Journal of Analytical Chemistry

, Volume 72, Issue 12, pp 1255–1262 | Cite as

Identification of endogenous and anthropogenic hydrocarbons in bottom deposits of peat lakes and evaluation of their contribution to the “hydrocarbon index”

  • E. S. BrodskiiEmail author
  • A. A. Shelepchikov
  • E. Ya. Mir-Kadyrova
  • G. A. Kalinkevich


Gas chromatography with mass spectrometric detection was used to analyze bitumens isolated from bottom sediments of peat lakes contaminated with petroleum products. Endogenous hydrocarbons are characterized by the presence of n-alkanes with an odd number of carbon atoms in the molecule in the characteristic region of C23–C33, the absence of a “hump” characteristic of oil products in the chromatogram, and the presence of light hydrocarbons, eluting in the initial part of the chromatogram (light hydrocarbons are usually lost when the sample is dried). The distribution profile of odd n-alkanes is used to assess the contribution of endogenous hydrocarbons to the “hydrocarbon index” with the help of the pattern recognition method. The concentration of light hydrocarbons is from 50 and 300–400 to 3500–5000 mg/kg for a number of samples and even up to 26000 mg/kg in some samples. The concentration of petroleum hydrocarbons and heteroatomic compounds varies from the lowest values of 30–80 mg/kg up to 20000 mg/kg and higher.


endogenous and anthropogenic hydrocarbons bitumens of bottom sediments of peat lakes gas chromatography–mass spectrometry pattern recognition 


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  1. 1.
    Tissot, B.P. and Welte, D.H., Petroleum Formation and Occurrence, Berlin: Springer, 1978. 2.CrossRefGoogle Scholar
  2. 2.
    Shor, E.L. and Khurshudov, A.G., Estimation of average background concentrations of oil products in soils and surface waters of oil deposits in the Nizhnevartovsk region, 2005. C994AE08F2C37BCEF79B77B. Cited April 04, 2017.Google Scholar
  3. 3.
    Glyaznetsova, Yu.S. and Zueva, I.N., Arktika Sever, 2012, no. 5, p. 97.Google Scholar
  4. 4.
    Chivilev, S.M., Prozorova, M.V., Matveev, I.V., Korneva, S.V., Pchelincev, V.G., and Solodov, A.A., Features of determination of petroleum products in soils and bottom sediments. Cited April 04, 2017.Google Scholar
  5. 5.
    Nott, C.J., Xie, S.S., Avsejs, L.A., Maddy, D.D., Chambers, F.M., and Evershed, R.P., Org. Geochem., 2000, vol. 31, nos. 2–3, p. 231.CrossRefGoogle Scholar
  6. 6.
    Nichols, J.E., Booth, R.K., Jackson, S.T., Pendall, E.G., and Huang, Y., Org. Geochem., 2006, vol. 37, no. 11, p. 1505.CrossRefGoogle Scholar
  7. 7.
    Vonk, J.E. and Gustafsson, O., Org. Geochem., 2009, vol. 40, no. 10, p. 1085.CrossRefGoogle Scholar
  8. 8.
    López-Días, V., Borrego, T., Blanco, C.G., Arboleya, M., López-Sáez, J.A., and López-Merino, L., J. Chromatogr. A, 2010, vol. 1217, no. 21, p. 3538.CrossRefGoogle Scholar
  9. 9.
    Bingham, E.M., McClymont, E.L., Valiranta, M., Mauquoy, D., Roberts, Z., Chambers, F.M., Pancost, R.D., Richard, P., and Evershed, R.P., Org. Geochem., 2010, vol. 41, no. 2, p. 214.CrossRefGoogle Scholar
  10. 10.
    Andersson, R.A., Kuhry, P., Meyers, P., Zebühr, Y., Crill, P., and Mörth, M., Org. Geochem., 2011, vol. 4, no. 9, p. 1065.CrossRefGoogle Scholar
  11. 11.
    Ishiwatari, R., Yamamoto, S., and Uemura, H., Org. Geochem., 2005, vol. 36, no. 3, p. 327.CrossRefGoogle Scholar
  12. 12.
    Jansen, B., Nierop, K.G.J., Hageman, J.A., Cleef, A.M., and Verstraten, J.M., Org. Geochem., 2006, vol. 37, no. 11, p. 1514.CrossRefGoogle Scholar
  13. 13.
    Ficken, K.J., Li, B., Swain, D.L., and Eglinton, G., Org. Geochem., 2000, vol. 31, nos. 7–8, p. 745.CrossRefGoogle Scholar
  14. 14.
    Meyers, P.A., Org. Geochem., 2003, vol. 34, no. 2, p. 261.CrossRefGoogle Scholar
  15. 15.
    Zheng, Y., Zhou, W., Meyers, P.A., and Xie, S., Org. Geochem., 2007, vol. 38, no. 11, p. 1927.CrossRefGoogle Scholar
  16. 16.
    Andersson, R.A. and Meyers, P.A., Org. Geochem., 2012, vol. 53, p. 63.CrossRefGoogle Scholar
  17. 17.
    Bertrand, O., Mansuy-Huault, L., Montarges-Pelletier, E., Losson, B., Argant, J., Ruffaldi, P., Etienne, D., Garnier, E., Dezileau, L., Faure, P., and Michels, R., Org. Geochem., 2012, vol. 50, p. 1.CrossRefGoogle Scholar
  18. 18.
    Xie, S., Nott, C.J., Avsejs, L.A., Maddy, D., Chambers, F.M., and Evershed, R.P., Geochim. Cosmochim. Acta, 2004, vol. 68, no. 13, p. 2849.CrossRefGoogle Scholar
  19. 19.
    Ortiz, J.E., Gallego, J.L.R., Torres, T., Diaz-Bautista, A., and Sierra, C., Org. Geochem., 2010, vol. 41, no. 5, p. 454.CrossRefGoogle Scholar
  20. 20.
    Bush, R.T. and McInerney, F.A., Geochim. Cosmochim. Acta, 2013, vol. 117, p. 161.CrossRefGoogle Scholar
  21. 21.
    Brodskii, E.S., in Metody issledovaniya sostava organicheskikh soedinenii nefti i bitumoidov (Methods for Studying the Composition of Organic Compounds of Oils and Bitumens), Gal’pern, G.D., Ed., Moscow: Nauka, 1985, p. 57.Google Scholar
  22. 22.
    Brodskii, E.S., Lukashenko, I.M., Kalinkevich, G.A., and Savchuk, S.A., J. Anal. Chem., 2002, vol. 57, no. 6, p. 486.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • E. S. Brodskii
    • 1
    Email author
  • A. A. Shelepchikov
    • 1
  • E. Ya. Mir-Kadyrova
    • 1
  • G. A. Kalinkevich
    • 1
  1. 1.Severtsov Institute of Ecology and EvolutionRussian Academy of SciencesMoscowRussia

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