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Gas chromatographic determination of benzothiophenes in high-purity sulfur

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Abstract

A procedure is developed for the determination of benzothiophene, dibenzothiophene, and 4,6-dimethyldibenzothiophene in high-purity sulfur, including liquid-phase microextraction preconcentration, identification by gas chromatography−mass spectrometry, and gas chromatographic determination with flame photometric detection. The rate of microextraction recovery was from 16 to 78%. The limits of detection were 8 × 10–5 wt % for benzophiophene and 2 × 10–5 wt % for dibenzothiophene and 4,6-dimethyldibenzothiophene.

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References

  1. Devyatykh, G.G., Churbanov, M.F., Vysokochistye khal’kogeny (High-Purity Chalcogenes), Nizhnii Novgorod Nizhegorod. Gos. Univ. im. N.I. Lobachevskogo, 1997.

    Google Scholar 

  2. Menkovskii, M.A. and Yavorskii, V.G., Tekhnologiya sery (Technology of Sulfur), Moscow Khimiya, 1983.

    Google Scholar 

  3. Egorov, A.P., Shereshevskii, A.A., Shmankov, I.V., Obshchaya khimicheskaya tekhnologiya neorganicheskikh veshchestv (General Chemical Technology of Inorganic Substances), Moscow Khimiya, 1964.

    Google Scholar 

  4. Devyatykh, G.G. and Churbanov M.F., Vysokochist. Veshchestva, 1990, no. 1, p. 32.

    Google Scholar 

  5. Krylov, V.A., Vysokochist. Veshchestva, 1994, no. 5, p. 116.

    Google Scholar 

  6. Ezheleva, A.E., Malygina, L.S., and Churbanov, M.F., Zh. Anal. Khim., 1982, vol. 37, no. 8, p. 1502.

    CAS  Google Scholar 

  7. Alekeseeva, N.M. and Shushkanova, I.M., Zavod. Lab., 1961, vol. 27, no. 7, p. 811.

    Google Scholar 

  8. USSR Inventor’s Certificate no. 1807354, 1993.

  9. Schumann, R., Chem. Technol. (DDR), 1990, vol. 42, no. 1, p. 31.

    CAS  Google Scholar 

  10. Kato, A., Osumi, Y., and Mijake, Y., Bull. Govt. Inv. Res. Inst. Osaka, 1972, vol. 23, no. 9, p. 81.

    CAS  Google Scholar 

  11. Feher, F., Lutz, H.D., and Obst, K., Z. Anal. Chem., 1967, vol. 224, p. 407.

    Article  CAS  Google Scholar 

  12. Zimakov, I.E., Karavanov, N.A., and Il’ina, T.S., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1992, vol. 35, no. 10, p. 45.

    CAS  Google Scholar 

  13. Churbanov, M.F., Chugunova, S.G., and Devyatykh, G.G., Zh. Anal. Khim., 1973, vol. 28, no. 2, p. 385.

    CAS  Google Scholar 

  14. GOST (State Standard) 127.2-93: Sulphur for Industrial Use. Test Methods, Moscow: Izd. Standartov, 1996.

  15. GOST (State Standard) 30355.1-96 (ISO 2866-74): Sulphur for Industrial Use. Determination of Total Carbon Content. Titrimetric Method, Moscow: Izd. Standartov, 1999.

  16. Krylov, V.A., Volkova, V.V., and Savel’eva, O.A., Analitika Kontrol’, 2013, vol. 17, no. 1, p. 81.

    Google Scholar 

  17. Colón, L.A. and Baird, L.J., Detectors in Modern Practice of Gas Chromatography, Grob, R.L. and Barry, E.F., Eds., Hoboken, NJ: Wiley, 2004, 4th ed.

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Authors and Affiliations

  1. Faculty of Chemistry, Lobachevsky State University, Nizhny Novgorod, 603950, Russia

    V. A. Krylov & M. F. Churbanov

  2. Devyatykh Institute of Chemistry of High-Purity Substances, Russian Academy of Sciences, Nizhny Novgorod, 603950, Russia

    M. F. Churbanov, O. Yu. Chernova & A. Yu. Sozin

Authors
  1. V. A. Krylov
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  2. M. F. Churbanov
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  3. O. Yu. Chernova
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  4. A. Yu. Sozin
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Correspondence to V. A. Krylov.

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Original Russian Text © V.A. Krylov, M.F. Churbanov, O.Yu. Chernova, A.Yu. Sozin, 2017, published in Zhurnal Analiticheskoi Khimii, 2017, Vol. 72, No. 6, pp. 552–556.

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Krylov, V.A., Churbanov, M.F., Chernova, O.Y. et al. Gas chromatographic determination of benzothiophenes in high-purity sulfur. J Anal Chem 72, 639–643 (2017). https://doi.org/10.1134/S1061934817060089

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  • DOI: https://doi.org/10.1134/S1061934817060089

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