Abstract
An efficient, highly sensitive, fast and selective kinetic method for determination of traces of Cu(II) was developed and applied for its quantification in different real samples. The method was based on the catalytic effect of Cu(II) traces on the redox reaction of artificial azo-dye tartrazine (tri-sodium-5-hydroxy-1-(4-sulfophenyl)-4-[(4-sulfophenyl)azo]pyrazole-3-carboxylate) with H2O2. The optimum operating conditions regarding reagent concentration were examined and established. Linearity of the method was obtained in the concentration range from 13 to 318 ng/mL of Cu(II), with a detection limit (LOD) (3s b/m) of 2 ng/mL, and limit of quantification (LOQ) (10s b/m) of 7 ng/mL. Obtained results for Cu(II) determination in analyzed samples, as well as the development and validation of the proposed analytical procedure are given and discussed.
Similar content being viewed by others
References
Aksuner, N., Basaran, B., Henden, E., Yilmaz, I., and Cukurovali, A., Dyes and Pigments, 2011, vol. 88, no. 2, p. 143.
Clark, A.C. and Scollary, G.R., Anal. Chim. Acta, 2000, vol. 25, p. 413.
Rajeev, J., Meenakshi, B., and Nidhi, S., Industrial & Engineering Chemistry Research, 2003, vol. 42, p. 243.
Mitic, S.S., Micic, R.J., and Simonovic, R.M., Food Chem., 2009, vol. 117, p. 461.
Reddy, S.A., Reddy, K.J., Narayana, S.L., and Reddy, A.V., Food Chem., 2008, vol. 109, p. 654.
Moreno-Cid, A. and Yebra, M.C., Spectrochim. Acta B, 2002, vol. 57, p. 967.
Anthemidis, A., Zachariadis, G., and Stratis, J., Talanta, 2001, vol. 54, p. 935.
Ferreira, S., Ferreira J., Dantas, A., Lemos, V., Araujo, N., and Costa, A., Talanta, 2000, vol. 50, p. 1253.
Chen, J., Liu, X., and Mao, H., Anal. Chim. Acta, 1998, vol. 370, no. 11, p. 151.
Pinto, J., Moreno, C., and Vargas, M.G., Talanta, 2004, vol. 64, p. 562.
Queiroz, Z., Rocha, F., Knapp, G., and Krug, F., Anal. Chim. Acta, 2002, vol. 463, p. 275.
Bermejo, P., Peña, E., Fompedriña, D., Domímguez, R., Bermejo, A., Fraga, J.M., and Cocho, J.A., Analyst, 2001, vol. 126, p. 571.
Pomazal, K., Prohaska, C., Steffan, I., Reich, G., and Huber, J.F.K., Analyst, 1999, vol. 124, p. 657.
Zeng, A., Liu, E., Tan, S., Zhang, J., and Gao, J., Electroanalysis, 2002, vol. 14, no. 18, p. 1294.
Agra-Gutiérrez, C., Hardcastle, J.L., Ball, J.C., and Compton, R.G., Analyst, 1999, vol. 124, p. 1053.
Ajtony, Z., Szoboszlai, N., Susko, E.K., Mezei, P., Gyorgy, K., and Bencs, L., Talanta, 2008, vol. 76, p. 627.
Moreno, I.M., Gonzalez-Weller, D., Gutierrez, V., Marino, M., Camean, A.M., Gonzalez, A.G., and Hardisson, A., Microchem. J., 2008, vol. 88, p. 56.
Taylor, V.F., Longerich, H.P., and Greenough. J.G., J. Food Chem., 2003, vol. 51, p. 856.
Magni, D.M., Olivieri, A.C., and Bonivardi, A.L., Anal. Chim. Acta, 2005, vol. 528, p. 275.
Khan, M.N. and Sarwar, A., Anal. Sci., 2001, vol. 17, p. 1195.
Crespo, G.A., Andrade, F.J., Inon, F.A., and Tudino, M.B., Anal. Chim. Acta, 2005, vol. 539, p. 317.
Prasad, S. and Halafihi, T., Microchim Acta, 2003, vol. 142, p. 237.
Prasad, S., Anal. Chim. Acta, 2005, vol. 540, p. 173.
Rustoiu-Csavdari, A., Mihai, D., and Baldea, I., Anal. Bioanal. Chem., 2005, vol. 381, p. 1373.
Wei, J., Teshima, N., Ohno, S., and Sakai, T., Anal. Sci., 2003, vol. 19, p. 731.
Mitic, S., Miletic, G., and Obradovic, M., Spectrosc. Lett., 2003, vol. 37, p. 43.
Tosic, S., Mitic, S., Obradovic, M., and Sunaric, S., Oxidation Communication, 2004, vol. 27, p. 728.
Tomiyacu, T., Aikou, S., Anazawa, K., and Sakamoto, H., Anal. Sci., 2005, vol. 21, p. 917.
Oho, S., Teshima, N., Zhang, H., and Sakai, T., Talanta, 2003, vol. 60, p. 1177.
Grahovac Z., Mitic S., and Pecev, E., J. Serb. Chem. Soc., 2003, vol. 68, p. 219.
Skine, Y., Shitanda, I., Itagaki, M., Watanabe, K., Nakano, S., and Kawashima, T., Microchim. Acta, 2010, vol. 170, p. 113.
Lurye, U.U., Spravocnik po analiticheskoi khimii, (Handbook on analytical Chemistry) Moscow: Kimiia, 1989, p. 273 (in Rus.).
Terrab, A., Hernanz, D., and Heredia, F.J., J Agri. Food Chem., 2004, vol. 52, no.11, p. 3441.
Pyatnitskii, I.V. and Sukhan, V.V., Masking and demasking in analytical chemistry, Moscow: Nauka, 1990, p. 14 (in Rus.).
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Micić, R.J., Mitić, S.S., Pavlović, A.N. et al. Application of tartrazine for sensitive and selective kinetic determination of Cu(II) traces. J Anal Chem 69, 1147–1152 (2014). https://doi.org/10.1134/S1061934814120107
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061934814120107