Complex formation of thiocyanate ions with iron(III) on the solid phase of fibrous ion exchangers
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Characteristics of complex formation of SCN–-ions with iron(III) on fibrous materials filled with an AV-17 anion exchanger (PANV–AV-17) and a KU-2 cation exchanger (PANV–KU-2) are studied by diffuse reflection spectroscopy. Sorption conditions of thiocyanate ions on PANV–AV-17 in the dynamic mode and the influence of concentrations of Cl–, SO 4 2- and NO 3 - on the sorption and analytical signals of thiocyanate complexes are studied. Sorption conditions of iron(III) on PANV–KU-2 and the conditions of formation of thiocyanate complexes are studied. Systems for the sorption–spectroscopic determination of 0.1–0.7 μg/mL of SCN–-ions in aqueous solutions of pH 5 ± 1 on PANV–AV-17 and test-determination of 5–30 μg of SCN–-ions on PANV–KU-2 are proposed.
Keywordsdiffuse reflection spectroscopy PANV–KU-2 PANV–AV-17 iron(III) thiocyanate ions
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