Skip to main content

A simple and selective spectrophotometric flow injection method for the determination of ultra trace amounts of phenylhydrazine by its inhibition effect on the reaction of victoria blue B and bromate in micellar medium

Journal of Analytical Chemistry volume 68, pages 423–428 (2013)Cite this article

Abstract

In this work, a simple, selective and rapid flow injection method has been developed for the determination of phenylhydrazine. The method is based on its inhibition effect on the reaction of victoria blue B and bromate in acidic micellar medium. The reaction was monitored spectrophotometrically by measuring victoria blue B absorbance at λmax = 632 nm. The reagents and manifold variables, which have influences on the sensitivity, were investigated and the optimum conditions were established. The optimized conditions made it possible to determine phenylhydrazine in the ranges of 7–370 nM with a detection limit of 5 nM and a sample rate of 25 ± 5 samples/h. The proposed method has been successfully applied to the determination of phenylhydrazine in human serum and water samples.

This is a preview of subscription content, access via your institution.

Access options

Buy single article

Instant access to the full article PDF.

39,95 €

Price includes VAT (Finland)

References

  1. Berger, J., J. Appl. Biomed., 2007, vol. 5, p. 125.

    CAS  Google Scholar 

  2. Schulek, E. and Burger, K., Talanta, 1958, vol. 1, p. 344.

    Article  CAS  Google Scholar 

  3. Murty, N.K., Rao, V.J., and Rao, N.V.S., Talanta, 1984, vol. 31, p. 466.

    Article  CAS  Google Scholar 

  4. Hasan, T., Anal. Lett., 1988, vol. 21, p. 633.

    Article  CAS  Google Scholar 

  5. Yatsimirsky, A.K., Yatsimirskaya, N.T., and Kashina, S.B., Anal. Chem., 1994, vol. 66, p. 2232.

    Article  CAS  Google Scholar 

  6. Afkhami, A. and Bahram, M., Talanta, 2006, vol. 68, p. 1148.

    Article  CAS  Google Scholar 

  7. Mosinska, K., Chem. Anal., 1980, vol. 25, p. 859.

    CAS  Google Scholar 

  8. Afkhami, A. and Zarei, A.R., Talanta, 2004, vol. 62, p. 559.

    Article  CAS  Google Scholar 

  9. Mitic, V.D., Nikolic, S.D., and Stankov-Jovanovic, V., J. Serb. Chem. Soc., 2005, vol. 70, p. 987.

    Article  CAS  Google Scholar 

  10. Afkhami, A. and Assl, A.A., Microchem. J., 2001, vol. 69, p. 51.

    Article  CAS  Google Scholar 

  11. Arab Chamjangali, M., Bagherian, G., and Ameri, S., J. Hazard. Mater., 2009, vol. 166, p. 701.

    Article  CAS  Google Scholar 

  12. Khalilzadeh, M. and Karimi-Maleh, H., Anal. Lett., 2010, vol. 43, p. 186.

    Article  CAS  Google Scholar 

  13. Ensafi, A.A., Chamjangali, M., and Rahimi Mansour, H., Talanta, 2002, vol. 55, p. 715.

    Article  Google Scholar 

  14. Alargova, R.G., Kochijashky, I.I., Sierra, M.L., Kwetkat, K., and Zana, R., J. Coll. Inter. Sci., 2001, vol. 235, p. 119.

    Article  CAS  Google Scholar 

  15. Ensafi, A.A. and Keyvanfard, M., Anal. Lett., 2002, vol. 35, p. 423.

    Article  CAS  Google Scholar 

  16. Ensafi, A.A. and Keyvanfard, M., J. Anal. Chem., 2003, vol. 58, p. 1060.

    Article  CAS  Google Scholar 

  17. Keyvanfard, M. and Sharifian, A., J. Anal. Chem., 2006, vol. 61, p. 596.

    Article  CAS  Google Scholar 

  18. Rubio, S. and Perez-Bendito, D., Anal. Chem. Acta, 1989, vol. 224, p. 185.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Majlesi Branch, Islamic Azad University, Isfahan, Iran

    M. Keyvanfard & Kh. Alizad

Authors
  1. M. Keyvanfard
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Kh. Alizad
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

The article is published in the original.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Keyvanfard, M., Alizad, K. A simple and selective spectrophotometric flow injection method for the determination of ultra trace amounts of phenylhydrazine by its inhibition effect on the reaction of victoria blue B and bromate in micellar medium. J Anal Chem 68, 423–428 (2013). https://doi.org/10.1134/S1061934813050109

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934813050109

Keywords

  • phenylhydrazine
  • flow injection analysis
  • spectrophotometry
  • victoria blue B (VB)
  • micellar media