Advertisement

Journal of Analytical Chemistry

, Volume 72, Issue 5, pp 551–556 | Cite as

Amalgamation performances of gold-coated quartz wool, alumina, silica, sand and carbon fiber for the determination of inorganic mercury in waters by cold vapor atomic absorption spectrometry

  • Arzu Erdem Şimşek
  • Aslı Erdem Yayayürük
  • Talal Shahwan
  • Ahmet E. Eroğlu
Articles
  • 56 Downloads

Abstract

Different gold-coated sorbents for amalgamation were applied for the determination of inorganic mercury in waters using a home-made cold vapor generation unit coupled to atomic absorption spectrometry. Among the gold-coated materials investigated (quartz wool, alumina, silica, sand and carbon fiber) quartz wool was found to give the most efficient results in terms of sorption and release. Analytical performance of the system without and with amalgamation was investigated and it was found that when amalgamation was applied, the linearity and slope of the calibration plots were independent on the sample volume for 1.0, 5.0 and 10.0 mL. Method validation was realized through the analysis of a sample of spring water spiked with 1.0 μg/L inorganic mercury and the spike recoveries were found to be 95 ± 1, 91 ± 3, and 99 ± 5% for 1.0, 5.0, and 10.0 mL, respectively. The results demonstrated that the methodology can be applied to these types of samples directly or after amalgamation, depending on the mercury concentration.

Keywords

mercury amalgamation gold-coated sorbents preconcentration cold vapor atomic absorption spectrometry 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Dakova, I., Karadjova, I., Georgieva, V., and Georgiev, G., Talanta, 2009, vol. 78, p. 523.CrossRefGoogle Scholar
  2. 2.
    Hamza, A., Bashammakh, A.S., AlSibaai, A.A., Al Saidi, H.M., and El Shahawi, M.S., J. Hazard. Mater., 2010, vol. 178, p. 287.CrossRefGoogle Scholar
  3. 3.
    Andac, M., Mirel, S., Senel, S., Say, R., Ersoz, A., and Denizli, A., Int. J. Biol. Macromol., 2007, vol. 40, p. 159.CrossRefGoogle Scholar
  4. 4.
    Stanisz, E., Justyna Werner, J., and Matusiewicz, H., Microchem. J., 2013, vol. 110, p. 28.CrossRefGoogle Scholar
  5. 5.
    Soleimani, M. and Afshar, M.G., J. Anal. Chem., 2015, vol. 70, no. 1, p. 5.CrossRefGoogle Scholar
  6. 6.
    Environmental Protection Agency, 2010, vol. 75, no. 59, p. 15504.Google Scholar
  7. 7.
    European Union (Drinking Water) Regulations, 2014, S.I. no. 122.Google Scholar
  8. 8.
    Alonso, E.V., Cordero, M.T.S., Torres, A.G., Rudner, P.C., and Pavon, J.M.C., Talanta, 2008, vol. 77, p. 53.CrossRefGoogle Scholar
  9. 9.
    Geng, W., Nakajima, T., Takanashi, H., and Ohki, A., J. Hazard. Mater., 2008, vol. 154, p. 325.CrossRefGoogle Scholar
  10. 10.
    Yayayuruk, O., Henden, E., and Bicak, N., Anal. Sci., 2011, vol. 27, no. 8, p. 833.CrossRefGoogle Scholar
  11. 11.
    Welz, B. and Sperling, M., Atomic Absorption Spectrometry, Weinheim: Wiley, 1999, 3rd ed.Google Scholar
  12. 12.
    Labatzke, T. and Schlemmer, G., Anal. Bioanal. Chem., 2004, vol. 378, no. 4, p. 1075.CrossRefGoogle Scholar
  13. 13.
    Zierhut, A., Leopold, K., Harwardt, L., Worsfold, P., and Schuster, M., J. Anal. At. Spectrom., 2009, vol. 24, no. 6, p. 767.CrossRefGoogle Scholar
  14. 14.
    Rivaro, P., Ianni, C., Soggia, F., and Frache, R., Microchim. Acta, 2007, vol. 158, p. 345.CrossRefGoogle Scholar
  15. 15.
    Cossa, D., Sanjuan, J., Cloud, J., Stockwell, P.B., and Corns, W.T., J. Anal. At. Spectrom., 1995, vol. 10, p. 287.CrossRefGoogle Scholar
  16. 16.
    Liang, L. and Bloom, N.S., J. Anal. At. Spectrom., 1993, vol. 8, p. 591.CrossRefGoogle Scholar
  17. 17.
    Aeschliman, D.B. and Norton, G.A., Environ. Sci. Technol., 1999, vol. 33, p. 2278.CrossRefGoogle Scholar
  18. 18.
    Magalhaes, C.E.C., Krug, F.J., Fostier, A.H., and Berndt, H., J. Anal. At. Spectrom., 1997, vol. 12, p. 1231.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • Arzu Erdem Şimşek
    • 1
  • Aslı Erdem Yayayürük
    • 2
  • Talal Shahwan
    • 3
  • Ahmet E. Eroğlu
    • 1
  1. 1.Department of Chemistryİzmir Institute of TechnologyUrla-İzmirTurkey
  2. 2.Department of ChemistryEge UniversityBornova-IzmirTurkey
  3. 3.Department of ChemistryBirzeit UniversityRamallah, West BankPalestine

Personalised recommendations