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Determination of gold and palladium in rocks and ores by atomic absorption spectrometry using two-stage probe atomization

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Abstract

The efficiency of two-stage probe atomization for the determination of gold and palladium in geological samples by electrothermal atomic absorption spectrometry is studied. The effects of temperature–time program and the position of the probe in an atomizer on the fractionation of sample components and the magnitude of the analytical signal are studied. It is demonstrated that gold and palladium can be quantitatively determined by atomic absorption spectrometry in rocks and ores, using a two-stage probe atomization with the limits of detection for gold and palladium 0.01 and 0.04 g/t, respectively.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    A. V. Volzhenin, N. I. Petrova, N. S. Medvedev & A. I. Saprykin

  2. Kazan Federal University, Kazan, 420008, Russia

    D. S. Irisov

  3. Novosibirsk State University, Novosibirsk, 630090, Russia

    A. I. Saprykin

Authors
  1. A. V. Volzhenin
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  2. N. I. Petrova
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  3. N. S. Medvedev
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  4. D. S. Irisov
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  5. A. I. Saprykin
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Correspondence to A. V. Volzhenin.

Additional information

Original Russian Text © A.V. Volzhenin, N.I. Petrova, N.S. Medvedev, D.S. Irisov, A.I. Saprykin, 2017, published in Zhurnal Analiticheskoi Khimii, 2017, Vol. 72, No. 2, pp. 129–136.

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Volzhenin, A.V., Petrova, N.I., Medvedev, N.S. et al. Determination of gold and palladium in rocks and ores by atomic absorption spectrometry using two-stage probe atomization. J Anal Chem 72, 156–162 (2017). https://doi.org/10.1134/S1061934817020150

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  • DOI: https://doi.org/10.1134/S1061934817020150

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