Skip to main content
SpringerLink
Log in

Detection of salicylic acid by electrocatalytic oxidation at a nickel-modified glassy carbon electrode

  • Articles
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

An electrochemical biosensor for the accurate determination of salicylic acid (SA) is prepared by potentiostatic deposition of nickel on the glassy carbon electrode (GCE). The electrochemical performance of the Ni/GCE film and the parameters affecting its activity are investigated by cyclic voltammetry, amperometry and electrochemical impedance spectroscopy (EIS). The electrooxidation of SA is significantly enhanced on Ni/GCE, compared to GCE. Indeed, the modified electrode has a fast response (less than 3 s) and excellent linear behavior over a wide SA concentration range (2 μM-0.55 mM) with a detection limit (LD) of 0.5 μM (signal/noise = 3) under the optimal conditions. Moreover, the stability and the reproducibility of the biosensor are satisfactorily evaluated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Mikami, E., Goto, T., Ohno, T., Matsumoto, H., and Nishida, M., J. Pharm. Biomed. Anal., 2002, vol. 28, no. 7, p. 261.

    Article  CAS  Google Scholar 

  2. Abdolmohammad-Zadeh, H., Kohansal, S., and Sadeghi, G.H., Talanta, 2011, vol. 84, no. 6, p. 368.

    Article  CAS  Google Scholar 

  3. Ruiz-Medina, A., Fernàndez-de Córdova, M.L., Ortega-Barrales, P., and Molina-Díaz, A., Int. J. Pharm., 2001, vol. 216, no. 10, p. 95.

    Article  CAS  Google Scholar 

  4. Kokot, Z. and Burda, K., J. Pharm. Biomed. Anal., 1998, vol. 18, no. 5, p. 871.

    Article  CAS  Google Scholar 

  5. Marcelo, M.S., Marcello, G.T., and Ronei, J.P., Talanta, 2006, vol. 68, no. 6, p. 1707.

    Google Scholar 

  6. Kees, F., Jehnich, D., and Grobecker, H., J. Chromatogr. B, 1996, vol. 677, no. 6, p. 172.

    Article  Google Scholar 

  7. Jena, J.F., Tsaia, Y.Y., and Yang, T.C., J. Chromatogr. A, 2001, vol. 912, no. 5, p. 39.

    Article  Google Scholar 

  8. Kakkar, T. and Mayersohn, M., J. Chromatogr. B, 1998, vol. 718, no.7, p. 69.

    Article  CAS  Google Scholar 

  9. Rivas, G.A. and Calatayud, J.M., Talanta, 1995, vol. 212, no. 5, p. 1285.

    Article  Google Scholar 

  10. Wang, Z., Wei, F., Liu, S.Y., Xu, Q., Huang, J.Y., Dong, X.Y., Yu, J.H., Yang, Q., Zhao, Y.D., and Chen, H., Talanta, 2010, vol. 80, no. 5, p. 1277.

    Article  CAS  Google Scholar 

  11. Wang, Z., Ai, F., Xu, Q., Yang, Q., Yu, J.H., Huang, W.H., and Zhao, Y.D., Colloids. Surf. B, 2010, vol. 76, no. 5, p. 370.

    Article  CAS  Google Scholar 

  12. Tian, L., Bian J., Wang, B., and Qi, Y., Electrochim Acta, 2010, vol. 55, no. 6, p. 3083.

    Article  CAS  Google Scholar 

  13. Shakkthivel, P. and Chen, S.M., Biosens. Bioelectron., 2007, vol. 22, no. 8, p. 1680.

    Article  CAS  Google Scholar 

  14. Arvinte, A., Westermann, A.C., Sesay, A.M., and Virtanen, V., Sens. Actuators, B, 2010, vol. 150, no. 8, p. 756.

    Article  CAS  Google Scholar 

  15. Bian, L.J., Zhang, J.H., Qi, J., Liu, X.X., Dermot, D., and Lau, K.T., Sens. Actuators, B, 2010, vol. 147, no. 5, p. 73.

    Article  CAS  Google Scholar 

  16. Adekunle, A.S., Agboola, B.O., Pillay, J., and Ozoemen, K.I., Sens. Actuators, B, 2010, vol. 148, no. 10, p. 93.

    Article  CAS  Google Scholar 

  17. Yi, Q., Huang, W., Zhang, J., Liu, X., and Li, L., J. Electroanal. Chem., 2007, vol. 610, no. 8, p. 163.

    Article  CAS  Google Scholar 

  18. Jafarian, M., Forouzandeh, F., Danaee, I., and Gobal, F., J. Solid State Electrochem., 2009, vol. 13, no. 9, p. 1171.

    Article  CAS  Google Scholar 

  19. Safavi, A., Maleki, N., and Farjami, E., Biosens. Bioelectron., 2009, vol. 24, no. 6, p. 1655.

    Article  CAS  Google Scholar 

  20. Qiu, C., Shang, R., Xie, Y., Bu, Y., Li, C., and Ma, H., Mater. Chem. Phys., 2010, vol. 120, no. 8, p. 323.

    Article  CAS  Google Scholar 

  21. Danae, I., Jafarian, M., Forouzandeh, F., Gobal, F., and Mahjania, M.G., Int. J. Hydrogen Energy, 2008, vol. 33, no. 10, p. 4367.

    Article  Google Scholar 

  22. Bard, A.J. and Faulkner, L.R., Electrochemical Methods, Fundamentals and Applications, Wiley, New York, 2001.

    Google Scholar 

  23. Gualandi, I., Scavetta, E., Zappoli, S., and Tonelli, D., Biosens. Bioelectron., 2011, vol. 26, no. 7, p. 3200.

    Article  CAS  Google Scholar 

  24. Torriero, A.A.J., Luco, J.M., Sereno, L., and Raba, J., Talanta, 2004, vol. 62, no. 6, p. 247.

    Article  CAS  Google Scholar 

  25. Zhang, W.D., Xu, B., Hong, Y.X., Yu, Y.X., Ye, J.S., and Zhang, J.Q., J. Solid State Electrochem., 2010, vol. 14, no. 6, p. 1713.

    Article  CAS  Google Scholar 

  26. Kutner, W., Wang, J., Lher, M., and Buck, R.P., Pure Appl. Chem., 1998, vol. 70, no. 18, p. 1301.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratory of Electrochemistry-Corrosion, Metallurgy and Inorganic Chemistry, Faculty of Chemistry (USTHB), BP 32, El Alia, Algiers, 16111, Algeria

    M. Doulache & A. Benchettara

  2. Laboratory of storage and valorization of renewable Energies, Faculty of chemistry (USTHB), BP 32, El Alia, 16111, Algiers, Algeria

    M. Trari

Authors
  1. M. Doulache
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Benchettara
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Trari
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Doulache, M., Benchettara, A. & Trari, M. Detection of salicylic acid by electrocatalytic oxidation at a nickel-modified glassy carbon electrode. J Anal Chem 69, 51–56 (2014). https://doi.org/10.1134/S1061934814010067

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934814010067

Keywords

Search

Navigation