Abstract
The results of a study on interfacing an Orbitrap mass analyzer with direct ion injection to a surface assisted laser desorption/ionization (SALDI) ion source are presented. Osmium complexes with 8-mercaptoquinoline were studied. Titanium oxide thin films prepared by electron beam evaporation were found an effective emitter of the ions of the test complexes. It was demonstrated that interfacing the Orbitrap mass analyzer to a SALDI source can significantly improve the analytical performance of this method in comparison to a typical combination of SALDI/time-of-flight mass spectrometer.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Sunner, J., Dratz, E., and Chen, Y.C., Anal. Chem., 1995, Vol. 67, no. 23, p. 4335.
Alimpiev, S., Grechnikov, A., Sunner, J., Karavanskii, V., Zhabin, S., Simanovsky, Ya., and Nikiforov, S., J. Chem. Phys., 2008, Vol. 128, no. 1, p. 014711.
Zhabin, S.N., Pento, A.V., Grechnikov, A.A., Borodkov, A.S., Sartakov, B.G., Simanovskii, Ya.O., Nikiforov, S.M., and Alimpiev, S.S., Kvantovaya Elektron., 2011, Vol. 41, no. 9, p. 835.
Grechnikov, A.A., Borodkov, A.S., Alimpiev, S.S., Nikiforov, S.M., Simanovskii, Ya.O., and Karavanskii, V.A., J. Anal. Chem., 2010, Vol. 65, no. 14, p. 1504.
Makarov, A., Anal. Chem., 2000, Vol. 72, no. 6, p. 1156.
Makarov, A., Denisov, E., Lange, O., Kholomeev, A., and Horning, S., J. Amer. Soc. Mass Spectrom., 2006, Vol. 17, no. 7, p. 977.
Wei, J., Buriak, J.M., and Siuzdak, G., Nature, 1999, Vol. 399, no. 6733, p. 243.
Alimpiev, S., Grechnikov, A., Sunner, J., Borodkov, A., Karavanskii, V., Simanovsky, Ya., and Nikiforov, S., Anal. Chem., 2009, Vol. 81, no. 3, p. 1255.
Grechnikov, A.A., Borodkov, A.S., Alimpiev, S.S., Nikiforov, S.M., and Simanovskii, Ya.O., J. Anal. Chem., 2013, Vol. 69, no. 1, p. 19.
Hagfeldt, A. and Graetzel, M., Chem. Rev., 1995, Vol. 95, no. 1, p. 49.
Bankovskii, Yu.A., Khimiya vnutrikompleksnykh soedinenii merkaptokhinolina i ego proizvodnykh (Chemistry of Chelate Compounds of Mercaptoquinoline and Its Derivatives), Riga: Zinatne, 1978.
Rose, R., Damoc, E., Denisov, E., Makarov, A., and Heck, A., Nat. Meth., 2012, Vol. 9, no. 11, p. 1084.
Makarov, A. and Denisov, E., J. Amer. Soc. Mass Spectrom., 2009, Vol. 20, no. 8, p. 1486.
Nikiforov, S.M., Simanovskii, Ya.O., Grechnikov, A.A., Pento, A.V., and Alimpiev, S.S., Elektromagn. Volny Elektron. Sist., 2012, no. 4, p. 39.
Alimpiev, S.S., Grechnikov, A.A., Sunner, J., Karavanskii, V.A., Simanovsky, Ya.O., and Nikiforov, S.M., Rapid Commun. Mass Spectrom., 2011, Vol. 25, no. 1, p. 140.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.A. Makarov, A.A. Grechnikov, S.M. Nikiforov, O.A. Tyutyunnik, E.V. Denisov, 2013, published in Mass-spektrometria, 2013, Vol. 10, No. 2, pp. 77–82.
Rights and permissions
About this article
Cite this article
Makarov, A.A., Grechnikov, A.A., Nikiforov, S.M. et al. The Orbitrap mass analyzer with direct ion injection interfaced to a laser desorption/ionization ion source. J Anal Chem 68, 1165–1169 (2013). https://doi.org/10.1134/S1061934813140062
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061934813140062