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Adsorption of Eu(III) ions on silicas with noncovalently immobilized thiacalix[4]arene derivatives

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Abstract

Using the noncovalent immobilization of some thiacalix[4]arene derivatives on the surface of silanized silica, we obtained efficient adsorption materials for the extraction of Eu(III) ions from aqueous solutions of medium mineralization. The specific surface area of the adsorbents is 200–370 m2/g. It is shown that adsorbents containing thiacalix[4]arenes with phosphoryl groups selectively extract up to 99% of europium ions from aqueous solutions at pH 5.5–6; they are characterized by adsorption capacity of 7.5–14.5 mg/g and high distribution coefficients. The studied adsorbents exhibit high selectivity with respect to Eu(III) ions, wherein the distribution coefficients for Cs, Sr, Tb(III), Sm(III), Gd(III), La(III), and UO 2+2 are five times or more smaller.

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Authors and Affiliations

  1. Science and Technology Complex “Institute of Single Crystals”, National Academy of Sciences of Ukraine, pr. Lenina 60, Kharkov, 61178, Ukraine

    M. S. Lukashova, K. N. Belikov, K. Yu. Bryleva, I. B.-Kh. Shcherbakov & A. N. Slyusarev

  2. Institute of Organic Chemistry, the National Academy of Sciences of Ukraine, Murmanskaya ul. 5, Kyiv, 02660, Ukraine

    S. G. Kharchenko & V. I. Kal’chenko

  3. Faculty of Chemistry, Karazin National University, Kharkiv, pl. Svobody 4, Kharkiv, 61000, Ukraine

    K. N. Belikov

  4. Faculty of Chemistry, Taras Shevchenko National University, Kyiv, Vladimirskaya ul. 62, Kyiv, 01033, Ukraine

    O. A. Beda

Authors
  1. M. S. Lukashova
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  2. S. G. Kharchenko
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  3. K. N. Belikov
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  4. K. Yu. Bryleva
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  5. V. I. Kal’chenko
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  6. I. B.-Kh. Shcherbakov
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  7. A. N. Slyusarev
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  8. O. A. Beda
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Corresponding author

Correspondence to M. S. Lukashova.

Additional information

Original Russian Text © M.S. Lukashova, S.G. Kharchenko, K.N. Belikov, K.Yu. Bryleva, V.I. Kal’chenko, I.B.-Kh. Shcherbakov, A.N. Slyusarev, O.A. Beda, 2016, published in Zhurnal Analiticheskoi Khimii, 2016, Vol. 71, No. 5, pp. 499–504.

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Lukashova, M.S., Kharchenko, S.G., Belikov, K.N. et al. Adsorption of Eu(III) ions on silicas with noncovalently immobilized thiacalix[4]arene derivatives. J Anal Chem 71, 476–481 (2016). https://doi.org/10.1134/S1061934816050063

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  • DOI: https://doi.org/10.1134/S1061934816050063

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