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Determination of gasoline and diesel residues on wool, silk, polyester and cotton materials by SPME–GC–MS

Abstract

The identification of ignitable liquids is very important and challenging aspect in arson crime investigations. The detection of gasoline and diesel fuel components using solid phase micro-extraction prior to gas chromatography–mass spectrometry for the forensic analysis of fire debris has been carried out. Previous works show that the absorption characteristics of the substrate are one of the most important factors in determining the evaporation rate of the accelerants. In order to determine the presence of the fuel residues, four of the most common substrate materials were tested in this work; wool, cotton, silk and polyester. The obtained results indicate that both gasoline and diesel fuel accelerants persisted longer on wool and silk than on the other selected substrates. Such information illustrates the influence of fuel persistence times after extinguishing and the best materials to be scanned for ignitable liquids at the fire scene.

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References

  1. Campbell, R., Intentional Fires, Quincy, MA: Natl. Fire Protection Assoc., Fire Anal. Res. Division, 2014.

    Google Scholar 

  2. De Haan, J.D. and Icove, D.J., Kirk’s Fire Investigation, Upper Saddle River: Pearson, 2012, 7th ed., ch. 1.

    Google Scholar 

  3. Bertsch, W. and Zhang, Q.W., Anal. Chim. Acta, 1990, vol. 236, p. 183.

    Article  CAS  Google Scholar 

  4. Muller, D., Levy, A., and Shelef, R., Forensic Sci. Int., 2011, vol. 206, p. 150.

    Article  CAS  Google Scholar 

  5. Pert, A.D., Baron, M.G., and Birkett, J.W., J. Forensic Sci., 2006, vol. 51, p. 1033.

    Article  CAS  Google Scholar 

  6. Lu, Y., Chen, P., and Harrington, P.B., Anal. Bioanal. Chem., 2009, vol. 394, p. 2061.

    Article  CAS  Google Scholar 

  7. Sigman, M.E. and Williams, M.R., Anal. Chem., 2006, vol. 78, p. 1713.

    Article  CAS  Google Scholar 

  8. Borusiewicz, R., Zadora, G., and Zieba-Palus, J., Chromatographia, 2004, vol. 60, p. S133.

    Article  CAS  Google Scholar 

  9. Ahmad, U.K. and Voon, C.K., Malays. J. Anal. Sci., 2001 vol. 7, p. 57.

    Google Scholar 

  10. Baechler, S., Comment, S., and Delemont, O., Talanta, 2010, vol. 82, p. 1247.

    Article  CAS  Google Scholar 

  11. Tan, B., Hardy, J.K., and Snavely, R.E., Anal. Chim. Acta., 2000, vol. 422, p. 37.

    Article  CAS  Google Scholar 

  12. Choodum, A. and Daeid, N.N., Anal. Methods, 2011, vol. 3, p. 1136.

    Article  CAS  Google Scholar 

  13. Smale, T., Arthur, I., and Royds, D., Aust. J. Forensic Sci., 2014, vol. 46, p. 216.

    Article  Google Scholar 

  14. Borusiewicz, R., Zieba-Palus, J., and Zadora, G., Forensic Sci. Int., 2006, vol. 160, p. 115.

    Article  CAS  Google Scholar 

  15. Choodum, A. and Daeid, N.N., Anal. Methods, 2011, vol. 3, p. 1525.

    Article  CAS  Google Scholar 

  16. Jayatilaka, A. and Poole, C.F., Chromatographia, 1994, vol. 39, p. 200.

    Article  CAS  Google Scholar 

  17. Arthur, C.L. and Pawliszyn, J., Anal. Chem., 1990, vol. 62, p. 2145.

    Article  CAS  Google Scholar 

  18. Pawliszyn, J., J. Chromatogr. Sci., 2000, vol. 38, p. 270.

    Article  CAS  Google Scholar 

  19. Furton, K.G., Almirall, J.R., Bi, M., Wang, J., and Wu, L., J. Chromatogr. A, 2000, vol. 885, p. 419.

    Article  CAS  Google Scholar 

  20. Dhabbah, A.M., Al-Jaber, S.S., Al-Ghamdi, A.H., and Aqel, A., Arabian J. Sci. Eng., 2014, vol. 39, p. 6749.

    Article  CAS  Google Scholar 

  21. Calderara, S., Gardebas, D., and Martinez, F., Forensic Sci. Int., 2003, vol. 137, p. 6.

    Article  CAS  Google Scholar 

  22. Almirall, J.R., Bruna, J., and Furton, K.G., Sci. Justice, 1996, vol. 36, p. 283.

    Article  CAS  Google Scholar 

  23. Furton, K.G., Bruna, J., and Almirall, J.R., J. High Resolut. Chromatogr., 1995, vol. 18, p. 625.

    Article  CAS  Google Scholar 

  24. Darrer, M., Jacquemet-Papilloud, J., and Delemont, O., Forensic Sci. Int., 2008, vol. 175, p. 171.

    Article  CAS  Google Scholar 

  25. Whyte, C., Wyche, K.P., Kholia, M., Ellis, A.M., and Monks, P.S., Int. J. Mass Spectrom., 2007, vol. 263, p. 222.

    Article  CAS  Google Scholar 

  26. Bodle, E. and Hardy, J.K., Anal. Chim. Acta, 2007, vol. 589, p. 247.

    Article  CAS  Google Scholar 

  27. Monfreda, M. and Gregori, A., J. Forensic Sci., 2011, vol. 56, p. 372.

    Article  CAS  Google Scholar 

  28. Sandercock, P.M., Forensic Sci. Int., 2008, vol. 176, p. 93.

    Article  CAS  Google Scholar 

  29. Agata, S., Michal, P., Adam, K., and Jacek, N., Chem. Soc. Rev., 2010, vol. 39, p. 4524.

    Article  Google Scholar 

  30. Vas, G. and Vekey, K., J. Mass Spectrom., 2004, vol. 39, p. 233.

    Article  CAS  Google Scholar 

  31. Bell, S., Forensic Chemistry, New York: Prentice Hall, 2005.

    Google Scholar 

  32. Pawliszyn, J., Solid Phase Microextraction: Theory and Practice, New York: Wiley, 1997.

    Google Scholar 

  33. Wercinski, S.A., Solid Phase Extraction: A Practical Guide, New York: Marcel Dekker, 1999.

    Book  Google Scholar 

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Correspondence to Ahmad Aqel.

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Aqel, A., Dhabbah, A.M., Yusuf, K. et al. Determination of gasoline and diesel residues on wool, silk, polyester and cotton materials by SPME–GC–MS. J Anal Chem 71, 730–736 (2016). https://doi.org/10.1134/S1061934816070029

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  • DOI: https://doi.org/10.1134/S1061934816070029

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