Abstract
We have studied analytical parameters of tetrarhodanozincate-selective film electrodes based on high-lipophilic quaternary ammonium salts: trinonyloctadecylammonium iodide, R-trioctadecylammonium bromide, R-trimethylammonium nitrate, R-tricetylammonium bromide, R-triethylammonium bromide, R-tributylammonium bromide, R-trilaurylammonium bromide, where R is 3,4,5-tris(dodecyloxy)benzyl. A procedure has been developed for the study of the molecular extraction of zinc rhodanide with membrane plasticizers. The applicability of these electrode to zinc determination in solid wastes has been demonstrated.
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Original Russian Text © E.M. Rakhman’ko, Yu.V. Matveichuk, V.V. Yasinetskii, L.S. Stanishevskii, 2013, published in Zhurnal Analiticheskoi Khimii, 2013, Vol. 68, No. 4, pp. 355–362.
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Rakhman’ko, E.M., Matveichuk, Y.V., Yasinetskii, V.V. et al. [Zn(NCS)4]2−-Selective electrodes based on higher quaternary ammonium salts (QAS). J Anal Chem 68, 328–334 (2013). https://doi.org/10.1134/S1061934813040096
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DOI: https://doi.org/10.1134/S1061934813040096