Acta Chim. Slov., 2011, vol. 58, p. 311.

    CAS  Google Scholar 

  10. Arvand, M., Bozorgzadeh, E., Shariati, Sh., and Zanjanchi, M.A., Environ. Monit. Assess., 2012, vol. 184, p. 7597.

    Article  CAS  Google Scholar 

  11. Arvand, M., Bozorgzadeh, E., Shariati, Sh., and Zanjanchi, M.A., Anal. Methods, 2012, vol. 4, p. 2272.

    Article  CAS  Google Scholar 

  12. Rezaee, M. and Assadi, Y., Milani Hosseini, M.R., Aghaee, E., Ahmadi, F., and Berijani, S., J. Chromatogr. A, 2006, vol. 1116, p. 1.

    Article  CAS  Google Scholar 

  13. Liang, P., Xu, J., and Li, Q., Anal. Chim. Acta, 2008, vol. 609, p. 53.

    Article  CAS  Google Scholar 

  14. Shamsipur, M. and Ramezani, M., Talanta, 2008, vol. 75, p. 294.

    Article  CAS  Google Scholar 

  15. Nagaraju, D. and Huang, S.D., J. Chromatogr. A, 2007, vol. 1161, nos. 1–2, p. 89.

    Article  CAS  Google Scholar 

  16. Jiang, H., Qin, Y., and Hu, B., Talanta, 2008, vol. 74, p. 1160.

    Article  CAS  Google Scholar 

  17. Pandey, S., Anal. Chim. Acta, 2006, vol. 556, p. 38.

    Article  CAS  Google Scholar 

  18. Zhang, H.F. and Shi, Y.P., Talanta, 2010, vol. 82, p. 1010.

    Article  CAS  Google Scholar 

  19. Clesceri, L.S., Greenberg, A.E., and Trussell, R.R., Standard Methods for the Examination of Water and Wastewater, Washington, D.C.: American Public Health Association, 1989, 17th ed.

    Google Scholar 

  20. Emerson, E., J. Org. Chem., 1943, vol. 8, p. 417.

    Article  CAS  Google Scholar 

  21. Fiamegos, Y., Stalikas, C., and Pilidis, G., Anal. Chim. Acta, 2002, vol. 467, p. 105.

    Article  CAS  Google Scholar 

  22. Powell, M.F., Wu, J.C., and Bruice, T.C., J. Am. Chem. Soc., 1984, vol. 106, p. 3850.

    Article  CAS  Google Scholar 

  23. Bezerra, M.A., Santelli, E., Oliveiraa, E.P., Villar, L.S., and Escaleira, L.A., Talanta, 2008, vol. 76, p. 965.

    Article  CAS  Google Scholar 

  24. Jalali-Heravi, M., Parastar, H., and Ebrahimi-Najafabadi, H., J. Chromatogr. A, 2009, vol. 1216, p. 6088.

    Article  CAS  Google Scholar 

  25. Jerkovic, I., Mastelic, J., Marijianovic, Z., Klein, Z., and Jelic, M., Ultrason. Sonochem., 2007, vol. 14, p. 750.

    Article  CAS  Google Scholar 

  26. Pan, J., Xia, X.X., and Liang, J., Ultrason. Sonochem., 2008, vol. 15, p. 25.

    Article  Google Scholar 

  27. Sheikheldin, S.Y., Cardwell, T.J., Cattrall, R.W., Luque de Castro, M.D., and Koleva, S.D., Anal. Chim. Acta, 2000, vol. 419, p. 9.

    Article  CAS  Google Scholar 

  28. Zhang, J., Su, T., and Lee, H.K., J. Chromatogr. A, 2006, vol. 1121, p. 10.

    Article  CAS  Google Scholar 

  29. Zhao, L. and Lee, H.K., J. Chromatogr. A, 2001, vol. 931, p. 95.

    Article  CAS  Google Scholar 

  30. Crespín, M.A., Gallego, M., and Valcarcel, M., J. Chromatogr. B: Anal. Technol. Biomed. Life Sci., 2002, vol. 773, p. 89.

    Article  Google Scholar 

  31. Montero, L., Conradi, S., Weiss, H., and Popp, P., J. Chromatogr. A, 2005, vol. 1071, p. 163.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Rasht Branch, Islamic Azad University, Rasht, Iran

    Shahab Shariati & Fariba Safa

  2. Young Researchers and Elite Club, Rasht Branch, Islamic Azad University, Rasht, Iran

    Elahe Bozorgzadeh

  3. Department of Environment, Lahijan Branch, Islamic Azad University, Lahijan, Iran

    Fatemeh Shariati

Authors
  1. Shahab Shariati
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  2. Elahe Bozorgzadeh
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  3. Fatemeh Shariati
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  4. Fariba Safa
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Correspondence to Shahab Shariati.

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Shariati, S., Bozorgzadeh, E., Shariati, F. et al. Ionic Liquid Based Ultrasound-Assisted Emulsification Microextraction for Preconcentration of Phenol Using Central Composite Design. J Anal Chem 73, 36–41 (2018). https://doi.org/10.1134/S1061934818010100

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  • DOI: https://doi.org/10.1134/S1061934818010100

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