Abstract
Within the problem of the synthesis of silver nanoclusters and nanoparticles in polyether media, systems containing silver nitrate AgNO3 and low-molecular-weight polyethers, poly(ethylene glycol) PEG-400 or oxyethylated glycerol OEG-5, were studied by fast atom bombardment (FAB) mass spectrometry. The formation of stable clusters of polyether oligomers (M m ) with silver cations M m · Ag+ was shown, in agreement with the previous data of laser desorption/ionization. Quantum-chemical DFT calculations have shown that the M m · Ag+ clusters are stabilized by wrapping of the polyether chain around the silver cation with the cation coordinating ether oxygen atoms. Silver nanoclusters were not found in the FAB mass spectra of liquid systems, but Ag + n clusters were detected for silver nanoparticles separated from the reaction medium. No products of chemical transformations of PEG-400 or OEG-5 were observed by FAB. A plausible mechanism of the reduction of silver cations involving nitrate anions is discussed.
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Luo, C., Zhang, Y., Zeng, X., Zeng, Y., and Wang, Y., J. Colloid Interface Sci., 2005, vol. 288, no. 2, p. 444.
Popa, M., Pradel, T., Crespo, D., and Calderyn-Moreno, J.M., Colloids Surf. A, 2007, vol. 303, no. 3, p. 184.
Kim, M., Byun, J.-W., Shin, D.-S., and Lee, Y.-S., Mater. Res. Bull., 2009, vol. 44, no. 2, p. 334.
Kosevich, M.V., Chagovets, V.V., Severinovskaya, O.V., Boryak, O.A., Zobnina, V.G., Shelkovsky, V.S., Orlov, V.V., and Pokrovskiy, V.A., Mass-Spektrometria, 2011, vol. 8, no. 3, p. 201.
Silvert, P.-Y., Herrera-Urbina, R., Duvauchelle, N., Vijayakrishnan, V., and Elhsissen, K.T., J. Mater. Chem., 1996, vol. 6, no. 4, p. 573.
Silvert, P.-Y., Herrera-Urbina, R., and Tekaia-Elhsissen, K., J. Mater. Chem., 1997, vol. 7, no. 2, p. 293.
Díez, I. and Ras, R.H.A., in Springer Series on Fluorescence, Vol. 9: Advanced Fluorescence Reporters in Chemistry and Biology II: Molecular Constructions, Polymers and Nanoparticles, Wolfbeis, O.S., Demchenko, A.P., Eds., Berlin: Springer, 2010.
Andrae, D., Häussermann, U., Dolg, M., Stoll, H., Preuss, H., Theor. Chim. Acta, 1990, vol. 77, no. 2, p. 123.
ChemCraft. http://www.chemcraftprog.com. Accessed April 26, 2011.
Kravtsov, V.A., Massy atomov i energii svyazi yader (Atomic Weighs and Nuclear Binding Energies), Moscow: Atomizdat, 1965.
Gordon, A.J. and Ford, R.A., The Chemist’s Companion: A Handbook of Practical Data, Techniques, and References, New York: Wiley-Interscience, 1972.
Kosevich, M.V., Zobnina, V.G., Zhivotova, E.N., Shmigol’, I.V., Boryak, O.A., Chagovets, V.V., Chekanova, V.V., Zinchenko, A.V., Pokrovskiy, V.A., and Gomori, A., Mass-Spektrometria, 2009, vol. 6, no. 1, p. 7.
Sharpe, P. and Cassady, C.J., Chem. Phys. Lett., 1992, vol. 191, nos. 1–2, p. 111.
Katakuse, I., Ichihara, T., Fujita, Y., Matsuo, T., Sakurai, T., and Matsuda, H., Int. J. Mass Spectrom. Ion Proc., 1985, vol. 67, no. 2, p. 229.
Rele, M., Kapoor, S., Sharma, G., and Mukherjee, T., Phys. Chem. Chem. Phys., 2004, vol. 6, no. 3, p. 590.
Jacob, J.A., Kapoor, S., Biswas, N., and Mukherjee, T., Colloid Surface A: Physicochem. Eng. Aspect, 2007, vol. 301, nos. 1–3, p. 329.
Park, K.H., Im, S.H., and Park, O.O., Nanotecnology, 2011, vol. 22, no. 4, p. 045602.
Wyttenbach, Th., von Helden, G., and Bowers, M.T., Int. J. Mass Spectrom. Ion Proc., 1997, vol. 165–166, p. 377.
Shimada, K., Matsuyama, S., Saito, T., Kinugasa, S., Nagahata, R., and Kawabata, S., Int. J. Mass Spectrom. Ion Proc., 2005, vol. 247, nos. 1–3, p. 85.
Yokoyama, Y., Hirajima, R., Morigaki, K., Yamaguchi, Y., and Ueda, K., J. Am. Soc. Mass Spectrom., 2007, vol. 18, no. 11, p. 1914.
Zobnina, V.G., Kosevich, M.V., Chagovets, V.V., Boryak, O.A., Kulik, A.N., and Gomori, A., J. Anal. Chem., 2010, vol. 66, no. 13, p. 1341.
Kosevich, M.V., Zobnina, V.G., Chagovets, V.V., and Boryak, O.A., Rapid Commun. Mass Spectrom., 2011, vol. 25, no. 6, p. 713.
Harris, J.M. and Zalipsky, S., Poly(Ethylene Glycol): Chemistry and Biological Aplications, Washington, DC: American Chemical Society, 1997.
Goronovskii, I.T., Nazarenko, Yu.P., and Nekryach, E.F., Kratkii spravochnik po khimii (Brief Handbook on Chemistry), Kiev: Naukova Dumka, 1987.
Bagatur’yants, A.A., Freidzon, A.Ya., Alfimov, M.V., Baerends, E.J., Howard, J.A.K., and Kuz’mina, L.G., J. Mol. Struct.: Theochem, 2002, vol. 588, nos. 1–3, p. 55.
Freidzon, A.Ya., Bagatur’yants, A.A., and Alfimov, M.V., Izv. Akad. Nauk, Ser. Khim., 2007, vol. 56, no. 3, p. 395.
Andersson, M., Alfredsson, V., Kjellin, P., and Palmqvist, A.E.C., Nano Lett., 2002, vol. 2, no. 12, p. 1403.
Neumann, R., Dermeik, S., and Sasson, Y., Isr. J. Chem., 1985, vol. 26, p. 239.
Rogers, R.D., Zhang, J., and Bauer, C.B., J. Alloys Compd., 1997, vol. 249, nos. 1–2, p. 41.
Antonioli, B., Clegg, J.K., Bray, D.J., Gloe, K., Gloe, K., Hesske, H., and Lindoy, L.F., Cryst. Eng. Comm., 2006, vol. 8, no. 10, p. 748.
Ershov, B.G., Ionova, G.V., and Kiseleva, A.D., Zh. Fiz. Khim., 1995, vol. 69, no. 2, p. 260.
Chandra, S., Hashmi, S.A., Saleem, M., and Agrawal, R.C., Solid State Ion., 1993, vol. 67, nos. 1–2, p. 1.
Benninghoven, A., Rudenauer, F.G., and Werner, H.W., Secondary Ion Mass Spectrometry: Basic Concepts, Instrumental Aspects, Applications and Trends, New York: Wiley, 1987.
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Original Russian Text © O.A. Boryak, M.V. Kosevich, V.V. Chagovets, V.G. Zobnina, V.V. Orlov, V.S. Shelkovsky, S.G. Stepanian, 2011, published in Mass-Spektrometria, 2011, vol. 8, no. 3, pp. 209–216.
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Boryak, O.A., Kosevich, M.V., Chagovets, V.V. et al. Mass-spectrometric study of the formation of silver nanoclusters in polyether media: 2. Fast atom bombardment and modeling. J Anal Chem 67, 994–1000 (2012). https://doi.org/10.1134/S1061934812130035
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DOI: https://doi.org/10.1134/S1061934812130035